2-Mercaptobenzothiazole
- CAS No.
- 149-30-4
- Chemical Name:
- 2-Mercaptobenzothiazole
- Synonyms
- MBT;2-MBT;MERCAPTOBENZOTHIAZOLE;Benzo[d]thiazole-2(3H)-thione;2-BENZOTHIAZOLETHIOL;2-Benzothiazolethiol (MBT);Accelerator M;2-Merkaptobenzotiazol;benzothiazole-2-thiol;2-Mercaptobenzthiazole
- CBNumber:
- CB2853123
- Molecular Formula:
- C7H5NS2
- Molecular Weight:
- 167.25
- MOL File:
- 149-30-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/29 20:37:10
| Melting point | 177-181 °C(lit.) |
|---|---|
| Boiling point | 223°C (rough estimate) |
| Density | 1.42 |
| vapor pressure | <0.000003 hPa (25 °C) |
| refractive index | 1.6100 (estimate) |
| Flash point | 243 °C |
| storage temp. | Store below +30°C. |
| solubility | 0.12g/l |
| form | Powder |
| pka | 9.80±0.20(Predicted) |
| color | Yellow |
| PH | 7 (0.12g/l, H2O, 25℃) |
| Odor | Odorless |
| explosive limit | 15%(V) |
| Water Solubility | <0.1 g/100 mL at 19 ºC |
| Sensitive | Air Sensitive |
| λmax | 325nm(MeOH)(lit.) |
| Merck | 14,5868 |
| BRN | 119484 |
| Stability | Stable. Incompatible with strong oxidizing agents. Flammable. |
| InChIKey | YXIWHUQXZSMYRE-UHFFFAOYSA-N |
| LogP | 2.86 |
| CAS DataBase Reference | 149-30-4(CAS DataBase Reference) |
| NIST Chemistry Reference | 2-Mercaptobenzothiazole(149-30-4) |
| IARC | 2A (Vol. 115) 2018 |
| EPA Substance Registry System | 2-Mercaptobenzothiazole (149-30-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H317-H410 | |||||||||
| Precautionary statements | P261-P272-P273-P280-P302+P352-P333+P313 | |||||||||
| Hazard Codes | Xi,N | |||||||||
| Risk Statements | 43-50/53 | |||||||||
| Safety Statements | 24-37-60-61 | |||||||||
| RIDADR | UN 3077 9/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | DL6475000 | |||||||||
| F | 9-13-23 | |||||||||
| Autoignition Temperature | 465 °C | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 9 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29342020 | |||||||||
| Toxicity | LD50 orally in Rabbit: 1680 mg/kg LD50 dermal Rabbit > 7940 mg/kg | |||||||||
| NFPA 704 |
|
2-Mercaptobenzothiazole price More Price(16)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | M3302 | 2-Mercaptobenzothiazole 97% | 149-30-4 | 5G | ₹1114.98 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | M3302 | 2-Mercaptobenzothiazole 97% | 149-30-4 | 100G | ₹2284.08 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | M3302 | 2-Mercaptobenzothiazole 97% | 149-30-4 | 1KG | ₹7826.48 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.14674 | 2-Mercaptobenzothiazole for synthesis | 149-30-4 | 250G | ₹3780 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.14674 | 2-Mercaptobenzothiazole for synthesis | 149-30-4 | 1KG | ₹8960.01 | 2022-06-14 | Buy |
2-Mercaptobenzothiazole Chemical Properties,Uses,Production
Description
Mercaptobenzothiazole is a rubber chemical, an accelerant of vulcanization. It is contained in the "mercapto mix". The most frequent occupational categories are metal industry, homemakers, health services and laboratories, building industries, and shoemakers. It is also used as a corrosion inhibitor in cutting fluids or in releasing fluids used in the pottery industry.
Uses
2-Mercaptobenzothiazole (MBT) is an industrial chemical that is used principally in the manufacture of rubber.Vulcanization accelerator for type of rubber usually used in the production of household rubber gloves rather than medical rubber gloves; corrosion inhibitor in metal-working fluids, detergents, antifreeze, and photographic emulsions. In addition, 2-MBT is formed as a reaction product from some vulcanisation accelerators in elastomer production.
Definition
ChEBI: 2-Mercaptobenzothiazole is a 1,3-Benzothiazole substituted at the 2-position with a sulfanyl group. It is used as a vulcanisation accelerator in the crosslinking of rubber.
