Methyl 2-(methylamino)benzoate
- CAS No.
- 85-91-6
- Chemical Name:
- Methyl 2-(methylamino)benzoate
- Synonyms
- DIMETHYL ANTHRANILATE;METHYL N-METHYLANTHRANILATE;Methyl methanthranilate;Benzoic acid, 2-(methylamino)-, methyl ester;DIMETHYLANTHRANILAT;METHYL METHYLANTHRANILATE;2-Methylaminomethyl benzoate;Dimethylanthanilate;3-Amino-2-butenamide;FEMA 2718
- CBNumber:
- CB1755530
- Molecular Formula:
- C9H11NO2
- Molecular Weight:
- 165.19
- MOL File:
- 85-91-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/2 8:55:01
| Melting point | 17-19 °C(lit.) |
|---|---|
| Boiling point | 256 °C(lit.) |
| Density | 1.126 g/mL at 25 °C(lit.) |
| vapor pressure | 2.74Pa at 25℃ |
| refractive index |
n |
| FEMA | 2718 | METHYL N-METHYLANTHRANILATE |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| solubility | Miscible in all proportions with ethanol 96%, DMSO and diethyl ether. |
| pka | 2.80±0.10(Predicted) |
| form | <17°C Solid,>19°C Liquid |
| color | Colourless to Yellow |
| PH | 7-8 (H2O, 20℃) |
| Odor | at 100.00 %. fruity musty sweet neroli powdery phenolic wine |
| Odor Type | floral |
| Water Solubility | 329.792mg/L at 30℃ |
| JECFA Number | 1545 |
| BRN | 607217 |
| LogP | 2.81-3.08 at 25℃ |
| CAS DataBase Reference | 85-91-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzoic acid,o-(methylamino)-, methyl ester(85-91-6) |
| EPA Substance Registry System | Methyl N-methyl anthranilate (85-91-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H319 | |||||||||
| Precautionary statements | P264-P280-P305+P351+P338-P337+P313 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36-36/37/39-22 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | CB3500000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 2922498590 | |||||||||
| NFPA 704 |
|
Methyl 2-(methylamino)benzoate price More Price(11)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W271810 | Dimethyl anthranilate natural, ≥98%, FG | 85-91-6 | 1SAMPLE-K | ₹5347.55 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W271810 | Dimethyl anthranilate natural, ≥98%, FG | 85-91-6 | 100G | ₹18586.53 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W271802 | Dimethyl anthranilate ≥97%, FG | 85-91-6 | 1SAMPLE-K | ₹5141.88 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W271810 | Dimethyl anthranilate natural, ≥98%, FG | 85-91-6 | 1KG | ₹110631.5 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W271802 | Dimethyl anthranilate ≥97%, FG | 85-91-6 | 100G | ₹6852.23 | 2022-06-14 | Buy |
Methyl 2-(methylamino)benzoate Chemical Properties,Uses,Production
Description
Methyl n-methylanthranilate has an orange and mandarin peel-like odor with a musty, grape-like flavor. It is somewhat more berry-like than grape. May be prepared by methylation of methyl anthranilate or esterification of N-methylanthranilic acid.
Chemical Properties
Methyl N-Methylanthranilate is the main component of petitgrain oils from mandarin leaves and is also found in mandarin oil. It is a pale yellow, fluorescent liquid with a delicate mandarin odor. The ester can be prepared by methylation ofmethyl anthranilate. It is used in soap and cosmetic perfumes as well as in aromas, particularly for mandarin flavors.
Occurrence
Reported found in mandarin essential oil and mandarin leaves essential oil (50 to 76.5%); also reported in the oil from bulbs of Kaempferia ethelae L., in orange petitgrain, and in the oil from hyacinth flowers. Also reported found in starfruit, orange peel oil and grapefruit juice.
Uses
Methyl 2-(Methylamino)benzoate is one of many volatile components from mango cultivars.
Production Methods
Methyl N-methanthranilate is a component of mandarin and mandarin tree leaf essential oil. It is also found in oil from bulbs of Kaempferia ethelae L., hyacinth flowers, and orange petitgrain . It is synthesized by methylation of methyl anthranilate or esterification ofN-methylanthranilic acid.
Preparation
By methylation of methyl anthranilate or esterification of N-methylanthranillic acid.
Safety Profile
Poison by intravenous route. Moderately toxic by ingestion. Combustible liquid. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS.
Methyl 2-(methylamino)benzoate Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
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| SALVI CHEMICAL | +91-9321313096 +91-9321313096 | Mumbai, India | 26 | 58 | Inquiry |
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