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Barium acetate

Barium acetate Structure
CAS No.
543-80-6
Chemical Name:
Barium acetate
Synonyms
octanbarnaty;BARIUM ACETATE;BariumAcetateGr;Barium diacetate;BariumAcetateA.R.;Bariumacetate,99%;BARIUM ACETATE 99%;BARIUM ACETATE XTL;BARIUM ACETATE, ACS;BariumAcetateAcs/Ar
CBNumber:
CB2450535
Molecular Formula:
C4H6BaO4
Molecular Weight:
255.42
MOL File:
543-80-6.mol
MSDS File:
SDS
Modify Date:
2023/8/31 16:33:09

Barium acetate Properties

Melting point 450°C
Density 2.46
vapor pressure 15.7hPa at 25℃
storage temp. Store at +5°C to +30°C.
solubility 720g/l
form Solid
Specific Gravity 2.468
color White
PH 7-8.5 (20℃, 5%)
Odor Slight acetic acid odor
PH Range 7 - 8.5 at 50 g/l at 25 °C
Water Solubility soluble
Merck 14,965
BRN 3693411
Exposure limits ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
Stability Stable. Incompatible with strong oxidizing agents, acids.
InChIKey ITHZDDVSAWDQPZ-UHFFFAOYSA-L
LogP -0.17
CAS DataBase Reference 543-80-6(CAS DataBase Reference)
EPA Substance Registry System Barium acetate (543-80-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302+H332
Precautionary statements  P261-P264-P270-P271-P301+P312-P304+P340+P312
Hazard Codes  Xn
Risk Statements  20/22
Safety Statements  28-28A
RIDADR  1564
WGK Germany  1
RTECS  AF4550000
TSCA  No
HS Code  2915 29 00
HazardClass  6.1
PackingGroup  III
Toxicity LD50 orally in Rabbit: 921 mg/kg
NFPA 704
1
2 0

Barium acetate price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 255912 Barium acetate 99.999% trace metals basis 543-80-6 10G ₹8605.88 2022-06-14 Buy
Sigma-Aldrich(India) 255912 Barium acetate 99.999% trace metals basis 543-80-6 50G ₹32063.65 2022-06-14 Buy
Sigma-Aldrich(India) 243671 Barium acetate ACS reagent, 99% 543-80-6 100G ₹4600.63 2022-06-14 Buy
Sigma-Aldrich(India) 243671 Barium acetate ACS reagent, 99% 543-80-6 500G ₹9634.25 2022-06-14 Buy
Sigma-Aldrich(India) 1.01704 Barium acetate for analysis EMSURE? ACS 543-80-6 500G ₹14790 2022-06-14 Buy
Product number Packaging Price Buy
255912 10G ₹8605.88 Buy
255912 50G ₹32063.65 Buy
243671 100G ₹4600.63 Buy
243671 500G ₹9634.25 Buy
1.01704 500G ₹14790 Buy

Barium acetate Chemical Properties,Uses,Production

Description

Barium acetate (Ba(C2H3O2)2) is the salt of barium (II) and acetic acid.

Chemical Properties

Barium acetate is a white powder, which is highly soluble: at 0 °C, 55.8 g of barium acetate can be dissolved in 100 g of water. It decomposes upon heating into barium carbonate .

Physical properties

White powdery solid; density 2.47g/cm3; decomposes on heating; highly soluble in water (55.8g /100g at 0°C), sparingly soluble in methanol (~1.43 g per liter).

Uses

Barium acetate is used as a mordant for printing textile fabrics, for drying paints and varnishes and in lubricating oil. In chemistry, it is used in the preparation of other acetates; and as a catalyst in organic synthesis.

Preparation

Barium acetate is generally produced by the reaction of acetic acid with barium carbonate :
BaCO3 + 2 CH3COOH → (CH3COO)2Ba + CO2 + H2O
The reaction is performed in solution and the barium acetate crystallizes out. Alternatively, barium sulfide can be used :
BaS + 2 CH3COOH → (CH3COO)2Ba +H2S
Again, the solvent is evaporated off and the barium acetate crystallized.

Reactions

When heated in air, barium acetate decomposes to the carbonate. It reacts with acids: reaction with sulfuric acid, hydrochloric acid and nitric acid give the sulfate, chloride and nitrate respectively.

General Description

Barium acetate is the barium salt of acetic acid.

Hazard

The salt or its aqueous solution is highly toxic. LD10 (oral) rabbit: 236 mg/kg; LD10 (subcutaneous) rabbit: 96 mg/kg. See Barium.

Safety Profile

Poison via ingestion, intravenous, and subcutaneous routes. When heated to decomposition it emits acrid smoke and fumes. See also BARIUM COMPOUNDS.

Purification Methods

Crystallise the salt twice from anhydrous acetic acid and dry it under vacuum for 24hours at 100o. [Beilstein 2 I 49, 2 II 117, 2 III 192, 2 IV 114.]

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