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CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&

CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& Structure
  • ₹7625.7 - ₹24852.9
  • Product name: CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&
  • CAS: 677736-23-1
  • MF: C35H25.2CO.ClRu
  • MW: 638.125
  • EINECS:
  • MDL Number:MFCD09265041
  • Synonyms:CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&;Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II);Dicarbonylchloro[(1,2,3,4,5-η)-1,2,3,4,5-pentaphenyl-2,4-cyclopentadien-1-yl]-Ruthenium;CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& ISO 9001:2015 REACH;2,3,4,5-Tetraphenylcyclopenta-1,4-dien-1-yl)benzene carbon monoxide Chlororuthenium(1+
3 prices
Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 100MG
  • 250MG
  • 1G
  • ManufacturerSigma-Aldrich(India)
  • Product number686441
  • Product descriptionChlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
  • Packaging250MG
  • Price₹7625.7
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number669156
  • Product descriptionChlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
  • Packaging100MG
  • Price₹19080.9
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number686441
  • Product descriptionChlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
  • Packaging1G
  • Price₹24852.9
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 686441 Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II) 250MG ₹7625.7 2022-06-14 Buy
Sigma-Aldrich(India) 669156 Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II) 100MG ₹19080.9 2022-06-14 Buy
Sigma-Aldrich(India) 686441 Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II) 1G ₹24852.9 2022-06-14 Buy

Properties

Melting point :152-167 °C
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Reactant for:
  • Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst
  • Ligand exchange
  • Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds

Catalyst for:
  • (S)-Selective dynamic kinetic resolution of secondary alcohols
  • Stereoselective synthesis of neonicorinoide pesticide derivatives
  • Divergent asymmetric synthesis of 3,5-disubstituted piperidines

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