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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Nitro compounds >Methyl nitroacetate

Methyl nitroacetate

Methyl nitroacetate Structure
  • ₹3454 - ₹33860.6
  • Product name: Methyl nitroacetate
  • CAS: 2483-57-0
  • MF: C3H5NO4
  • MW: 119.08
  • EINECS:219-622-0
  • MDL Number:MFCD00075480
  • Synonyms:NITROACETIC ACID METHYL ESTER;Methyl a-nitroacetate;methyl2-nitroacetate ;nitro-aceticacimethylester ;METHYL ALFA NITROACETATE;METHYL NITROACETATE;Methylnitroacetate,98%;Methyl nitrozcetate
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  • Sigma-Aldrich(India)
  • TCI Chemicals (India)
  • ALFA India

Package

  • 1G
  • 2g
  • 5G
  • 10g
  • 25G
  • ManufacturerSigma-Aldrich(India)
  • Product number366463
  • Product descriptionMethyl nitroacetate 98%
  • Packaging5G
  • Price₹33860.6
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number366463
  • Product descriptionMethyl nitroacetate 98%
  • Packaging1G
  • Price₹9255.38
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberN0656
  • Product descriptionMethyl Nitroacetate min. 97.0 %
  • Packaging25G
  • Price₹21500
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberN0656
  • Product descriptionMethyl Nitroacetate min. 97.0 %
  • Packaging5G
  • Price₹10800
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L18950-09
  • Product descriptionMethyl nitroacetate, 97+%
  • Packaging10g
  • Price₹13757
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L18950-04
  • Product descriptionMethyl nitroacetate, 97+%
  • Packaging2g
  • Price₹3454
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 366463 Methyl nitroacetate 98% 5G ₹33860.6 2022-06-14 Buy
Sigma-Aldrich(India) 366463 Methyl nitroacetate 98% 1G ₹9255.38 2022-06-14 Buy
TCI Chemicals (India) N0656 Methyl Nitroacetate min. 97.0 % 25G ₹21500 2022-05-26 Buy
TCI Chemicals (India) N0656 Methyl Nitroacetate min. 97.0 % 5G ₹10800 2022-05-26 Buy
ALFA India ALF-L18950-09 Methyl nitroacetate, 97+% 10g ₹13757 2022-05-26 Buy
ALFA India ALF-L18950-04 Methyl nitroacetate, 97+% 2g ₹3454 2022-05-26 Buy

Properties

Boiling point :195-198 °C (lit.)
Density :1.294 g/mL at 25 °C (lit.)
refractive index :n20/D 1.425(lit.)
Flash point :221 °F
storage temp. :Keep in dark place,Sealed in dry,Room Temperature
solubility :Miscible with ethanol, ether and most organic solvents.
pka :5.73±0.29(Predicted)
form :clear liquid
color :Colorless to Light yellow
Sensitive :Light Sensitive
BRN :1758670
InChI :InChI=1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3
InChIKey :ALBSWLMUHHZLLR-UHFFFAOYSA-N
SMILES :C(OC)(=O)C[N+]([O-])=O
CAS DataBase Reference :2483-57-0(CAS DataBase Reference)
NIST Chemistry Reference :Acetic acid, nitro-, methyl ester(2483-57-0)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.

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