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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Silane >Diphenylsilane

Diphenylsilane

Diphenylsilane Structure
  • ₹2114 - ₹29155
  • Product name: Diphenylsilane
  • CAS: 775-12-2
  • MF: C12H12Si
  • MW: 184.31
  • EINECS:212-271-4
  • MDL Number:MFCD00003002
  • Synonyms:DIPHENYLSILANE FOR SYNTHESIS 25 ML;DIPHENYLSILANE FOR SYNTHESIS 5 ML;Diphenylsilane, min. 97%;Diphenylsilane,97%;Diphenylsilane,99%;diphenyl-silan ;Silane,diphenyl- ;TSL8224
9 prices
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Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5g
  • 25g
  • 100g
  • ManufacturerALFA India
  • Product numberALF-A10884-06
  • Product descriptionDiphenylsilane, 97%
  • Packaging5g
  • Price₹2114
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A10884-14
  • Product descriptionDiphenylsilane, 97%
  • Packaging25g
  • Price₹9661
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A10884-22
  • Product descriptionDiphenylsilane, 97%
  • Packaging100g
  • Price₹29155
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD2406
  • Product descriptionDiphenylsilane min. 97.0 %
  • Packaging5G
  • Price₹4000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD2820
  • Product descriptionDiphenylsilane min. 98.0 %
  • Packaging5G
  • Price₹5000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD2406
  • Product descriptionDiphenylsilane min. 97.0 %
  • Packaging25G
  • Price₹12700
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD2820
  • Product descriptionDiphenylsilane min. 98.0 %
  • Packaging25G
  • Price₹20500
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number148482
  • Product descriptionDiphenylsilane 97%
  • Packaging5G
  • Price₹2413.98
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number148482
  • Product descriptionDiphenylsilane 97%
  • Packaging25G
  • Price₹8313.6
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-A10884-06 Diphenylsilane, 97% 5g ₹2114 2022-05-26 Buy
ALFA India ALF-A10884-14 Diphenylsilane, 97% 25g ₹9661 2022-05-26 Buy
ALFA India ALF-A10884-22 Diphenylsilane, 97% 100g ₹29155 2022-05-26 Buy
TCI Chemicals (India) D2406 Diphenylsilane min. 97.0 % 5G ₹4000 2022-05-26 Buy
TCI Chemicals (India) D2820 Diphenylsilane min. 98.0 % 5G ₹5000 2022-05-26 Buy
TCI Chemicals (India) D2406 Diphenylsilane min. 97.0 % 25G ₹12700 2022-05-26 Buy
TCI Chemicals (India) D2820 Diphenylsilane min. 98.0 % 25G ₹20500 2022-05-26 Buy
Sigma-Aldrich(India) 148482 Diphenylsilane 97% 5G ₹2413.98 2022-06-14 Buy
Sigma-Aldrich(India) 148482 Diphenylsilane 97% 25G ₹8313.6 2022-06-14 Buy

Properties

Melting point :<20°C
Boiling point :95-97 °C/13 mmHg (lit.)
Density :0.993 g/mL at 25 °C (lit.)
refractive index :n20/D 1.579(lit.)
Flash point :209 °F
storage temp. :Inert atmosphere,2-8°C
form :liquid
Specific Gravity :1
color :colorless
Water Solubility :Decomposes in water.
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :3: reacts with aqueous base
BRN :2935887
InChIKey :VDCSGNNYCFPWFK-UHFFFAOYSA-N
CAS DataBase Reference :775-12-2(CAS DataBase Reference)
NIST Chemistry Reference :Silane, diphenyl-(775-12-2)
EPA Substance Registry System :Silane, diphenyl- (775-12-2)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P337+P313 IF eye irritation persists: Get medical advice/attention.

Description

Thiocarbonyl derivatives of secondary alcohols are readily reduced by diphenylsilane in a radical chain process at room temperature using triethylborane-air as an initiator. An improved radical chain procedure for the deoxygenation of secondary and primary alcohols using diphenylsilane as hydrogen atom donor and triethylborane-air as initiator. Diphenylsilane is a reagent in the invention of radical reactions for deoxygenation of alcohols via their thiocarbonyl derivatives, deamination via isonitriles, and dehalogenation of bromo- and iodo- compounds by radical chain chemistry. Fluorescent film sensor for vapor-phase nitroaromatic explosives via monolayer assembly of oligo(diphenylsilane) on glass plate surfaces. Reductions of carboxylic acid derivatives by silanes in the presence of rhodium complexes were studied. Carboxylic esters were reduced to alcohols by diphenylsilane catalyzed by [RhCl (cod)] 2/4PPh 3 or [RhCl (PPh 3) 3] at room temperature in up to 99% yields. Sequential C- Si bond formations from diphenylsilane and its application to silanediol peptide isostere precursors.

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