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ChemicalBook > Product Catalogue >Pharmaceutical intermediates >OLED material intermediate >Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III)

Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III)

Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III) Structure
  • ₹18981
  • Product name: Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III)
  • CAS: 435294-03-4
  • MF: C35H28IrN2O2-2
  • MW: 700.82602
  • EINECS:
  • MDL Number:MFCD12022533
  • Synonyms:Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III);Ir(piq)2(acac) , Bis(1-phenylisoquinoline)(acetylacetonato)ir;IridiuM (III) bis(1-phenylisoquinolyl-N,C2') acetylacetonate;iridium(III) 4-oxopent-2-en-2-olate bis(2-(isoquinolin-1-yl)benzen-1-ide);(piq)2Ir(acac);Bis[2-(1-isoquinolinyl-N)phenyl-C](2,4-pentanedionato-O2,O4)iridium(III);Bis(1-phenyl-isoquinoline-C2,N)(acetylacetonato)iridium(III);Iridium, bis(1-phenyl-isoquinolinato-C2,N) acetylacetonate
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Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 250MG
  • ManufacturerSigma-Aldrich(India)
  • Product number771457
  • Product descriptionBis[2-(1-isoquinolinyl-N)phenyl-C](2,4-pentanedionato-O2,O4)iridium(III) 98%
  • Packaging250MG
  • Price₹18981
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 771457 Bis[2-(1-isoquinolinyl-N)phenyl-C](2,4-pentanedionato-O2,O4)iridium(III) 98% 250MG ₹18981 2022-06-14 Buy

Properties

Melting point :366-370°C
form :powder or crystals
color :Red
Absorption :λmax?302 nm in THF

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P333+P313 IF SKIN irritation or rash occurs: Get medical advice/attention.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P370+P378 In case of fire: Use … for extinction.
P391 Collect spillage. Hazardous to the aquatic environment
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Description

Bis(1-phenylisoquinoline)(acetylacetonate)iridium(III),?Ir(piq)2(acac) is widely used as an efficient phosphorescent red emitter dopant material in PhOLED devices.?It was reported that the piq ligand can?partially?suppress?the triplet-triplet annihilation and show short phosphorescent lifetime [2].

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