Name: Epi-N-Quinyl-N’-bis(3,5-trifluoromethyl) phenylthiourea
Brand: chemicalbook
SKU: 852913-16-7

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Epi-N-Quinyl-N’-bis(3,5-trifluoromethyl) phenylthiourea

₹25990.83
Product name: Epi-N-Quinyl-N’-bis(3,5-trifluoromethyl) phenylthiourea
CAS: 852913-16-7
MF: C29H28F6N4OS
MW: 594.61
EINECS:
MDL Number:MFCD16875670
Synonyms:N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(8a,9S)-6'-methoxy-9-cinchonanyl]thiourea;N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(8a,9S)-6'-methoxy-9-cinchonanyl]thiourea 90%; 1-[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-3-[(S)(6-METHOXY-4-QUINOLINYL)-[(2S,4S,5R)-5-VINYL-1-AZA-BICYCLO[2.2.2]OCT-2-YL]METHYL]THIOUREA;1-[3,5-bis(trifluoromethyl)phenyl]-3-[(S)-[(1S,2S,4S,5R)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methyl]thiourea;N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(8α,9S)-6'-methox ycinchonan-9-yl]thiourea,99%d.e.;1-(3,5-Bis(trifluoromethyl)phenyl)-3-((6-methoxyquinolin-4-yl)((1S,2R,4S,5R)-5-vinylquinuclidin-2-yl)methyl)thiourea;Epi-N-Quinyl-N’-bis(3,5-trifluoromethyl) phenylthiourea;N-[3,5-bis(trifluoroMethyl)phenyl]-N'-[(8α,9S)-6'-Methoxycinchonan-9-yl]- Thiourea

Price1 Properties Safety Information Description

1 prices

Selected condition：

Brand

Sigma-Aldrich(India)

Package

250MG

ManufacturerSigma-Aldrich(India)
Product number690481
Product descriptionN-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8a,9S)-6′-methoxy-9-cinchonanyl]thiourea 90%
Packaging250MG
Price₹25990.83
Updated2022-06-14
Buy

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	690481	N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8a,9S)-6′-methoxy-9-cinchonanyl]thiourea 90%	250MG	₹25990.83	2022-06-14	Buy

Properties

Boiling point :598.2±60.0 °C(Predicted)
Density :1.39±0.1 g/cm3(Predicted)
pka :11.39±0.70(Predicted)

Safety Information

Symbol(GHS):

Signal word:

Danger

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	Pictogram	P-Codes
H301	Toxic if swalloed	Acute toxicity,oral	Category 3	Danger		P264, P270, P301+P310, P321, P330,P405, P501

Precautionary statements:

P301+P310

IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

Description

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8a,9S)-6′-methoxy-9-cinchonanyl]thiourea is a bifunctional cinchona organocatalyst, which can be used to synthesize:

Stereoselective diaryl(nitro)butanone via enantioselective Michael addition of nitromethane to chalcones.
Enantioselective β-amino acids via asymmetric Mannich reaction of malonates with aryl and alkyl imines.
The synthesis of 3-indolylmethanamines by the reaction of indoles with imines via asymmetric Friedel-Crafts reaction.
The enantioselective conjugate addition of active methylene compounds to enones to obtain the corresponding addition products.

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