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Lithium azide

Lithium azide Structure
CAS No.
19597-69-4
Chemical Name:
Lithium azide
Synonyms
LITHIUM AZIDE;ution in water;Lthium triazide;lithium triazide;LiN3 (20% in H2O);lithiumazide(li(n3));lithium azide solution;ithium azide, pure, 20% soL;LithiuM Azide (Aqueous Solution);LITHIUM AZIDE ISO 9001:2015 REACH
CBNumber:
CB2739539
Molecular Formula:
LiN3
Molecular Weight:
48.96
MOL File:
19597-69-4.mol
Modify Date:
2024/7/10 13:17:07

Lithium azide Properties

Melting point decomposes at 115–298℃ [CRC10]
Boiling point 103 °C
Density 1.088 g/mL at 25 °C
solubility soluble in Water
form Liquid
color Clear colorless
Water Solubility g/100g H2O: 61.3 (0°C), 67.2 (20°C), 86.6 (60°C) [LAN05]
EPA Substance Registry System Lithium azide (Li(N3)) (19597-69-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06
Signal word  Danger
Hazard statements  H300+H330-H311
Precautionary statements  P280-P301+P310+P330-P302+P352+P312-P304+P340+P310
Hazard Codes  T+
Risk Statements  26/27/28-32
Safety Statements  23-36/37/39-45-36/37-28
RIDADR  UN 3287 6.1/PG 2
WGK Germany  3
HazardClass  4.1
HS Code  28500090

Lithium azide price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 480525 Lithium azide solution 20?wt. % in H2O 19597-69-4 25G ₹18305.08 2022-06-14 Buy
Sigma-Aldrich(India) 480525 Lithium azide solution 20?wt. % in H2O 19597-69-4 100G ₹31955.4 2022-06-14 Buy
ottokemi L 1507 Lithium azide, 20% w/w, solution in water 19597-69-4 100gm ₹15903 2022-05-26 Buy
Product number Packaging Price Buy
480525 25G ₹18305.08 Buy
480525 100G ₹31955.4 Buy
L 1507 100gm ₹15903 Buy

Lithium azide Chemical Properties,Uses,Production

Chemical Properties

clear colorless solution

Preparation

With gentle warming, NaN3 (91.30 g.) and LiSO4-H2O (1.41 g.) are dissolved in 7 ml. of H2O. Then 35 ml. of 96% alcohol is added with shaking. The solution is filtered after ten minutes and the residue of Na2SO4 and LiSO4 washed with alcohol. The filtrate and wash solutions are evaporated on a water bath and dried in a drying oven at 80°C. This crude product is digested at 35°C for two minutes with 10 ml. of 96% alcohol and filtered, and the solution is dried as described above. The yield is 0.6 g of 99.5% Lithium azide.

Purification Methods

Digest ~1g with 15mL of 96% EtOH at 35o, filter and dry it in air at temperatures below 80o. Store it in a cool place and treat it as potentially explosive. Its solubility in H2O is 66.4% at16o, and 20.26% at16o in EtOH. [Hofmann-Bang Acta Chem Scand 11 581 1957, Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 581 1963.]

Lithium azide Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 64)Suppliers
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Innovative Labs +91-9885794886 +91-9885794886 Telangana, India 219 58 Inquiry
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LITHIUM AZIDE lithiumazide(li(n3)) lithium triazide LITHIUM AZIDE, 20 WT. % SOLUTION IN WATE R Lithium azide, 20% solution in water, pure lithium azide solution Lithium azide,pure,20% solution in water Lithium azide, moistened with ca 10% methanol,99% LithiuM azide, 20 wt.% solution in H2O LithiuM Azide (Aqueous Solution) LithiuM azide solution 20 wt. % in H2O Lthium triazide Lithium azide, 20% Solution in Water ithium azide, pure, 20% soL ution in water LITHIUM AZIDE ISO 9001:2015 REACH Lithium azide, 20% w/w, solution in water LITHIUM AZIDE SOLUTION 20% W/W IN WATER LiN3 (20% in H2O) 19597-69-4 LiN3 C-X Bond Formation (Non-Halogen) Synthetic Reagents Azidation/Diazo Transfer Inorganics Azide SourcesMetal and Ceramic Science Azidation/Diazo TransferChemical Ligation Click Chemistry C-X Bond Formation (Non-Halogen) Lithium Salts Salts Synthetic Reagents