ALLYLDIPHENYLPHOSPHINE OXIDE
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- Product name: ALLYLDIPHENYLPHOSPHINE OXIDE
- CAS: 4141-48-4
- MF: C15H15OP
- MW: 242.25
- EINECS:
- MDL Number:MFCD00013908
- Synonyms:ALLYLDIPHENYLPHOSPHINE OXIDE;Alydiphenylphosphine oxide;NISTC4141484;Diphenylallylphosphine oxide;[allyl(phenyl)phosphoryl]benzene;[phenyl(prop-2-enyl)phosphoryl]benzene;Diphenyl-2-propenylphosphine oxide;NSC 616249
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Properties
Melting point :110-114 °C(lit.)
Boiling point :200-202 °C(Press: 2 Torr)
Density :1.0769 g/cm3
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :solid
Boiling point :200-202 °C(Press: 2 Torr)
Density :1.0769 g/cm3
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :solid
Safety Information
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Description
Reactant for:- Preparaton of a-substituted alkylsilanes via regio- and chemoselective copper-catalyzed silylzincation and electrophilic substitution from terminal alkenes, and prepn. of α-substituted alcohols via Fleming-Tamao oxidation of alkylsilanes
- Olefin isomerization with Grubbs′ catalysts occluded in a hydrophobic matrix of polydimethylsiloxane (PDMS)
- C9-substituted trans-hydrindene via diastereotopic group-selective intramolecular Diels-Alder reaction
- Isomerization of allyl group-containing compounds to propenyl group-containing compounds in the presence of a Grubbs second-generation Ru catalyst
- Ruthenium-catalyzed olefin cross-metathesis of vinyl and allyl phosphine oxides to give alkenyl phosphine oxides and bis-phosphine oxides
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