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6-CYANOHEXYLZINC BROMIDE

6-CYANOHEXYLZINC BROMIDE Structure
  • ₹11680.18
  • Product name: 6-CYANOHEXYLZINC BROMIDE
  • CAS: 312624-28-5
  • MF: C7H12BrNZn
  • MW: 255.47
  • EINECS:
  • MDL Number:MFCD01316997
  • Synonyms:6-CYANOHEXYLZINC BROMIDE, 0.5M SOLUTIONI N TETRAHYDROFURAN;6-CYANOHEXYLZINC BROMIDE;6-Cyanohexylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;6-cyanohexylzinc bromide solution;6-Cyanohexylzinc bromide solution 0.5 in THF;6-Cyanohexylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles;6-Cyanohexylzinc bromide solution 0.5M in THF;6-Cyanohexylzinc bromide 0.5 M in Tetrahydrofuran
Price1 Properties Safety Information Description
1 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)

Package

  • 50ML
  • ManufacturerSigma-Aldrich(India)
  • Product number497924
  • Product description6-Cyanohexylzinc bromide solution 0.5?M in THF
  • Packaging50ML
  • Price₹11680.18
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 497924 6-Cyanohexylzinc bromide solution 0.5?M in THF 50ML ₹11680.18 2022-06-14 Buy

Properties

Density :0.944 g/mL at 25 °C
Flash point :1 °F
storage temp. :2-8°C
Sensitive :Air Sensitive
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3		 Danger
Warning		 GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Description

6-Cyanohexylzinc bromide is an organozinc compound, which can be used as a reactant in palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bonds by coupling with organic halides or triflates.
It can also be used as a reactant to synthesize:
  • Cyanohexyl substituted aryl derivatives by palladium catalyzed coupling reaction with aryl bromides.
  • Methyl 5-(6-cyanohexyl)-3-methylfuran-2-carboxylate, a key intermediate which is used in the preparation of cyclic furfuryl ether via Wittig rearrangement.

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Suppliers and manufacturers

Rieke Metals, Inc. 3B Scientific Corporation SIGMA-RBI Alfa Aesar J & K SCIENTIFIC LTD. Shanghai Hanhong Scientific Co.,Ltd. Shenzhen Polymeri Biochemical Technology Co., Ltd. Riedel-de Haen AG Guangdong Wengjiang Chemical Reagent Co., Ltd. Sigma-Aldrich