Application
2-mercaptobenzothiazole is an accelerator, retarder, and peptizer for natural and other rubber products, but is also used as a corrosion inhibitor in soluble cutting oils and antifreeze mixtures; in greases, adhesives, photographic-film emulsions; detergents; veterinary products, such as tick and flea powders and sprays.It is added to polyether polymers as a stabilizer to resist damage by air and ozone, and is a component approved in the USA in some skin medications for dogs (HSDB, 2015).
2-Mercaptobenzothiazole is also used as an intermediate in the production of pesticides such as 2-(thiocyanomethylthio)benzothiazole (Azam & Suresh, 2012), and sodium and zinc salts of 2-mercaptobenzothiazole are approved for use as pesticides by the EPA (1994).
Preparation
2-Mercaptobenzothiazole is produced by reacting aniline, carbon disulfide, and sulfur at high temperature and pressure; the product is then purified by dissolution in a base to remove the dissolved organics. Re-precipitation is achieved by the addition of acid (Kirk-Othmer, 1982; NTP, 1988).
Refined 2-mercaptobenzothiazole was produced by recrystallization from 2-mercaptobenzothiazole with industrial grade and oxidized to 2,2'-dithiobis(benzothiazole), using oxygen as an oxidant, nitric oxide as a oxygen carrier and alcohols as solvents, in a circulating fluidized reactor under one-step oxidation. 2,2'-Dithiobis(benzothiazole) was thus obtained with high purity up to 99 %, melting point at 183 oC, high yield over 98 %, through the optimization of reaction parameters as reaction time, temperature, reactants ratio, with less waste generation and emission during the production process. Alcohol solvents can be reused after purification.
http://dx.doi.org/10.14233/ajchem.2013.14030
General Description
Pale yellow to tan crystalline powder with a disagreeable odor.
Air & Water Reactions
Insoluble in water.
Fire Hazard
2-Mercaptobenzothiazole is combustible.
Safety Profile
Suspected carcinogen withexperimental carcinogenic and tumorigenic data. Poisonby ingestion and intraperitoneal routes. Experimentalteratogenic and reproductive effects. Mutation datareported. Incompatible with oxidizers. When heated todecomposition
Toxicology
2-Mercaptobenzothiazole has a sensitizing effect, and with chronic exposure (e.g., through the use of rubber gloves) it may induce skin reactions. 2-Mercapto-1-methylimidazole displays teratogenic effects in humans, and it is suspected of being a carcinogen. 6-Mercaptopurine derivatives influence cell division, and have been employed as cytostatic agents. They have been found to be teratogenic in animal studies. Methylthio-substituted triazines, which are used as herbicides, are only slightly toxic. The corresponding LD50 or LC50 values derived from animal studies are above the level of 1000 mg/ kg. Similar values have been established for a methylthiotriazinone that is the active ingredient in the herbicide Sencor.
Carcinogenicity
MBT was not mutagenic in Ames bacterial assays, but it induced chromosomal damage in mammalian cells in culture. Reproductive effects were not observed in two-generation studies of rats treated with up to 15,000 ppm MBT in the diet.
Purification Methods
Crystallise it repeatedly from 95% EtOH, or purify it by incomplete precipitation by dilute H2SO4 from a basic solution, followed by several crystallisations from acetone/H2O or *benzene. It complexes with Ag, Au, Bi, Cd, Hg, Ir, Pt, and Tl. [Beilstein 27 II 233, 27 III/IV 2709.]
2-Mercaptobenzothiazole Preparation Products And Raw materials
Raw materials
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| Yogi Dye Chem Industries | +91-9821098577 +91-9821098577 | Mumbai, India | 124 | 58 | Inquiry |
| SAMSON ORGANICS | +91-8341971897 +91-8341971897 | Hyderabad, India | 15 | 58 | Inquiry |
| Melzer Chemicals Pvt Ltd | +91-2041004800 +91-2041004800 | Maharashtra, India | 17 | 58 | Inquiry |
| Raigad Chemicals Pvt Ltd | +91-9029419019 +91-9757110215 | Maharashtra, India | 11 | 58 | Inquiry |
| Rajasthan Antibiotics Ltd | 91-11-1147666111 | New Delhi, India | 11 | 58 | Inquiry |
| Finorchem Limited (Formerly Merchem Limited) | +91-3322826195 +91-9836060001 | West Bengal, India | 11 | 58 | Inquiry |
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| Ganpati Exim Pvt Ltd | 91-22-42349100 (30 Lines) | Maharashtra, India | 24 | 58 | Inquiry |
| Napar Pharmachem Pvt., Ltd. | 91-22-65607070 | Maharashtra, India | 3 | 58 | Inquiry |
| HiMedia Laboratories | 91-22-61471919 | Maharashtra, India | 1843 | 58 | Inquiry |
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