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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Boric acid >Pinacolborane

Pinacolborane

Pinacolborane Structure
  • ₹3800 - ₹153574.28
  • Product name: Pinacolborane
  • CAS: 25015-63-8
  • MF: C6H13BO2
  • MW: 127.98
  • EINECS:607-485-3
  • MDL Number:MFCD00674030
  • Synonyms:Pinacolatoborane;TetraMethyl-1,3,2-dioxab;Pinacolborane, 97%, stabilized;4,4,5,5-TetraMethyl-1,3,2-dioxaborolane 97%;4,4,5,5-TetraMethyl-1,3,2-dioxaborolane solution 1.0 M in THF;Pinacolborane (4,4,5,5-Tetramethyl-1,3,2-dioxaborolane);PINACOLBORANE;4,4,5,5-Tetramethyl-1,3,2-dioxaborolane,Pinacolborane
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 5G
  • 25G
  • 100G
  • 100ML
  • 4X25ML
  • 500G
  • ManufacturerTCI Chemicals (India)
  • Product numberT2572
  • Product description4,4,5,5-Tetramethyl-1,3,2-dioxaborolane min. 97.0 %
  • Packaging5G
  • Price₹3800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT2572
  • Product description4,4,5,5-Tetramethyl-1,3,2-dioxaborolane min. 97.0 %
  • Packaging25G
  • Price₹13000
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number655856
  • Product description4,4,5,5-Tetramethyl-1,3,2-dioxaborolane 97%
  • Packaging5G
  • Price₹4882.08
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number655856
  • Product description4,4,5,5-Tetramethyl-1,3,2-dioxaborolane 97%
  • Packaging25G
  • Price₹12091.53
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number458945
  • Product description4,4,5,5-Tetramethyl-1,3,2-dioxaborolane solution 1.0?M in THF
  • Packaging4X25ML
  • Price₹17016.9
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number458945
  • Product description4,4,5,5-Tetramethyl-1,3,2-dioxaborolane solution 1.0?M in THF
  • Packaging100ML
  • Price₹19106.13
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number655856
  • Product description4,4,5,5-Tetramethyl-1,3,2-dioxaborolane 97%
  • Packaging100G
  • Price₹39803.53
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number655856
  • Product description4,4,5,5-Tetramethyl-1,3,2-dioxaborolane 97%
  • Packaging500G
  • Price₹153574.28
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L17558-14
  • Product descriptionPinacolborane, 97%
  • Packaging25g
  • Price₹15467
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L17558-06
  • Product descriptionPinacolborane, 97%
  • Packaging5g
  • Price₹4879
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) T2572 4,4,5,5-Tetramethyl-1,3,2-dioxaborolane min. 97.0 % 5G ₹3800 2022-05-26 Buy
TCI Chemicals (India) T2572 4,4,5,5-Tetramethyl-1,3,2-dioxaborolane min. 97.0 % 25G ₹13000 2022-05-26 Buy
Sigma-Aldrich(India) 655856 4,4,5,5-Tetramethyl-1,3,2-dioxaborolane 97% 5G ₹4882.08 2022-06-14 Buy
Sigma-Aldrich(India) 655856 4,4,5,5-Tetramethyl-1,3,2-dioxaborolane 97% 25G ₹12091.53 2022-06-14 Buy
Sigma-Aldrich(India) 458945 4,4,5,5-Tetramethyl-1,3,2-dioxaborolane solution 1.0?M in THF 4X25ML ₹17016.9 2022-06-14 Buy
Sigma-Aldrich(India) 458945 4,4,5,5-Tetramethyl-1,3,2-dioxaborolane solution 1.0?M in THF 100ML ₹19106.13 2022-06-14 Buy
Sigma-Aldrich(India) 655856 4,4,5,5-Tetramethyl-1,3,2-dioxaborolane 97% 100G ₹39803.53 2022-06-14 Buy
Sigma-Aldrich(India) 655856 4,4,5,5-Tetramethyl-1,3,2-dioxaborolane 97% 500G ₹153574.28 2022-06-14 Buy
ALFA India ALF-L17558-14 Pinacolborane, 97% 25g ₹15467 2022-05-26 Buy
ALFA India ALF-L17558-06 Pinacolborane, 97% 5g ₹4879 2022-05-26 Buy

Properties

Boiling point :42-43 °C50 mm Hg(lit.)
Density :0.882 g/mL at 25 °C(lit.)
vapor pressure :29-119.9hPa at 20-50℃
refractive index :n20/D 1.396(lit.)
Flash point :41 °F
storage temp. :2-8°C
solubility :Miscible with ether, dichloromethane, tetrahydrofuran and organic solvents.
form :Liquid
Specific Gravity :0.882
color :Clear colorless to light yellow
Sensitive :Air Sensitive
BRN :7802871
Stability :Air Sensitive, Hygroscopic, Moisture Sensitive
CAS DataBase Reference :25015-63-8(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3
Danger
Warning
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P233 Keep container tightly closed.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378 In case of fire: Use … for extinction.

Description

Pinacolborane is used as a precursor of boronic esters by hydroboration or coupling reactions. It acts as a monofunctional hydroborating agent. It is used in the synthesis of unsymmetrical biaryls through aromatic C-H borylation-cross-coupling sequence. It is involved in the preparation of 4,4,5,5-tetramethyl-2-thiophen-2-yl-[1,3,2]dioxaborolane by reacting with 2-iodo-thiophene. Further, it is used to prepare vinylboronates by palladium-catalyzed coupling with alkenyl triflates and iodides.

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