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Triphenylene

Triphenylene Structure
CAS No.
217-59-4
Chemical Name:
Triphenylene
Synonyms
ISOCHRYSENE;Triphenylene,98%;9,10-Benzphenanthrene;riphenylene;TRIPHENYLENE;Triphenylene 98%;Triphenylene >benzo(l)phenathrene;benzo[e]phenanthrene;benzo(1)phenanthrene
CBNumber:
CB0452742
Molecular Formula:
C18H12
Molecular Weight:
228.29
MOL File:
217-59-4.mol
MSDS File:
SDS
Modify Date:
2024/1/2 16:51:54

Triphenylene Properties

Melting point 195-198 °C(lit.)
Boiling point 438 °C(lit.)
Density 1.302
refractive index 1.5500 (estimate)
Flash point 438°C
storage temp. Sealed in dry,Room Temperature
solubility Soluble in ethanol, benzene, acetic acid, oils and chloroform.
form Crystalline Needles
color White to beige
Water Solubility 6.6ug/L(25.00 ºC)
λmax 335nm(Hexane)(lit.)
Merck 14,9740
BRN 1342908
InChIKey SLGBZMMZGDRARJ-UHFFFAOYSA-N
CAS DataBase Reference 217-59-4(CAS DataBase Reference)
IARC 3 (Vol. Sup 7, 92) 2010
NIST Chemistry Reference Triphenylene(217-59-4)
EPA Substance Registry System Triphenylene (217-59-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS09
Signal word  Danger
Hazard statements  H318-H410
Precautionary statements  P273-P280-P305+P351+P338-P391-P501
Hazard Codes  Xi,N
Risk Statements  41-50/53
Safety Statements  22-24/25-61-60-39-26
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS  YK2925000
HazardClass  9
PackingGroup 
HS Code  29029090
NFPA 704
1
3 0

Triphenylene price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) T82600 Triphenylene 98% 217-59-4 1G ₹4089.45 2022-06-14 Buy
Sigma-Aldrich(India) 45804 Triphenylene analytical standard 217-59-4 100MG ₹6678.75 2022-06-14 Buy
TCI Chemicals (India) T3267 Triphenylene (purified by sublimation) min. 98.0 % 217-59-4 200MG ₹7200 2022-05-26 Buy
TCI Chemicals (India) T3267 Triphenylene (purified by sublimation) min. 98.0 % 217-59-4 1G ₹28400 2022-05-26 Buy
TCI Chemicals (India) T0513 Triphenylene min. 96.0 % 217-59-4 100MG ₹2100 2022-05-26 Buy
Product number Packaging Price Buy
T82600 1G ₹4089.45 Buy
45804 100MG ₹6678.75 Buy
T3267 200MG ₹7200 Buy
T3267 1G ₹28400 Buy
T0513 100MG ₹2100 Buy

Triphenylene Chemical Properties,Uses,Production

Chemical Properties

white to beige crystalline needles

Uses

Triphenylene is a polycyclic aromatic hydrocarbon (PAH) that can be isolated from coal tar. Triphenylene emits fluorescence in the ultraviolet region and is a useful compound for developing semiconductor devices.

Definition

ChEBI: Triphenylene is an ortho-fused polycyclic arene consisting of four fused benzene rings.

Preparation

Triphenylene synthesis: 2-Chlorobenzoic acid(78mg, 0.5mmol), iodonium salt (236mg, 0.55mmol), palladium acetate (2.8mg, 0.0125mmol), potassium carbonate (152mg, 1.1mmol) were dissolved in 3mL of NMP solvent was heated to 110 °C and stirred for 17 hours, cooled to room temperature, extracted with ethyl acetate, washed with saturated sodium chloride solution, dried over anhydrous sodium sulfate, filtered, concentrated, and subjected to column chromatography to obtain 92 mg of triphenylene as a white solid, The yield was 80%.

General Description

Triphenylene belongs to the class of polycyclic aromatic hydrocarbons, which is commonly employed as a substrate for use as a precursor for the synthesis of graphenes, carbon nanotubes, buckminsterfullerenes as well as polycyclic heteroaromatics.

Purification Methods

Purify triphenylene by zone refining or crystallisation from EtOH or CHCl3 and sublime. [Beilstein 5 IV 2556.]

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