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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organomagnesium >Isopropylmagnesium chloride lithium chloride complex

Isopropylmagnesium chloride lithium chloride complex

Isopropylmagnesium chloride lithium chloride complex Structure
  • ₹0
  • Product name: Isopropylmagnesium chloride lithium chloride complex
  • CAS: 745038-86-2
  • MF: C3H6Cl2LiMg
  • MW: 144.23
  • EINECS:
  • MDL Number:MFCD07784514
  • Synonyms:Lithium dichloro(1-methylethyl)-magnesate(1-);IsopropylMagnesiuM chloride-lithiuM chloride coMplex, 1.3 M solution in THF, J&KSeal;Magnesate(1-),dichloro(1-Methylethyl)-, lithiuM (1:1);Isopropyl MagnesiuM chloride LithiuM chloride coMplex in THF (1.3 M);IsopropylMagnesiuM chloride-lithiuM chloride coMplex, 1.3 M solution in THF, SpcSeal;Isopropylmagnesium Chloride - Lithium Chloride (15% in Tetrahydrofuran, ca. 1mol/L);Isopropylmagnesium chloride-lithium chloride complex, 1.3 M solution in THF, HySeal;Isopropylmagnesium chloride - Lithium chloride complex, 1.3 M in THF
Manufacturer Product number Product description Packaging Price Updated Buy

Properties

Density :1.05
Flash point :-17 °C
storage temp. :Flammables area
form :Solution
color :Clear yellow to brown to gray
Sensitive :air sensitive, moisture sensitive
InChI :InChI=1S/C3H6.2ClH.Li.Mg/c1-3-2;;;;/h1-2H3;2*1H;;/q-1;;;+1;+2/p-2
InChIKey :GFRAKTLEBRSDFT-UHFFFAOYSA-L
SMILES :[C-](C)(C)[Mg+2]([Cl-])[Cl-].[Li+]

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

Isopropylmagnesium chloride lithium chloride complex is a reagent for Selective Metalations. And it was used with CH3MgCl/LiCl to affect magnesium-halogen exchange on unprotected aryl carboxylic acids.

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