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CU-TMEDA CATALYST

CU-TMEDA CATALYST Structure
  • ₹5000 - ₹16700
  • Product name: CU-TMEDA CATALYST
  • CAS: 30698-64-7
  • MF: C12H34Cl2Cu2N4O2
  • MW: 464.42
  • EINECS:
  • MDL Number:MFCD01321163
  • Synonyms:COPPER(II) CHLORIDE HYDROXIDE (N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE) COMPLEX DIMER;CHLOROHYDROXO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)COPPER(II);Di-μ-hydroxo-bis[(N,N,N'.N'-tetramethylethylenediamine);CU-TMEDA CATALYST;DI-MU-HYDROXO-BIS[(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)COPPER(2)] CHLORIDE;DI-MU-HYDROXO-BIS[(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)COPPER(II)] CHLORIDE;DI-MU-HYDROXO-BIS[(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)COPPER(II)]DICHLORIDE;Di-?hydroxo-bis[(N,N,N,N-tetramethylethylenediamine)copper(II)] chloride
3 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 25G
  • ManufacturerTCI Chemicals (India)
  • Product numberD2542
  • Product descriptionDi-μ-hydroxo-bis[(N,N,N',N'-tetramethylethylenediamine)copper(II)] Chloride
  • Packaging5G
  • Price₹5000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD2542
  • Product descriptionDi-μ-hydroxo-bis[(N,N,N',N'-tetramethylethylenediamine)copper(II)] Chloride
  • Packaging25G
  • Price₹16700
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number593192
  • Product descriptionCu-TMEDA catalyst
  • Packaging5G
  • Price₹7685.75
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) D2542 Di-μ-hydroxo-bis[(N,N,N',N'-tetramethylethylenediamine)copper(II)] Chloride 5G ₹5000 2022-05-26 Buy
TCI Chemicals (India) D2542 Di-μ-hydroxo-bis[(N,N,N',N'-tetramethylethylenediamine)copper(II)] Chloride 25G ₹16700 2022-05-26 Buy
Sigma-Aldrich(India) 593192 Cu-TMEDA catalyst 5G ₹7685.75 2022-06-14 Buy

Properties

Melting point :138-148 °C
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
Water Solubility :Soluble in water
form :Powder
color :Dark purple

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P370+P378 In case of fire: Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

Catalyst for:
  • Asymmetric conjugate addition reactions
  • 1,3-dipolar cycloaddition of pyrazolidinone-based dipoles to terminal alkynes (precatalyst)
  • Oxidative N-arylation of imidazoles
  • Oxidative coupling copolymerization
  • Tandem phosphorous-carbon bond formation-oxyfunctionalization reactions
  • Benzylation and allylation of amides

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