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Chloroform-d

Chloroform-d Structure
CAS No.
865-49-6
Chemical Name:
Chloroform-d
Synonyms
deuterated chloroform;CHLOROFORM-D1;Deuteriochloroform;Deuterotrichloromethane;Methane-d, trichloro-;Chloroform-d, 99.8 atom % D, anhydrous;CHLOROFORM-D, 99.8 ATOM % D(CONTAINS 1%V/V TMS);Chloroform-d,for NMR,100.0 atom % D, packagedin 0.50 ml ampules;oroform-d;d,ChloroforM
CBNumber:
CB2103569
Molecular Formula:
CCl3D
Molecular Weight:
120.38
MOL File:
865-49-6.mol
MSDS File:
SDS
Modify Date:
2024/4/22 11:58:20

Chloroform-d Properties

Melting point −64 °C(lit.)
Boiling point 60.9 °C(lit.)
Density 1.500 g/mL at 25 °C(lit.)
vapor pressure 211 hPa (20 °C)
refractive index n20/D 1.444(lit.)
Flash point 62°C
storage temp. Store at +2°C to +8°C.
solubility Miscible with organic solvents, ethyl acetate and acetone.
form Liquid
color White to beige
Specific Gravity 1.505
Sensitive Moisture Sensitive
BRN 1697633
Exposure limits ACGIH: TWA 10 ppm
OSHA: Ceiling 50 ppm(240 mg/m3)
NIOSH: IDLH 500 ppm; STEL 2 ppm(9.78 mg/m3)
Stability Stable. Incompatible with strong bases, alkali metals, aluminium, magnesium, strong oxidizing agents.
InChIKey HEDRZPFGACZZDS-MICDWDOJSA-N
LogP 1.5-1.6 at 20-23℃ and pH9
Surface tension 72.3mN/m at 998.5mg/L and 20℃
CAS DataBase Reference 865-49-6(CAS DataBase Reference)
EPA Substance Registry System Chloroform-d (865-49-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08
Signal word  Danger
Hazard statements  H302-H315-H319-H331-H336-H351-H361d-H372
Precautionary statements  P201-P301+P312-P302+P352-P304+P340+P311-P305+P351+P338-P308+P313
Hazard Codes  Xn,T
Risk Statements  22-38-40-48/20/22-48/20-36/38-20/22-63
Safety Statements  36/37
RIDADR  UN 1888 6.1/PG 3
WGK Germany  2
HazardClass  6.1
PackingGroup  III
HS Code  28459000
Toxicity LD50 orally in Rabbit: 695 mg/kg LD50 dermal Rabbit > 3980 mg/kg
NFPA 704
1
3 1

Chloroform-d price More Price(46)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 612200 Chloroform-d 99.8 atom % D, contains 0.05?% (v/v) TMS 865-49-6 100G ₹6603.25 2022-06-14 Buy
Sigma-Aldrich(India) 530735 Chloroform-d ≥99.8 atom % D, contains 0.5?wt. % silver foil as stabilizer, 0.03?% (v/v) TMS 865-49-6 100G ₹8908.98 2022-06-14 Buy
Sigma-Aldrich(India) 570699 Chloroform-d ≥99.8 atom % D, anhydrous 865-49-6 50G ₹4730.53 2022-06-14 Buy
Sigma-Aldrich(India) 494275 Chloroform-d "100%", 99.96 atom % D, contains 0.03?% (v/v) TMS 865-49-6 10X0.75ML ₹4016.08 2022-06-14 Buy
Sigma-Aldrich(India) 530735 Chloroform-d ≥99.8 atom % D, contains 0.5?wt. % silver foil as stabilizer, 0.03?% (v/v) TMS 865-49-6 250G ₹9688.38 2022-06-14 Buy
Product number Packaging Price Buy
612200 100G ₹6603.25 Buy
530735 100G ₹8908.98 Buy
570699 50G ₹4730.53 Buy
494275 10X0.75ML ₹4016.08 Buy
530735 250G ₹9688.38 Buy

Chloroform-d Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Uses

Chloroform-d is widely used in the organic solvent for the NMR analysis.

Definition

ChEBI: Deuterated chloroform is a deuterated compound that is an isotopologue of chloroform in which the hydrogen atom is replaced with deuterium. Commonly used as a solvent in proton NMR spectroscopy. It has a role as a non-polar solvent, a NMR solvent and a NMR chemical shift reference compound. It is a deuterated compound and a member of chloromethanes.

General Description

Chloroform-d (Deuterochloroform, CDCl3), deuterated chloroform, is a 100% isotopically enriched NMR (Nuclear Magnetic Resonance) solvent. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitaive infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the in the ν1 and ν2 bands of CHCl3 and CDCl3.

