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Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3]

Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3] Structure
  • ₹1720.5 - ₹14800
  • Product name: Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3]
  • CAS: 935449-46-0
  • MF: C94H100Cl5NO8P4Ru2
  • MW: 1875.12
  • EINECS:
  • MDL Number:MFCD09753038
  • Synonyms:Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3];DiMethylaMMoniuM dichlorotri(Mu-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dM-segphos)}2(μ-Cl)3];(R)[(RuCl(DMSEGPHOS)2(μCl)3][NH2Me2];(R)-[(RUCL(DM-SEGPHOS)2(Μ-CL)3][NH2ME2];[NH2Me2][(RuCl((R)-dm-segphos(regR)))2(mu-Cl)3];[NH2ME2][(RUCL((R)-DM-SEGPHOS))2(Μ-CL)3];Dimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos(R))}2(μ-Cl)3];[NH2Me2][(RuCl((R)-dm-segphos[R]))2(μ-Cl)3]
4 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 50MG
  • 100MG
  • 200MG
  • 1G
  • ManufacturerTCI Chemicals (India)
  • Product numberN1023
  • Product description[NH2Me2][(RuCl((R)-dm-segphos®))2(μ-Cl)3]
  • Packaging200MG
  • Price₹5200
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberN1023
  • Product description[NH2Me2][(RuCl((R)-dm-segphos®))2(μ-Cl)3]
  • Packaging1G
  • Price₹14800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number692212
  • Product description(R)−[(RuCl(DM−SEGPHOS®)2(μ−Cl)3][NH2Me2]
  • Packaging50MG
  • Price₹1720.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number692212
  • Product description(R)−[(RuCl(DM−SEGPHOS®)2(μ−Cl)3][NH2Me2]
  • Packaging100MG
  • Price₹3074.7
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) N1023 [NH2Me2][(RuCl((R)-dm-segphos®))2(μ-Cl)3] 200MG ₹5200 2022-05-26 Buy
TCI Chemicals (India) N1023 [NH2Me2][(RuCl((R)-dm-segphos®))2(μ-Cl)3] 1G ₹14800 2022-05-26 Buy
Sigma-Aldrich(India) 692212 (R)−[(RuCl(DM−SEGPHOS®)2(μ−Cl)3][NH2Me2] 50MG ₹1720.5 2022-06-14 Buy
Sigma-Aldrich(India) 692212 (R)−[(RuCl(DM−SEGPHOS®)2(μ−Cl)3][NH2Me2] 100MG ₹3074.7 2022-06-14 Buy

Properties

Melting point :>100°C
storage temp. :2-8°C
Water Solubility :Insoluble in water
form :Powder
color :light brown
Sensitive :air sensitive

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321 Specific treatment (see … on this label).
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.

Description

(R)-[(RuCl(DM-SEGPHOS?)2(μ-Cl)3][NH2Me2] can be used as a catalyst for the asymmetric hydrogenation of ketones to chiral alcohols. It can also be utilized to prepare (R)-methyl-3-hydroxybutanoate from methyl acetoacetate via stereoselective hydrogenation reaction.

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