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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Phosphine ligand >(R)-DM-BINAP

(R)-DM-BINAP

(R)-DM-BINAP Structure
  • ₹3160.9 - ₹19648
  • Product name: (R)-DM-BINAP
  • CAS: 137219-86-4
  • MF: C52H48P2
  • MW: 734.89
  • EINECS:681-153-6
  • MDL Number:MFCD01630821
  • Synonyms:(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;(R)-(+)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL;RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;RAC-XYLYL-BINAP;(R)-3,5-XYLYL-BINAP;(R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-B ;(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%(R)-3,5-xylyl-BINAP;(R)-(+)-2,2'-bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl
5 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 100MG
  • 200MG
  • 500mg
  • 1G
  • ManufacturerTCI Chemicals (India)
  • Product numberX0070
  • Product description(R)-(+)-XylBINAP
  • Packaging200MG
  • Price₹3400
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberX0070
  • Product description(R)-(+)-XylBINAP
  • Packaging1G
  • Price₹9800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number692379
  • Product description(R)-DM-BINAP
  • Packaging100MG
  • Price₹3160.9
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H27680-ME
  • Product description(R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
  • Packaging500mg
  • Price₹19648
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H27680-MC
  • Product description(R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
  • Packaging100mg
  • Price₹6356
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) X0070 (R)-(+)-XylBINAP 200MG ₹3400 2022-05-26 Buy
TCI Chemicals (India) X0070 (R)-(+)-XylBINAP 1G ₹9800 2022-05-26 Buy
Sigma-Aldrich(India) 692379 (R)-DM-BINAP 100MG ₹3160.9 2022-06-14 Buy
ALFA India ALF-H27680-ME (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 500mg ₹19648 2022-05-26 Buy
ALFA India ALF-H27680-MC (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 100mg ₹6356 2022-05-26 Buy

Properties

Melting point :203-206°C
Boiling point :825.3±65.0 °C(Predicted)
alpha :169 º (c=1 in chloroform)
storage temp. :Inert atmosphere,Room Temperature
Water Solubility :Insoluble in water
form :crystal
color :white to pale yellow
optical activity :[α]20/D +169°, c = 1 in chloroform

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

(R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction.

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