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ChemicalBook > Product Catalogue >Organic Chemistry >Carboxylic acids and derivatives >Acyclic carboxylic acid >Oxalic acid

Oxalic acid

Oxalic acid Structure
  • ₹1667.05 - ₹65247.58
  • Product name: Oxalic acid
  • CAS: 144-62-7
  • MF: C2H2O4
  • MW: 90.03
  • EINECS:205-634-3
  • MDL Number:MFCD00002573
  • Synonyms:OXALATE ION CHROMATOGRAPHY STANDARD;BETZ 0295;DICARBOXYLIC ACID C2;Kleesαure ;Kyselina stavelova;NCI-C55209;Oxaalzuur;Oxalate Ion Chromatography Standard Solution Fluka
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  • Sigma-Aldrich(India)
  • Sigma-Aldrich
  • ALFA India
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  • ManufacturerSigma-Aldrich(India)
  • Product number194131
  • Product descriptionOxalic acid 98%
  • Packaging5G
  • Price₹1667.05
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number75688
  • Product descriptionOxalic acid puriss. p.a., anhydrous, ≥99.0% (RT)
  • Packaging50G
  • Price₹3485.65
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number194131
  • Product descriptionOxalic acid 98%
  • Packaging250G
  • Price₹3507.3
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number68487
  • Product descriptionOxalic acid concentrate 0.1?M (COOH)2 (0.2N), eluent concentrate for IC
  • Packaging1L
  • Price₹5228.48
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number658537
  • Product descriptionOxalic acid purified grade, 99.999% trace metals basis
  • Packaging25G
  • Price₹10738.4
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number194131
  • Product descriptionOxalic acid 98%
  • Packaging1KG
  • Price₹14678.7
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.16144
  • Product descriptionOxalic acid anhydrous for synthesis
  • Packaging250G
  • Price₹16730
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number658537
  • Product descriptionOxalic acid purified grade, 99.999% trace metals basis
  • Packaging100G
  • Price₹23382
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number75688
  • Product descriptionOxalic acid puriss. p.a., anhydrous, ≥99.0% (RT)
  • Packaging250G
  • Price₹5726.43
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number41706
  • Product descriptionOxalic acid analytical standard
  • Packaging100MG
  • Price₹5964.58
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number241172
  • Product descriptionOxalic acid ReagentPlus?, ≥99%
  • Packaging50G
  • Price₹6040.35
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number1.60329
  • Product descriptionOxalic acid solution c(CsH2O4) = 0.005 mol; standardised against Potassium permangante solution, Titripur?
  • Packaging1L
  • Price₹6370
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.16144
  • Product descriptionOxalic acid anhydrous for synthesis
  • Packaging50G
  • Price₹6490
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number1.60330
  • Product descriptionOxalic acid solution c(CsH2O4) = 0.05 mol; standardised against Potassium permangante solution, Titripur?
  • Packaging1L
  • Price₹6650
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number1.09965
  • Product descriptionOxalic acid solution for 1000 ml, c(C?H?O?) = 0.05 mol/l (0.1 N) Titrisol?
  • Packaging1AMP
  • Price₹3880
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number1.09932
  • Product descriptionOxalic acid solution for 1000 ml, c(C?H?O?) = 0.005 mol/l (0.01 N) Titrisol?
  • Packaging1AMP
  • Price₹3500
  • Updated2022-06-14
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Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 194131 Oxalic acid 98% 5G ₹1667.05 2022-06-14 Buy
Sigma-Aldrich(India) 75688 Oxalic acid puriss. p.a., anhydrous, ≥99.0% (RT) 50G ₹3485.65 2022-06-14 Buy
Sigma-Aldrich(India) 194131 Oxalic acid 98% 250G ₹3507.3 2022-06-14 Buy
Sigma-Aldrich(India) 68487 Oxalic acid concentrate 0.1?M (COOH)2 (0.2N), eluent concentrate for IC 1L ₹5228.48 2022-06-14 Buy
Sigma-Aldrich(India) 658537 Oxalic acid purified grade, 99.999% trace metals basis 25G ₹10738.4 2022-06-14 Buy
Sigma-Aldrich(India) 194131 Oxalic acid 98% 1KG ₹14678.7 2022-06-14 Buy
Sigma-Aldrich(India) 8.16144 Oxalic acid anhydrous for synthesis 250G ₹16730 2022-06-14 Buy
Sigma-Aldrich(India) 658537 Oxalic acid purified grade, 99.999% trace metals basis 100G ₹23382 2022-06-14 Buy
Sigma-Aldrich(India) 75688 Oxalic acid puriss. p.a., anhydrous, ≥99.0% (RT) 250G ₹5726.43 2022-06-14 Buy
Sigma-Aldrich(India) 41706 Oxalic acid analytical standard 100MG ₹5964.58 2022-06-14 Buy
Sigma-Aldrich(India) 241172 Oxalic acid ReagentPlus?, ≥99% 50G ₹6040.35 2022-06-14 Buy
Sigma-Aldrich(India) 1.60329 Oxalic acid solution c(CsH2O4) = 0.005 mol; standardised against Potassium permangante solution, Titripur? 1L ₹6370 2022-06-14 Buy
Sigma-Aldrich(India) 8.16144 Oxalic acid anhydrous for synthesis 50G ₹6490 2022-06-14 Buy
Sigma-Aldrich(India) 1.60330 Oxalic acid solution c(CsH2O4) = 0.05 mol; standardised against Potassium permangante solution, Titripur? 1L ₹6650 2022-06-14 Buy
Sigma-Aldrich(India) 1.09965 Oxalic acid solution for 1000 ml, c(C?H?O?) = 0.05 mol/l (0.1 N) Titrisol? 1AMP ₹3880 2022-06-14 Buy
Sigma-Aldrich(India) 1.09932 Oxalic acid solution for 1000 ml, c(C?H?O?) = 0.005 mol/l (0.01 N) Titrisol? 1AMP ₹3500 2022-06-14 Buy

