TOLYLFLUANID
![TOLYLFLUANID Structure](CAS/GIF/731-27-1.gif)
- CAS No.
- 731-27-1
- Chemical Name:
- TOLYLFLUANID
- Synonyms
- B-49854;bay5212;BAY 5212;bay49854;bay5712a;EUPAREN M;ELVARON M;BAY 49854;BAY 5712a;kue13183b
- CBNumber:
- CB3438572
- Molecular Formula:
- C10H13Cl2FN2O2S2
- Molecular Weight:
- 347.26
- MOL File:
- 731-27-1.mol
- Modify Date:
- 2023/5/25 18:01:06
Melting point | 96°C |
---|---|
Boiling point | 93℃ |
Density | 1.5132 (rough estimate) |
vapor pressure | 2 x 10-5 Pa (20 °C) |
refractive index | 1.6000 (estimate) |
storage temp. | -20°C |
solubility | soluble in DMSO, Methanol |
Colour Index | 45430 |
Water Solubility | 0.9 mg l-1 (20 °C) |
pka | -5.06±0.50(Predicted) |
BRN | 2949607 |
LogP | 3.900 |
EPA Substance Registry System | Tolylfluanid (731-27-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() GHS06,GHS08,GHS09 |
---|---|
Signal word | Danger |
Hazard statements | H315-H317-H319-H330-H335-H372-H400 |
Precautionary statements | P273-P280-P302+P352-P304+P340+P310-P305+P351+P338-P314 |
Hazard Codes | T,N,T+ |
Risk Statements | 23-36/37/38-43-48/20-50/53-50-48/23-26 |
Safety Statements | 24-26-37-38-45-60-61-63-36/37/39-28 |
RIDADR | 2588 |
WGK Germany | 3 |
RTECS | WO6560000 |
HazardClass | 6.1(b) |
PackingGroup | III |
TOLYLFLUANID price More Price(2)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 90619 | Tolylfluanid certified reference material, TraceCERT? | 731-27-1 | 50MG | ₹19138.6 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 32060 | Tolylfluanid PESTANAL?, analytical standard | 731-27-1 | 250MG | ₹7458.43 | 2022-06-14 | Buy |
TOLYLFLUANID Chemical Properties,Uses,Production
Uses
Tolylfluanid is used to control a wide range of fungal diseases on apples, grapes, strawberries and other fruit and storage diseases on many crops.
Definition
ChEBI: A member of the class of sulfamides that is dichlofluanid in which the hydrogen at the para position of the phenyl group is replaced by a methyl group. A fungicide first marketed in 1971 and used in the cultivation of fruit and vegetables, as ell as in wood preservatives, it is no longer approved for use in the European Union.
Metabolic pathway
Tolylfluanid contains an unstable dichlorofluoromethylthio (sulfenyl) moiety that has been shown to undergo rapid hydrolytic and metabolic degradation to dimethylaminosulfotoluidide (2). By analogy with captan, presumably the dichlorofluoromethylthio moiety can be transferred to the sulfur atoms of cellular thiols such as cysteine and glutathione. Thus, in the presence of thiols tolylfluanid is probably cleaved at the N-S bond to form thiophosgene or its monofluoro analogue (3) and other gaseous products such as hydrogen sulfide, hydrogen chloride and carbonyl sulfide. Thiophosgene or its monofluoro analogue is rapidly hydrolysed by water. The dichlorofluoromethylthio group and thiophosgene may be intermediates in the formation of addition products, for example addition to cysteine affords thiazolidine-2-thione-4-carboxylica cid (4). A thiazolidine derivative of glutathione may also be formed. The main metabolic reactions in all media were cleavage of the N-S bond to give dimethylaminosulfotoluidide (2) followed by hydroxylation of the phenyl ring and oxidation of the methyl substituent on the phenyl ring. Glucoside conjugates were detected in plants and the cysteine adduct, thiazolidine-2- thione-4-carboxylic acid (4), was formed in rats.
TOLYLFLUANID Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | China | 8673 | 58 | Inquiry |
Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | China | 49739 | 58 | Inquiry |
SUZHOU SENFEIDA CHEMICAL CO.,LTD | +86-0512-83500002 +8615195660023 | China | 23053 | 58 | Inquiry |
LEAPCHEM CO., LTD. | +86-852-30606658 | China | 43348 | 58 | Inquiry |
Shanghai Acmec Biochemical Technology Co., Ltd. | +undefined18621343501 | China | 33350 | 58 | Inquiry |
LGC Standards | +44 (0)20 8943 8480 | United Kingdom | 6495 | 0 | Inquiry |
United States Biological | 800.520.3011 or 781.639.5092 | United States | 6256 | 80 | Inquiry |
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd | 15229059051 | China | 9976 | 58 | Inquiry |