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ChemicalBook > Product Catalogue >Inorganic chemistry >Inorganic salts >Hydrides, nitrides, azides >Hydride >Hydrocinnamoyl chloride

Hydrocinnamoyl chloride

Hydrocinnamoyl chloride Structure
  • ₹1948.5 - ₹5011.98
  • Product name: Hydrocinnamoyl chloride
  • CAS: 645-45-4
  • MF: C9H9ClO
  • MW: 168.62
  • EINECS:211-443-6
  • MDL Number:MFCD00000748
  • Synonyms:BETA-PHENYLPROPIONYL CHLORIDE;2-Ethoxybenzyl Chloride;3-Phenylpropionylchloride,98%;3-Phenylpropionyl Chloride beta-Phenylpropionyl Chloride;3-PHENYL PROPANOYL CHLOVIDE;PHENYLPROPIONYLCHLORIDE;beta-Phenylpropanoyl chloride;Hydrocinnamoyl
Price5 Properties Safety Information Description
5 prices
Selected condition：

Brand

  • Sigma-Aldrich
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 25G
  • ManufacturerSigma-Aldrich
  • Product number249440
  • Product descriptionHydrocinnamoyl chloride 98%
  • Packaging5G
  • Price₹1948.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number249440
  • Product descriptionHydrocinnamoyl chloride 98%
  • Packaging25G
  • Price₹5011.98
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberH0696
  • Product description3-Phenylpropionyl Chloride min. 97.0 %
  • Packaging25G
  • Price₹4500
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number249440
  • Product descriptionHydrocinnamoyl chloride 98%
  • Packaging5G
  • Price₹1948.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number249440
  • Product descriptionHydrocinnamoyl chloride 98%
  • Packaging25G
  • Price₹5011.98
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 249440 Hydrocinnamoyl chloride 98% 5G ₹1948.5 2022-06-14 Buy
Sigma-Aldrich 249440 Hydrocinnamoyl chloride 98% 25G ₹5011.98 2022-06-14 Buy
TCI Chemicals (India) H0696 3-Phenylpropionyl Chloride min. 97.0 % 25G ₹4500 2022-05-26 Buy
Sigma-Aldrich(India) 249440 Hydrocinnamoyl chloride 98% 5G ₹1948.5 2022-06-14 Buy
Sigma-Aldrich(India) 249440 Hydrocinnamoyl chloride 98% 25G ₹5011.98 2022-06-14 Buy

Properties

Melting point :−7-−5 °C(lit.)
Boiling point :107 °C11 mm Hg(lit.)
Density :1.135 g/mL at 25 °C(lit.)
vapor pressure :6.893Pa at 25℃
refractive index :n20/D 1.5265(lit.)
Flash point :227 °F
storage temp. :Inert atmosphere,2-8°C
solubility :Chloroform (Slightly)
form :Liquid
color :deep greenish-yellow
Water Solubility :Soluble in water (reacts), and ether.
Sensitive :Moisture Sensitive
BRN :742586
LogP :1.73
CAS DataBase Reference :645-45-4(CAS DataBase Reference)
NIST Chemistry Reference :Benzenepropanoyl chloride(645-45-4)
EPA Substance Registry System :Benzenepropanoyl chloride (645-45-4)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger GHS hazard pictograms P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P302+P352 IF ON SKIN: wash with plenty of soap and water.

Description

The 3-phenylpropionate (dihydrocinnamoyl) ester has been used as a protecting group in nucleoside synthesis. Used in the synthesis of 1-Phenyl-3-methyl-4-acyl-5- pyrazolones. N-(3-phenyl-n-propyl)-1-phenyl-2-aminopropane were prepared by acylation of the appropriate amine with 3-phenylpropionyl chloride followed by reduction of the resulting amide with either LiA1H4. For the preparation of the phenylacetyl (PA) and 3-phenylpropionyl (PP) derivatives, the corresponding amino acids were coupled in the usual manner with phenylacetyl chloride or 3-phenylpropionyl chloride in the presence of either NaOH(PA-LD- and DL-Pgly. 3-Phenylpropionyl chloride (4) was treated with diazomethane to give diazoketone. Allyloxy resin 12 was acylated with 3-phenylpropionyl chloride and treated with 50% TFA for 1 h followed by treatment with Pd(PPh3)4/PPh3 in solution to furnish the desired hydrox- amic acid.

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