Zinc dimethyldithiocarbamate
- CAS No.
- 137-30-4
- Chemical Name:
- Zinc dimethyldithiocarbamate
- Synonyms
- ZIRAM;ZDMC;Mexene;Rhodiacid;Accelerator PZ;Zinc bis dimethyldithiocarbamate;ZC;z75;Z 75;ZMDC
- CBNumber:
- CB1202261
- Molecular Formula:
- C6H12N2S4Zn1
- Molecular Weight:
- 305.829
- MOL File:
- 137-30-4.mol
- Modify Date:
- 2023/10/16 16:12:12
| Melting point | 248-257 °C(lit.) |
|---|---|
| Boiling point | 335.83℃[at 101 325 Pa] |
| Density | 1.66 |
| vapor pressure | <1 x 10-6 Pa |
| storage temp. | APPROX 4°C |
| solubility | DMSO (Sparingly), Methanol (Sparingly) |
| solubility | Insoluble[in water] |
| form | Powder |
| Specific Gravity | 1.71 |
| color | White |
| Odor | odorless when pure |
| Water Solubility | 0.0065 g/100 mL |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| Merck | 14,10172 |
| BRN | 3707008 |
| InChIKey | DUBNHZYBDBBJHD-UHFFFAOYSA-L |
| LogP | 1.65 at 20℃ |
| CAS DataBase Reference | 137-30-4(CAS DataBase Reference) |
| IARC | 3 (Vol. Sup 7, 53) 1991 |
| NIST Chemistry Reference | Zinc, bis(dimethylcarbamodithioato-s,s')-, (t-4)-(137-30-4) |
| EPA Substance Registry System | Ziram (137-30-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS05,GHS06,GHS08,GHS09 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H317-H318-H330-H335-H373-H410 | |||||||||
| Precautionary statements | P273-P280-P301+P312-P304+P340+P310-P305+P351+P338-P314 | |||||||||
| Hazard Codes | T+,N | |||||||||
| Risk Statements | 22-26-37-41-43-48/22-50/53 | |||||||||
| Safety Statements | 22-26-28-36/37/39-45-60-61 | |||||||||
| RIDADR | UN 2811 6.1/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | ZH0525000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29302000 | |||||||||
| Toxicity | LD50 orally in rats: 1.4 g/kg (Hodge) | |||||||||
| NFPA 704 |
|
Zinc dimethyldithiocarbamate price More Price(4)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 45708 | Ziram PESTANAL?, analytical standard | 137-30-4 | 250MG | ₹4319.18 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 329711 | Zinc dimethyldithiocarbamate 97% | 137-30-4 | 1KG | ₹15187.48 | 2022-06-14 | Buy |
| TCI Chemicals (India) | D0717 | Zinc Dimethyldithiocarbamate | 137-30-4 | 25G | ₹2200 | 2022-05-26 | Buy |
| TCI Chemicals (India) | D0717 | Zinc Dimethyldithiocarbamate | 137-30-4 | 500G | ₹6200 | 2022-05-26 | Buy |
Zinc dimethyldithiocarbamate Chemical Properties,Uses,Production
Chemical Properties
White and odorless when pure. Almost insoluble inwater; soluble in acetone, carbon disulfide, chloroform, dilute alkalies, and concentrated hydrochloric acid.
Uses
Zinc Dimethyldithiocarbamate is a member of a class of dithiocarbamates, and has been used in agriculture as a fungicide and in the rubber industry as a vulcanization accelerator.
Definition
ChEBI: A dithiocarbamate salt that is the zinc salt of dimethyldithiocarbamic acid. It is a broad-spectrum fungicide and bird and animal repellent that is also used to accelerate the vulcanisation of rubber.
Air & Water Reactions
Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Insoluble in water.
Reactivity Profile
Zinc bis dimethyldithiocarbamate is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides. Zinc bis dimethyldithiocarbamate is corrosive to iron and copper. Zinc bis dimethyldithiocarbamate is incompatible with strong oxidizing agents and acids. Zinc bis dimethyldithiocarbamate is also incompatible with mercury.
Hazard
Strong irritant to eyes and mucous membranes.
Fire Hazard
Zinc bis dimethyldithiocarbamate is combustible. Zinc bis dimethyldithiocarbamate may form explosive dust-air mixtures.
