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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >fatty acid >(S)-(+)-KETOPINIC ACID

(S)-(+)-KETOPINIC ACID

(S)-(+)-KETOPINIC ACID Structure
  • ₹6770 - ₹18200
  • Product name: (S)-(+)-KETOPINIC ACID
  • CAS: 40724-67-2
  • MF: C10H14O3
  • MW: 182.22
  • EINECS:
  • MDL Number:MFCD08061242
  • Synonyms:(1S)-(+)-KETOPINIC ACID;(1S)-(+)-KETOPINIC ACID 97+%;(1s)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid;(S)-7,7-DIMETHYL-2-OXO-BICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID;(S)-(+)-KETOPINIC ACID;rac-(1S*,4R*)-2-Oxobornane-10-oic acid;(1S,4R)-2-Oxobornane-10-oic acid;(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]-1-carboxylic acid
3 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • ManufacturerTCI Chemicals (India)
  • Product numberK0028
  • Product description(S)-(+)-Ketopinic Acid min. 98.0 %
  • Packaging1G
  • Price₹6900
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberK0028
  • Product description(S)-(+)-Ketopinic Acid min. 98.0 %
  • Packaging5G
  • Price₹18200
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number420964
  • Product description(1S)-(+)-Ketopinic acid 99%
  • Packaging1G
  • Price₹6770
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) K0028 (S)-(+)-Ketopinic Acid min. 98.0 % 1G ₹6900 2022-05-26 Buy
TCI Chemicals (India) K0028 (S)-(+)-Ketopinic Acid min. 98.0 % 5G ₹18200 2022-05-26 Buy
Sigma-Aldrich(India) 420964 (1S)-(+)-Ketopinic acid 99% 1G ₹6770 2022-06-14 Buy

Properties

Melting point :237-239 °C(lit.)
Boiling point :313.3±25.0 °C(Predicted)
alpha :58 º (C=1 IN CHLOROFORM)
Density :1.238±0.06 g/cm3(Predicted)
refractive index :25.5 ° (C=0.65, MeOH)
storage temp. :Sealed in dry,Room Temperature
pka :3.67±0.40(Predicted)
form :powder to crystal
color :White to Almost white
optical activity :[α]23/D +58°, c = 1 in chloroform
BRN :4180005
CAS DataBase Reference :40724-67-2(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(1S)-(+)-Ketopinic acid may be used to prepare:Chiral phosphine-oxazoline ligands, which can used in asymmetric palladium-catalyzed Heck reaction of aryl or alkenyl triflates with cyclic alkenes.A chiral imino-phosphine ligand, which can be used in palladium-catalyzed asymmetric Diels–Alder reactions to prepare six-membered carbocycles.A chiral iminopyridine ligand, which can be used in copper-catalyzed Henry (nitro aldol) reaction between nitromethane ando-anisol to form the corresponding β-hydroxynitroalkane.

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