Nickel(II) nitrate hexahydrate
- CAS No.
- 13478-00-7
- Chemical Name:
- Nickel(II) nitrate hexahydrate
- Synonyms
- NICKEL NITRATE;NICKEL NITRATE HEXAHYDRATE;NICKEL(II) NITRATE;Nitric acid nickel(II) salt hexahydrate;Nickel (II) nitrate hexahydrate≥ 97% (Titration);NickelNitrateAr;Nickelousnitrate,N;Nickel Nitrate (Ous);NICKEL (OUS) NITRATE;NICKEL NITRATE, HYDROUS
- CBNumber:
- CB3115275
- Molecular Formula:
- H12N2NiO12
- Molecular Weight:
- 290.79
- MOL File:
- 13478-00-7.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/3/28 16:55:20
| Melting point | 56 °C(lit.) |
|---|---|
| Boiling point | 137 °C |
| Density | 2.05 g/mL at 25 °C(lit.) |
| Flash point | 137°C |
| storage temp. | Store at +5°C to +30°C. |
| solubility | 940g/l |
| form | flakes |
| color | Green to blue |
| Specific Gravity | 2.05 |
| PH | 5 (50g/l, H2O, 20℃) |
| Water Solubility | 238.5 g/100 mL (20 ºC) |
| Sensitive | Hygroscopic |
| Merck | 14,6513 |
| Exposure limits |
ACGIH: TWA 0.1 mg/m3 NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| Stability | Stable. Strong oxidizer. Incompatible with reducing agents. |
| InChIKey | AOPCKOPZYFFEDA-UHFFFAOYSA-N |
| CAS DataBase Reference | 13478-00-7(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |      GHS03,GHS05,GHS07,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H272-H302+H332-H315-H317-H318-H334-H341-H350-H360-H372-H410 | |||||||||
| Precautionary statements | P201-P210-P273-P280-P305+P351+P338+P310-P308+P313 | |||||||||
| Hazard Codes | O,T,Xi,Xn,N | |||||||||
| Risk Statements | 45-8-22-43-40-68-50/53-48/23-42/43-41-38-20/22-61-49 | |||||||||
| Safety Statements | 53-17-36/37-45-61-60 | |||||||||
| RIDADR | UN 2725 5.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | QR7300000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 2834 29 20 | |||||||||
| HazardClass | 5.1 | |||||||||
| PackingGroup | III | |||||||||
| Toxicity | LD50 orally in Rabbit: 1620 mg/kg | |||||||||
| NFPA 704 |
|
Nickel(II) nitrate hexahydrate price More Price(38)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 72253 | Nickel(II) nitrate hexahydrate purum p.a., crystallized, ≥97.0% (KT) | 13478-00-7 | 250G | ₹4481.55 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 72253 | Nickel(II) nitrate hexahydrate purum p.a., crystallized, ≥97.0% (KT) | 13478-00-7 | 1KG | ₹10532.73 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 72252 | Nickel(II) nitrate hexahydrate puriss. p.a., ≥98.5% (KT) | 13478-00-7 | 50G | ₹11626.05 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 72252 | Nickel(II) nitrate hexahydrate puriss. p.a., ≥98.5% (KT) | 13478-00-7 | 250G | ₹24832.55 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 244074 | Nickel(II) nitrate hexahydrate crystals or chunks | 13478-00-7 | 500G | ₹2998.53 | 2022-06-14 | Buy |
Nickel(II) nitrate hexahydrate Chemical Properties,Uses,Production
Description
Nickel (II) nitrate hexahydrate appears as green crystals and substantially soluble in water. It is stable, a strong oxidiser, and incompatible with reducing agents. It has wide industrial applications in nickel plating as catalysts and is indirectly associated with other industries of nickel alloy manufacturers, nickel miners, smelters and refiners, nickel platers, and exposure to alloys, for example, in coinage.