Chloroform-d Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 210)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
SYNMR Chemicals Pvt Ltd +91-9341240792 +91-9353297350 Karnataka, India 13 58 Inquiry
Otto Chemie Pvt. Ltd. +91 9820041841 Mumbai, India 5873 58 Inquiry
Sisco Research Laboratories Pvt. Ltd. +91-22-4268 5800 Mumbai, India 4317 58 Inquiry
Central Drug House(P) Ltd. 91-11-49404040 New Delhi, India 6160 58 Inquiry
Triveni chemicals 08048762458 New Delhi, India 6093 58 Inquiry
Proton Laboratory Solutions 08046072525 Uttar Pradesh, India 1 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Peric Technology Co.,Ltd +86-0310-7183483 +8615030098277 China 36 58 Inquiry
Hangzhou ICH Biofarm Co., Ltd +86-0571-28186870; +undefined8613073685410 China 985 58 Inquiry
Chloroform-d, contains 0.03 v/v% TMS, 99.8+ atom % D, AcroSeal, for NMR ChloroforM-d, for NMR, 99.8 atoM % D, packaged in 0.75 Ml aMpoules CHLORAL HYDRATE SOLUTION PHE CONGO RED PAPER PHE COPPER EDETATE SOLUTION PHE GC TEMPASE 2X MASTER MIX I 2500R GC TEMPASE 2X MASTER MIX I 500R GC TEMPASE 2X MASTER MIX II 500R Chloroform-d, 99.8% Isotopic, contains 1% TMS Chloroform-d, 100% Isotopic, contains 0.03% TMS Chloroform-d, 99.8% Isotopic, contains 0.03% TMS CHLOROFORM-D, "100%", 99.96 ATOM % D, CO CHLOROFORM-D, >=99.8 ATOM % D, CONTA CHLOROFORM-D, 99.8 ATOM % D, CONTAINS 0& Chloroform-D1 with TMS (1 vol.%), deuteration degree min. 99.5 % for NMR spectroscopy (stabilized with silver) MagniSolv Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv Chloroform-D1 0.03 vol.% TMS, deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy MagniSolv Chloroform-D1 deuteration degree min. 99.96% for NMR spectroscopy MagniSolv Chloroform-d, Isotopic Chloroform - D1, Stabilized with silver Chloroform - D1, 0.03 vol.% TMS, Stabilized with silver Chloroform-d, 100.0 atom % D Trichloro(2H)methane trichloro-deuterio-methane CHLOROFORM-D >99.95 (ATOM % D) STAB. CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.75ML) CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.25ML) CHLOROFORM-D, 99.8 ATOM % D, STABILIZEDWITH 0.5 WT% SILVER FOIL (CONTAINS 0.03%( CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D) CONTAINS 0.03% V/V TMS(1PK=10 X 0.75ML CHLOROFORM-D, 99.9 ATOM % D (CONTAINS 0.03% V/V TMS) CHLOROFORM-D, 99.8 ATOM % D (CONTAINS 0.03% V/V TMS) CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D) CONTAINS 0.03% V/V TMS Chloroform-D,IsotopicPurity>99Atom%D Chloroform-d, isotopic purity Chloroform-d,100%D(Isotopic),contains0.03%v/vTMS Chloroform-d,99.8%(Isotopic),contains0.03%v/vTMS Chloroform-d, 100 atom % D, packaged in 0.75 ml ampules, for NMR Chloroform-d, 100.0 atom % D, for NMR Chloroform-d, 100.0 atom % D, packaged in 0.50 ml ampules, for NMR Chloroform-d, 99.6+ atom % D, for NMR Chloroform-d, 99.8 atom % D, contains 1 v/v% TMS, for NMR Chloroform-d, 99.8 atom % D, for NMR Chloroform-d, 99.8 atom % D, packaged in 0.75 ml ampules, for NMR Chloroform-d, 99.8 atom % D, packaged in 1 ml ampules, for NMR Chloroform-d, 99.8 atom % D, stabilized with silver foil, for NMR Chloroform-d, 99.8% D, stabilized with silver foil, 1 v/v% TMS, for NMR Chloroform-d, 99.8+ atom % D, contains 0.03 v/v% TMS, for NMR Chloroform-d, 99.8+% D, stab. with silver foil, 0.03 v/v% TMS, for NMR ChloroformD>99.96%10x0.75ml ChloroformD>99.96%+0.03%tms ChloroformD>99.8%+0.03%tms ChloroformD>99.8%10x0.75ml ChloroformD>99.8%5x10ml ChloroformD>99.96%10x0.6ml ChloroformD>99.96% ChloroformD>99.96%10x0.75ml(+0.03%tms) Chloroform-d,for NMR,99.8+ atom % D, contains0.03 v/v% TMS