2,3-Butanedione monoxime
- CAS No.
- 57-71-6
- Chemical Name:
- 2,3-Butanedione monoxime
- Synonyms
- DAM;BDM;DIACETYL MONOXIME;3-(Hydroxyimino)butan-2-one;NSC 660;NSC 116103;BIACETYL MONOXIME;Biacethylmonoxime;Diacety1monoxime;DIACETYL MONOOXIME
- CBNumber:
- CB2488015
- Molecular Formula:
- C4H7NO2
- Molecular Weight:
- 101.1
- MOL File:
- 57-71-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/5/18 11:31:09
| Melting point | 75-78 °C(lit.) |
|---|---|
| Boiling point | 185-186 °C(lit.) |
| Density | 1.2085 (rough estimate) |
| refractive index | 1.4340 (estimate) |
| Flash point | 185-186°C |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| pka | 9.32±0.10(Predicted) |
| form | Crystalline Powder |
| color | White to almost white |
| Odor | Odorless |
| Water Solubility | 5 g/100 mL (20 ºC) |
| Sensitive | Hygroscopic |
| BRN | 605582 |
| Stability | Stable. Incompatible with strong oxidizing agents. |
| InChIKey | FSEUPUDHEBLWJY-HWKANZROSA-N |
| CAS DataBase Reference | 57-71-6(CAS DataBase Reference) |
| NIST Chemistry Reference | 2,3-Butanedione, monooxime(57-71-6) |
| EPA Substance Registry System | Diacetyl monooxime (57-71-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H335-H332-H302-H319-H312-H315 | |||||||||
| Precautionary statements | P261-P271-P304+P340-P312-P264-P280-P302+P352-P321-P332+P313-P362-P264-P270-P301+P312-P330-P501-P280-P302+P352-P312-P322-P363-P501-P264-P280-P305+P351+P338-P337+P313P | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 36/37/38-20/21/22 | |||||||||
| Safety Statements | 22-24/25-36/37/39-26 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | EK3150000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29280090 | |||||||||
| Toxicity | LD50 ipr-mus: 51 mg/kg JPMSAE 53,1143,64 | |||||||||
| NFPA 704 |
|
2,3-Butanedione monoxime price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | B0753 | 2,3-Butanedione monoxime ≥98% | 57-71-6 | 25G | ₹4580 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | B0753 | 2,3-Butanedione monoxime ≥98% | 57-71-6 | 100G | ₹5830 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | B0753 | 2,3-Butanedione monoxime ≥98% | 57-71-6 | 500G | ₹20940 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | B0753 | 2,3-Butanedione monoxime ≥98% | 57-71-6 | 1KG | ₹57840 | 2022-06-14 | Buy |
| Sigma-Aldrich | 31550 | 2,3-Butanedione monoxime for spectrophotometric det. of urea, ≥99.0% | 57-71-6 | 25G | ₹3583.08 | 2022-06-14 | Buy |
2,3-Butanedione monoxime Chemical Properties,Uses,Production
Chemical Properties
white crystals
Uses
2,3-Butanedione monoxime is a reversible inhibitor of myosin ATPase. It is also used as a reagent for colorimetric determination of urea.
Preparation
Approximately 9 moles of ethyl nitrite are required for this preparation. The literature indicates a suitable apparatus for its generation.
In a well-ventilated hood, to freshly dried and distilled methyl ethyl ketone (620 gm, 8.6 moles) is added, with stirring, 40 ml of cone, hydrochloric acid. The temperature of the reaction system is raised to 40°C. Without delay the addition of ethyl nitrite is initiated and the flow of the reagent is regulated to such a rate that the reaction temperature never exceeds 55°C. About 1.5 hr are required for the addition. The ethanol formed in the reaction, as well as unreacted methyl ethyl ketone, is separated by distillation until the pot temperature just reaches 90°C.
The product is separated from the residue by rapid steam distillation. Virtually all of the product will be found in the first 5 liters of the distillate. The distillate is saturated with 1.5 kg of sodium chloride and cooled to 0°C. The product, which precipitates out, is filtered off. If necessary, the product may be recrystallized from water to afford 500 gm (58%), m.p. 76.5°C.
General Description
Cream-colored powder.
Air & Water Reactions
Soluble in water.
Reactivity Profile
2,3-Butanedione monoxime may react violently during vacuum distillation above 130 pascals.
Fire Hazard
Flash point data for 2,3-Butanedione monoxime are not available, but 2,3-Butanedione monoxime is probably combustible.
Safety Profile
Poison by intraperitoneal route. When heated to decomposition it emits toxic vapors of NOx.
2,3-Butanedione monoxime Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| ORGANO FINE CHEMICALS | +91-91-22-42128300 +91-2242128300 | Mumbai, India | 258 | 58 | Inquiry |
| Arnish Laborates Pvt Ltd | +91 7208475595 | Maharashtra, India | 187 | 58 | Inquiry |
| Deltamike Specialty Products Private Limited | +91-9820180482 +91-9820180482 | Maharashtra, India | 18 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| Suchmi Organics | +91-9765490787 +91-9545532082 | Maharashtra, India | 16 | 58 | Inquiry |
| Belami Fine Chemicals Pvt. Ltd. | 91-22-22051092 | Maharashtra, India | 89 | 58 | Inquiry |
| ORGANO FINE CHEMICALS | +91-22-42128300 | Mumbai, India | 202 | 58 | Inquiry |
| Finar Limited | 91-2717-616717 | Gujarat, India | 39 | 58 | Inquiry |
| Techno Pharmchem | 91-9818265860 | Delhi, India | 173 | 58 | Inquiry |
| Unisource Chemicals Private Limited. | 91-22-22052250 | Maharashtra, India | 43 | 58 | Inquiry |
57-71-6(2,3-Butanedione monoxime)Related Search:
1of4
chevron_right