Chemical Properties
Green crystal
Uses
Nickel plating, manufacturing of ceramic colorsNickel(II) nitrate hexahydrate is used as a precursor in the manufacturing of other nickel salts and supported nickel catalysts. It finds use as a catalyst in organic synthesis. Further it is used in electroplating and as a mordent in textile dyeing. It is a precursor for preparing nickel sulfide-reduced graphene oxide (RGO) composite powders with high initial capacities and good cycling performance. It can be employed in the preparation of nickel and nickel oxide nanocrystals impregnated O-MWCNTs (oxygen-functionalized multi-walled carbon nanotubes) with potential applications in semiconductor industries. It finds use in improving cycling stability ad rate capability of Li2MnO3.
Preparation
Emerald green crystals of the hexahydrate Ni(N03)2?6H20 crystallize
from aqueous solutions at room temperature. These are isomorphous with the corresponding
cobalt(II) salt containing the regular octahedral [Ni(H20)6]2+ ions with Ni-O distances = 2.03 A. The tetrahydrate crystallize above 54° and the dihydrate above 85.4°.
The pale green anhydrous nitrate can be obtained by dehydration of the hydrate with
dinitrogen pentoxide in fuming nitric acid or by the liquid phase reaction of dinitrogen
tetroxide with nickel carbonyl [the gas phase reaction gives the nitrite Ni(N02)2]
Ni(CO)4+2N2O4 -* Ni(N03)2+2NO+4CO
The first product of this latter rather violent reaction is the adduct Ni(NO3)2N2O4 from
which the nitrogen tetroxide is removed by heating in vacuo. It can also be prepared by the
reaction of dinitrogen tetroxide-ethyl acetate mixtures with nickel(II) chloride. The infrared
spectrum shows it to be a typical covalent nitrate. It is involatile and decomposes upon
heating in nitrogen to give the nitrite Ni(NO2)2 above 260°.
General Description
Nickel(II) nitrate hexahydrate (Ni(NO3)2.6H2O) is a hydrated nickel(II) salt. Its thermal degradation has been investigated by thermogravimetric methods under quasi-isothermal conditions.
Safety Profile
Confirmed carcinogen. Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx. See also NICKEL(II) NITRATE.
Purification Methods
Crystallise it from water (3.3g/mL) by partial evaporation in a desiccator. Store it in a desiccator as it is deliquescent.
Nickel(II) nitrate hexahydrate Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
| Yogi Dye Chem Industries | +91-9821098577 +91-9821098577 | Mumbai, India | 124 | 58 | Inquiry |
| S.V ENTERPRISES | +919322701159 | Mumbai, India | 150 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| Kronox Lab Sciences Pvt Ltd | +91-9313231074 +91-9313231074 | Gujarat, India | 240 | 58 | Inquiry |
| Dhara Industries | +91-9322395199 +91-9322395199 | Mumbai, India | 190 | 58 | Inquiry |
| Sajan Overseas Pvt Ltd | +91-9825074205 +91-9825074205 | Gujarat, India | 38 | 58 | Inquiry |
| Rivashaa Agrotech Biopharma Pvt. Ltd. | +91-26463395 +91-7926462688 | Gujarat, India | 1615 | 58 | Inquiry |
| Insta Chemi Private Limited | 08048958481 | Uttar Pradesh, India | 122 | 58 | Inquiry |
| Hemal Impex | 08048986288 | Gujarat, India | 15 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| GLR Innovations | 58 |
| Yogi Dye Chem Industries | 58 |
| S.V ENTERPRISES | 58 |
| JSK Chemicals | 58 |
| Kronox Lab Sciences Pvt Ltd | 58 |
| Dhara Industries | 58 |
| Sajan Overseas Pvt Ltd | 58 |
| Rivashaa Agrotech Biopharma Pvt. Ltd. | 58 |
| Insta Chemi Private Limited | 58 |
| Hemal Impex | 58 |
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