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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Esters >Methyl ester compound >Methyl 2-chloroacetoacetate

Methyl 2-chloroacetoacetate

Methyl 2-chloroacetoacetate Structure
  • ₹7000 - ₹30900
  • Product name: Methyl 2-chloroacetoacetate
  • CAS: 4755-81-1
  • MF: C5H7ClO3
  • MW: 150.56
  • EINECS:225-286-6
  • MDL Number:MFCD00008757
  • Synonyms:2-chloro-3-oxo-butanoicacimethylester ;Chloroacetoaceticacidmethylester;Butanoic acid, 2-chloro-3-oxo-, methyl ester;2-chloro-3-oxo-butyric acid methyl ester;2-Acetyl-2-chloroacetic acid methyl ester;Methyl 2-chloroacetoacetate,95%;2-chloro acetylacetate;2-CHLOROACETOACETIC ACID METHYL ESTER
3 prices
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 25G
  • 250G
  • ManufacturerTCI Chemicals (India)
  • Product numberC1219
  • Product descriptionMethyl 2-Chloroacetoacetate min. 95.0 %
  • Packaging25G
  • Price₹7000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberC1219
  • Product descriptionMethyl 2-Chloroacetoacetate min. 95.0 %
  • Packaging250G
  • Price₹30900
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number183911
  • Product descriptionMethyl 2-chloroacetoacetate
  • Packaging25G
  • Price₹13401.35
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) C1219 Methyl 2-Chloroacetoacetate min. 95.0 % 25G ₹7000 2022-05-26 Buy
TCI Chemicals (India) C1219 Methyl 2-Chloroacetoacetate min. 95.0 % 250G ₹30900 2022-05-26 Buy
Sigma-Aldrich(India) 183911 Methyl 2-chloroacetoacetate 25G ₹13401.35 2022-06-14 Buy

Properties

Melting point :-33--32.7 °C (lit.)
Boiling point :137 °C (lit.)
Density :1.236 g/mL at 25 °C (lit.)
refractive index :n20/D 1.446(lit.)
Flash point :161 °F
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Liquid
pka :7.89±0.46(Predicted)
color :Clear yellow
Water Solubility :50 g/L (20 ºC)
CAS DataBase Reference :4755-81-1(CAS DataBase Reference)
NIST Chemistry Reference :Butanoic acid, 2-chloro-3-oxo-, methyl ester(4755-81-1)
EPA Substance Registry System :Methyl 2-chloroacetoacetate (4755-81-1)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Methyl 2-chloroacetoacetate was used in one-pot synthesis of 2-arylimidazole-4-carboxylic acids. It was also used in synthesis of 3,5-disubstituted 1,2,4-triazoles.

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