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(+)-ALPHA-LONGIPINENE

(+)-ALPHA-LONGIPINENE Structure
  • ₹13634.93
  • Product name: (+)-ALPHA-LONGIPINENE
  • CAS: 5989-08-2
  • MF: C15H24
  • MW: 204.35
  • EINECS:
  • MDL Number:MFCD00077624
  • Synonyms:Tricyclo[5.4.0.0(2,8)]undec-9-ene, 2,6,6,9-tetramethyl-;Tricyclo[5.4.0.0(2,8)]undec-9-ene, 3,3,7,9-tetramethyl-;(+)-alpha-Longipinene >=99.0% (sum of enantiomers, GC);(1R,2S,7R,8R)-2,6,6,9-TETRAMETHYL-TRICYCLO[5.4.0.0(2.8)]UNDEC-9-ENE;(+)-ALPHA-LONGIPINENE;(+)-α-longipinene;2,6,6,9-Tetramethyl-tricyclo[5.4.0.0(2,8)]undec-9-ene;(+)-alfa-Longipinene
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Brand

  • Sigma-Aldrich(India)

Package

  • 250MG
  • ManufacturerSigma-Aldrich(India)
  • Product number62638
  • Product description(+)-α-Longipinene ≥97.0% (sum of enantiomers, GC)
  • Packaging250MG
  • Price₹13634.93
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 62638 (+)-α-Longipinene ≥97.0% (sum of enantiomers, GC) 250MG ₹13634.93 2022-06-14 Buy

Properties

Boiling point :244-246 °C(lit.)
Density :0.915 g/mL at 20 °C(lit.)
refractive index :n20/D 1.493
Flash point :92℃
storage temp. :2-8°C
solubility :Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
form :Oil
color :Colourless
optical activity :[α]20/D +25±1°, neat
Stability :Light Sensitive
LogP :6.398 (est)

Safety Information

Symbol(GHS):
Signal word:
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Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
Precautionary statements:

Description

(+)-α-Longipinene can be used as a starting material for the synthesis of new terpenoids, (+)-(5S)-5,12-dihydroxy-α-longipinene, (-)-(5R)-5,12-dihydroxy-α-longipinene, and (+)-12-hydroxy-α-longipinen-5-one by oxidation reaction using Aspergillus niger as a biocatalyst. It can be oxidized using lead tetraacetate into tertiary alcohol, longi-cis-verbenol, longi-trans-verbenol, longi-cis-β-crysanthenol, longiverbenone, longi-trans- β -crysanthenol, 2 β,3 β -dihydroxylongipinane, 4 α,8-dihydroxy- α -Iongipinene, and 4 β,8-dihydroxy- α -longipinene.

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