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ChemicalBook > Product Catalogue >Organic Chemistry >Organometalate >MERCURY(II) TRIFLUOROMETHANESULFONATE

MERCURY(II) TRIFLUOROMETHANESULFONATE

MERCURY(II) TRIFLUOROMETHANESULFONATE Structure
  • ₹18543.23
  • Product name: MERCURY(II) TRIFLUOROMETHANESULFONATE
  • CAS: 49540-00-3
  • MF: CHF3HgO3S
  • MW: 350.66
  • EINECS:
  • MDL Number:MFCD00144746
  • Synonyms:MERCURY(II) TRIFLUOROMETHANESULFONATE (MERCURY TRIFLATE);Mercury(Ⅱ) trifluoroMethanesulfonate;Hg(OTf)2;Methanesulfonic acid,1,1,1-trifluoro-, mercury(2+) salt (2:1);Mercury trifluoromethanesulfonate;MERCURY(II) TRIFLUOROMETHANESULFONATE;MERCURY(II) TRIFLUOROMETHANESULPHONATE;MERCURY TRIFLATE
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Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 25G
  • ManufacturerSigma-Aldrich(India)
  • Product number515906
  • Product descriptionMercury(II) trifluoromethanesulfonate ≥95% trace metals basis
  • Packaging25G
  • Price₹18543.23
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 515906 Mercury(II) trifluoromethanesulfonate ≥95% trace metals basis 25G ₹18543.23 2022-06-14 Buy

Properties

Melting point :>350 °C (lit.)
solubility :It is soluble in H2O and CH3CN, fairly soluble in CH3NO2 and CH2Cl2, insoluble in hexane, ether, and toluene.
form :Powder
color :White
Sensitive :Moisture Sensitive
Exposure limits :NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3
Stability :hygroscopic

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
Precautionary statements:
P262 Do not get in eyes, on skin, or on clothing.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Description

Hg(OTf)2 exhibits remarkable catalytic activity for the hydroxylative cyclization of 1,6-enynes. Mercuric triflate is a very versatile reagent and has been used for several organic catalytic transformations including C-C bond forming cyclizations, alkyne hydrations, heterocycle synthesis and very recently in C-N bond forming reactions. Commonly used as the metal source for Lewis acid catalyzed asymmetric reactions.

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