Properties

Melting point :189.5 °C (dec.)(lit.)
Boiling point :365.1°C (estimate)
Density :0.99 g/mL at 25 °C
vapor density :4.4 (vs air)
vapor pressure :<0.01 mm Hg ( 20 °C)
refractive index :1.4261 (estimate)
Flash point :101-157°C
storage temp. :Store below +30°C.
solubility :water: soluble108g/L at 25°C
form :Liquid
pka :1.23(at 25℃)
color :White
PH Range :6 - 8 at 25 °C
PH :3(1 mM solution);2.09(10 mM solution);1.31(100 mM solution);
Odor :odorless
Water Solubility :90 g/L (20 ºC)
Sublimation :101-157 ºC
Merck :14,6911
BRN :385686
Henry's Law Constant :1.43 at pH 4 (quoted, Gaffney et al., 1987)
Exposure limits :NIOSH REL: TWA 1, STEL 2, IDLH 500; OSHA PEL: TWA 1; ACGIH TLV: TWA 1, STEL 2 (adopted).
Stability :Stable, but moisture sensitive. Incompatible with metals.
InChIKey :MUBZPKHOEPUJKR-UHFFFAOYSA-N
LogP :-1.7 at 23℃
CAS DataBase Reference :144-62-7(CAS DataBase Reference)
NIST Chemistry Reference :Oxalic acid(144-62-7)
EPA Substance Registry System :Oxalic acid (144-62-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Oxalic acid is a strong dicarboxylic acid occurring in many plants and vegetables, usually as its calcium or potassium salts. Oxalic acid is the only possible compound in which two carboxyl groups are joined directly; for this reason oxalic acid is one of the strongest organic acids. Unlike other carboxylic acids (except formic acid), it is readily oxidized; this makes it useful as a reducing agent for photography, bleaching, and ink removal. Oxalic acid is usually prepared by heating sodium formate with sodium hydroxide to form sodium oxalate, which is converted to calcium oxalate and treated with sulfuric acid to obtain free oxalic acid.
concentrations of oxalic acid are pretty low in most plants and plant-based foods, but there’s enough in spinach, chard and beet greens to interfere with the absorption of the calcium these plants also contain.
It is produced in the body by metabolism of glyoxylic acid or ascorbic acid. It is not metabolized but excreted in the urine. It is used as an analytical reagent and general reducing agent.Oxalic acid is a natural acaricide used for treatment against varroa mites in colonies with no/low brood, packages, or swarms. Vaporized oxalic acid is used by some beekeepers as an insecticide against the parasitic Varroa mite.

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