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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Boric acid >4-(METHOXYCARBONYL)PHENYLBORONIC ACID

4-(METHOXYCARBONYL)PHENYLBORONIC ACID

4-(METHOXYCARBONYL)PHENYLBORONIC ACID Structure
  • ₹2268 - ₹16800
  • Product name: 4-(METHOXYCARBONYL)PHENYLBORONIC ACID
  • CAS: 99768-12-4
  • MF: C8H9BO4
  • MW: 179.97
  • EINECS:619-459-9
  • MDL Number:MFCD01632203
  • Synonyms:RARECHEM AH PB 0115;P-(METHOXYCARBONYL)PHENYLBORONIC ACID;AKOS BRN-0122;4-METHOXYCARBONYLBENZENEBORONIC ACID;4-CARBOMETHOXYPHENYLBORONIC ACID;Methyl 4-boronobenzoate 4-(Methoxycarbonyl)phenylboronic acid;4-METHOXYCATBONYLPHENYLBORONICACID;4-(Methoxycabonyl)phenylboronic acid
7 prices
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 1G
  • 5G
  • 25G
  • ManufacturerTCI Chemicals (India)
  • Product numberM1907
  • Product description4-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
  • Packaging1G
  • Price₹2600
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberM1907
  • Product description4-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
  • Packaging5G
  • Price₹8300
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberM1907
  • Product description4-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
  • Packaging25G
  • Price₹16800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number594539
  • Product description4-Methoxycarbonylphenylboronic acid ≥95%
  • Packaging1G
  • Price₹7014.6
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number594539
  • Product description4-Methoxycarbonylphenylboronic acid ≥95%
  • Packaging5G
  • Price₹11084.8
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H27627-06
  • Product description4-(Methoxycarbonyl)benzeneboronic acid, 97%
  • Packaging5g
  • Price₹6876
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H27627-03
  • Product description4-(Methoxycarbonyl)benzeneboronic acid, 97%
  • Packaging1g
  • Price₹2268
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) M1907 4-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 1G ₹2600 2022-05-26 Buy
TCI Chemicals (India) M1907 4-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 5G ₹8300 2022-05-26 Buy
TCI Chemicals (India) M1907 4-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 25G ₹16800 2022-05-26 Buy
Sigma-Aldrich(India) 594539 4-Methoxycarbonylphenylboronic acid ≥95% 1G ₹7014.6 2022-06-14 Buy
Sigma-Aldrich(India) 594539 4-Methoxycarbonylphenylboronic acid ≥95% 5G ₹11084.8 2022-06-14 Buy
ALFA India ALF-H27627-06 4-(Methoxycarbonyl)benzeneboronic acid, 97% 5g ₹6876 2022-05-26 Buy
ALFA India ALF-H27627-03 4-(Methoxycarbonyl)benzeneboronic acid, 97% 1g ₹2268 2022-05-26 Buy

Properties

Melting point :197-200 °C (lit.)
Boiling point :345.8±44.0 °C(Predicted)
Density :1.25±0.1 g/cm3(Predicted)
storage temp. :Inert atmosphere,Room Temperature
solubility :Soluble in methanol.
form :powder
pka :7.69±0.10(Predicted)
color :white to off-white
InChI :InChI=1S/C8H9BO4/c1-13-8(10)6-2-4-7(5-3-6)9(11)12/h2-5,11-12H,1H3
InChIKey :PQCXFUXRTRESBD-UHFFFAOYSA-N
SMILES :C1=CC(C(OC)=O)=CC=C1B(O)O
CAS DataBase Reference :99768-12-4(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

It is a reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration and cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. It is employed as reagent in Reagent used in preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid, chromenones and their bradykinin B1 antagonistic activity, Pt nanoparticles on Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injection and salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.

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