N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea
![N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea Structure](CAS/GIF/130-23-4.gif)
- CAS No.
- 130-23-4
- Chemical Name:
- N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea
- Synonyms
- K ACID;Euopean K Acid;EUROPEAN K-ACID;1-Amino-8-naphthol-4,6-disulfonicaci;1-amino-8-naphtho-4,6-Disulfonic acid;1 AMINO 8 HYDROXY 4:6 DISULFONIC ACID;1-AMINO-8-NAPHTHOL-4,6-DISULFONIC ACID;8-AMINO-1-NAPHTHOL-3,5-DISULFONIC ACID;4-Amino-5-naphthol-1,7-disulfonic acid;KACID(1-AMINO-8NAPHTHO-4,6-DISULFONICACID)
- CBNumber:
- CB0207416
- Molecular Formula:
- C10H9NO7S2
- Molecular Weight:
- 319.31
- MOL File:
- 130-23-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/11/7 17:05:35
Density | 1.880±0.06 g/cm3(Predicted) |
---|---|
pka | -0.83±0.40(Predicted) |
Water Solubility | 20g/L at 26.4℃ |
LogP | -2.33 |
CAS DataBase Reference | 130-23-4(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H302-H315-H319-H335 |
Precautionary statements | P261-P305+P351+P338 |
N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea Chemical Properties,Uses,Production
Chemical Properties
1-Amino-8-hydroxynaphthalene-4,6-disulfonic acid [130-23-4]. (4-amino-5-hydroxynaphthalene-1,7-disulfonic acid), K acid, C10H9NO7S2, Mr 319.3: the acid sodium salt of 1-Amino-8-hydroxynaphthalene-4,6-disulfonic acid is very soluble in water, but the acid potassium salt is less soluble and is more easily salted out. K acid couples under acid and alkaline conditions in a similar manner to H acid.
Uses
Azo dye intermediate.
Uses
The N-substituted derivatives of K acid, such as N-acetyl, N-benzoyl, N-(2,5-dichlorobenzoyl), and N-benzyl, are used as monoazo coupling components in special cases where an improvement in dye properties over the H acid analogue is demonstrable.
Production Methods
1-Aminonaphthalene-4,6,8-trisulfonic acid paste is heated with sodium hydroxide liquor in an autoclave at 170℃ for 12 h, after which the mixture is added to excess dilute hydrochloric acid. After heating to remove sulfur dioxide, the product (including ca. 8 % of the isomeric 5-amino-2-hydroxynaphthalene-4,8-disulfonic acid) is completely precipitated by cooling and is isolated in 86 % yield. Purification of crude K acid may be effected by dissolving it in aqueous alkali and filtering off the less soluble 5,2,4,8-isomer before reprecipitating.
N,N-methylenebis N'-1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl urea Preparation Products And Raw materials
Raw materials
Preparation Products
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