Agricultural Uses
Fungicide, Microbiocide, Animal repellant: Ziram is an agricultural fungicide registered to control fungal diseases on a wide range of crops including stone fruits, pome fruits, nut crops, vegetables and commercially grown ornamentals, and as a soil and seed treatment. In addition, it is formulated as a bird and rabbit repellent for outdoor foliar applications to ornamentals. Registered for use in EU countries . Registered for use in the U.S.
Trade name
AAPROTECT®; AAVOLEX®; AAZIRA®; ACCELERATOR®-L; ACCELERATOR® MZ® Powder; ACETO ZDED®; ACETO ZDMD®; ALCOBAM ZM®; ANCANZATE ME®; CARBAZINC®; CIRAM®; CORONA COROZATE®; COROZATE®; CUMAN®; CUMAN L®; CYMATE®; DRUPINA® 90; EPTAC-1®; FUCLASIN®; FUCLASIN® ULTRA; FUKLASIN®; FUNGOSTOP®; HERMAT ZDM®; HEXAZIR®; KARBAM WHITE®; KYPZIN®; METHASAN®; METHAZATE®; MEXENE®; MEZENE®; MILBAM®; MILBAN®; MOLURAME®; MYCRONIL®; OCTOCURE ZDM-50®; ORCHARD® BRAND ZIRAM; PERKACIT ZDMC®; POMARSOL® Z FORTE; PRODARAM®; PROKIL® Ziram; RHODIACID®; SOXINAL®-PZ; SOXINOL®-PZ; TRICARBAMIX Z®; TSIMAT®; TSIRAM® (Russian); ULTRA ZINC DMC®; VANCIDE® MZ-96; VANCIDE® 51Z Dispersion (with Zinc 2-mercaptobenzothiazolate); VANCIDE® 51Z Dispersion (with Ziram); ZERLATE®; ZINCMATE®; ZIMATE®; ZIMATE®; METHYL®; ZIRAMVIS®; ZIRASAN®; ZIRBERK®; ZIREX 90®; ZIRIDE®; ZIRTHANE®; ZITOX®
Contact allergens
Ziram is a rubber vulcanization accelerator of the dithiocarbamate group. Sensitization was reported in several patients. Ziram is also used as a fungicide and can cause contact dermatitis in agricultural workers.
Safety Profile
Poison by ingestion,intraperitoneal, and intravenous routes. Moderately toxicby inhalation. Questionable carcinogen with experimentalcarcinogenic and tumorigenic data. An experimentalteratogen. Other experimental reproductive effects.Human mutation d
Metabolic pathway
Ziram is one of the metal containing dithiocarbamates which generates dimethyldithiocarbamic acid by being cleaved in acidic conditions and in biological media. The resulting acid is conjugated with glucose and alanine in plants and with glucuronic acid in mammals. Dimethyldithiocarbamic acid is further degraded to dimethylamine and CS2. An extensive review of the properties of dithiocarbamate pesticides was published by the World Health Organisation (WHO, 1988) from which much of the following information is taken.
Purification Methods
Crystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. [Beilstein 4 III 149, 4 IV 234.]
Zinc dimethyldithiocarbamate Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Yasho Industries Ltd | +91-2262510100 +91-8291955977 | Mumbai, India | 70 | 58 | Inquiry |
| India Pesticides Limited | +91-5222653602 +91-5222653602 | Uttar Pradesh, India | 12 | 58 | Inquiry |
| SD Agro Chemicals | +91-9650182828 +91-9871331171 | Uttar Pradesh, India | 42 | 58 | Inquiry |
| AKASH PHARMA EXPORTS | +91-9388123451 +91-9846039283 | Kerela, India | 470 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| RAIGAD CHEMICALS PVT LTD | 08048953143 | Mumbai, India | 6 | 58 | Inquiry |
| Ambachem Industries | 08046031056 | Vadodara, India | 3 | 58 | Inquiry |
| Thakar Dass & Company Private Limited | 08048361356Ext 322 | Haryana, India | 4 | 58 | Inquiry |
| Sabari Crop Care Sciences (p) Ltd., | 91-44-23770345 | Tamil Nadu, India | 11 | 58 | Inquiry |
| Acme Organics Pvt Ltd | +91 120-2519970 | New Delhi, India | 1 | 58 | Inquiry |