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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organomagnesium >2-Thienylmagnesium bromide solution

2-Thienylmagnesium bromide solution

2-Thienylmagnesium  bromide  solution Structure
  • ₹18597.35
  • Product name: 2-Thienylmagnesium bromide solution
  • CAS: 5713-61-1
  • MF: C4H3BrMgS
  • MW: 187.34062
  • EINECS:
  • MDL Number:MFCD03094046
  • Synonyms:2-ThienylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal;magnesium,2H-thiophen-2-ide,bromide;Bromo-2-thienylmagnesium;THIOPHEN-2-YL-MAGNESIUM BROMIDE 1.0M;2-Thienylmagnesium bromide solution, 1.0M in tetrahydrofuran;thiophen-2-yl-magnesium bromide solution;2-Thienylmagnesium bromide solution;2-Thienylmagnesium bromide, 1M solution in THF, AcroSeal
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Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 50ML
  • ManufacturerSigma-Aldrich(India)
  • Product number550442
  • Product description2-Thienylmagnesium bromide solution 1.0?M in THF
  • Packaging50ML
  • Price₹18597.35
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 550442 2-Thienylmagnesium bromide solution 1.0?M in THF 50ML ₹18597.35 2022-06-14 Buy

Properties

Boiling point :65 °C
Density :1.011 g/mL at 25 °C
Flash point :−6 °F
form :Solution
color :Yellow to orange to brown

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

2-Thienylmagnesium bromide is a Grignard reagent that can be used as a reactant to synthesize:
  • 1-(2-thienyl)-carbinols by condensation reaction with aldehydes. Carbinols are further dehydrated to form 2-thienyl olefins.
  • Thiophene-functionalized polystyrene macromonomer (ThPStM), which is employed as a key intermediate to synthesize polystyrene-graft-polythiophene (PSt-g-PTh) via a combination of atom transfer radical polymerization (ATRP) and Grignard reaction.
  • Thienylene oligomers, which are used as conducting polymers and as potential OLEDs.


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