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ChemicalBook >> CAS DataBase List >>(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Structure
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE structure
CAS No.
118949-61-4
Chemical Name:
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
Synonyms
2,6-Bis((S);(S,S)-iPr-Pybox;-4-isopropyl-4,5-dihydrooxazol-2-yl);2,6-Bis[(4S)-4-isopropyl-2-oxazolin-2-yl]pyridine;(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE;2,6-BIS[(4S)-(-)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE;(-)-2,6-BIS[(4S)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE;(S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine >(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine;2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine 99%
CBNumber:
CB7298752
Molecular Formula:
C17H23N3O2
Molecular Weight:
301.38
MDL Number:
MFCD00191815
MOL File:
118949-61-4.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:38
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(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Properties

Melting point 155-157 °C(lit.)
alpha -120° (c 1.0, CH2Cl2)
Boiling point 457.1±30.0 °C(Predicted)
Density 1.23±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,2-8°C
pka 3.78±0.70(Predicted)
form crystal
color white
optical activity [α]25/D 118°, c = 0.7 in methylene chloride
BRN 5824976
FDA UNII C1A0B1BVRW

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  29309090
NFPA 704
0
2 0

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE price More Price(36)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 407151 2,6-Bis[(4S)-(?)-isopropyl-2-oxazolin-2-yl]pyridine 99% 118949-61-4 250mg $99 2024-03-01 Buy
Sigma-Aldrich 407151 2,6-Bis[(4S)-(?)-isopropyl-2-oxazolin-2-yl]pyridine 99% 118949-61-4 1g $324 2024-03-01 Buy
TCI Chemical B2218 (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine >98.0%(GC) 118949-61-4 5g $644 2024-03-01 Buy
TCI Chemical B2218 (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine >98.0%(GC) 118949-61-4 500mg $102 2024-03-01 Buy
Strem Chemicals 07-0307 (-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine, 98+% (S)-(i-Pr)-pybox 118949-61-4 250mg $148 2024-03-01 Buy
Product number Packaging Price Buy
407151 250mg $99 Buy
407151 1g $324 Buy
B2218 5g $644 Buy
B2218 500mg $102 Buy
07-0307 250mg $148 Buy

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Chemical Properties,Uses,Production

Reaction

  1. Ligand used in the dual-catalyst system for highly enantioselective conjugate cyanation of unsaturated imides.
  2. Ligand for cross-coupling reactions of iodoalkanes with alkyl zinc halides.
  3. Ligand for asymmetric 1,4-addition reactions of 1,3-dicarbonyl compounds to nitroalkenes.
  4. Ligand for asymmetric allylation of aldehydes with b-carbonyl allylstannanes.
  5. Ligand used in the enantioselective Negishi reaction of racemic secondary benzylic halides.
  6. Ligand for osmium catalyzed enantioselective transfer hydrogenation.
Reactions of 118949-61-4_1
Reactions of 118949-61-4_2

Chemical Properties

White powder or crystal or chunks

Uses

Used as a ligand to prepare novel ruthenium-pyridine-carboxylate complexes as new catalytic systems for alkene epoxidation.

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE synthesis

499-83-2
118949-61-4
Synthesis of (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE from Pyridine-2,6-dicarboxylic acid

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Preparation Products And Raw materials

Raw materials

Oxazole, 4,5-dihydro-4-(1-methylethyl)-, (4S)- (S)-(+)-2-Amino-3-methyl-1-butanol 2,6-Pyridinedicarboxylic acid chloride 2,6-Pyridinedicarbonitrile Pyridine-2,6-dicarboxylic acid
2,6-Dibromopyridine

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Preparation Products

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Suppliers

Global( 137)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 18777 58
Hi-Tech Chemistry Corp 		0519-86626038 yuhh@hitechem.com CHINA 810 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28172 58
Chongqing Chemdad Co., Ltd 		+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
Alchem Pharmtech,Inc. 		8485655694 sales@alchempharmtech.com United States 63687 58
Shaanxi Dideu Medichem Co. Ltd 		+86-29-87569262 +86-15319487004 1015@dideu.com China 2127 58
SIMAGCHEM CORP 		+86-13806087780 sale@simagchem.com China 17365 58
ANHUI WITOP BIOTECH CO., LTD 		+8615255079626 eric@witopchemical.com China 23541 58
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com China 52849 58
Labnetwork lnc. 		+86-27-50766799 +8618062016861 contact@labnetwork.com China 19987 58
Supplier Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		58
Hi-Tech Chemistry Corp 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Chongqing Chemdad Co., Ltd 		58
Alchem Pharmtech,Inc. 		58
Shaanxi Dideu Medichem Co. Ltd 		58
SIMAGCHEM CORP 		58
ANHUI WITOP BIOTECH CO., LTD 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
Labnetwork lnc. 		58

View Lastest Price from (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE pictures 2024-11-05 (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
118949-61-4
 US $0.00-0.00 / KG 1g 99% 2000tons Shaanxi Dideu Medichem Co. Ltd
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE pictures 2022-09-15 (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
118949-61-4
 US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Spectrum

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE(118949-61-4)FT-IR(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE(118949-61-4)IR

118949-61-4((S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE)Related Search:

2,6-Bis[(4S)-4-tert-butyloxazolin-2-yl]pyridine (R,R)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE 2-[(4R)-4,5-dihydro-4-(phenylMethyl)-2-oxazolyl]- Pyridine 2,6-bis[(4S,5S)-4,5-dihydro-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
(S)-5-CF3-pyrox-tBu 2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine 2,6-BIS[(4R)-4-TERT-BUTYL-2-OXAZOLIN-2YL]PYRIDINE 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
(S,S)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE 2,6-BIS(2-BENZIMIDAZOLYL)PYRIDINE (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
2,6-Pyridinedimethanol METHYL PICOLINIMIDATE PYRIDINE-2-CARBOXIMIDIC ACID ETHYL ESTER

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2,6-Bis[(4S)-4-isopropyl-2-oxazolin-2-yl]pyridine 2,6-Bis((S) -4-isopropyl-4,5-dihydrooxazol-2-yl) 2,6-Bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine,99%e.e. (-)-2,6-BIS[(4S)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE 2,6-BIS[(4S)-(-)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE 2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine ,99% (S,S)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE (S,S)-2,2μ-(2,6-Pyridinediyl)bis(4-isopropyl-2-oxazoline), (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine 2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine 99% (S, S) -2,6- bis (4-isopropyl-2-oxazoline-2-yl) pyridine 2,6-Bis((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine Pyridine, 2,6-bis[(4S)-4,5-dihydro-4-(1-methylethyl)-2-oxazolyl]- (-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine,98%,99%ee (S,S)-iPr-Pybox (4S)-4-propan-2-yl-2-[6-[(4S)-4-propan-2-yl-4,5-dihydro-1,3-oxazol-2-yl]pyridin-2-yl]-4,5-dihydro-1,3-oxazole (-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine, 98+% (S)-(i-Pr)-pybox 2,6-Bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine, 98%, (99% ee) (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine > (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine(S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine (-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine (-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine,98% 118949-61-4 Chiral Building Blocks Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis Heterocyclic Building Blocks Pyridines PyBOX Privileged Ligands organic amine BOX series Chiral Nitrogen Asymmetric Synthesis Synthetic Organic Chemistry