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TOLYLFLUANID

TOLYLFLUANID Structure
CAS No.
731-27-1
Chemical Name:
TOLYLFLUANID
Synonyms
B-49854;bay5212;BAY 5212;bay49854;bay5712a;EUPAREN M;ELVARON M;BAY 49854;BAY 5712a;kue13183b
CBNumber:
CB3438572
Molecular Formula:
C10H13Cl2FN2O2S2
Molecular Weight:
347.26
MOL File:
731-27-1.mol
Modify Date:
2023/5/25 18:01:06
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TOLYLFLUANID Properties

Melting point 96°C
Boiling point 93℃
Density 1.5132 (rough estimate)
vapor pressure 2 x 10-5 Pa (20 °C)
refractive index 1.6000 (estimate)
storage temp. -20°C
solubility soluble in DMSO, Methanol
Colour Index 45430
Water Solubility 0.9 mg l-1 (20 °C)
pka -5.06±0.50(Predicted)
BRN 2949607
LogP 3.900
EPA Substance Registry System Tolylfluanid (731-27-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H315-H317-H319-H330-H335-H372-H400
Precautionary statements  P273-P280-P302+P352-P304+P340+P310-P305+P351+P338-P314
Hazard Codes  T,N,T+
Risk Statements  23-36/37/38-43-48/20-50/53-50-48/23-26
Safety Statements  24-26-37-38-45-60-61-63-36/37/39-28
RIDADR  2588
WGK Germany  3
RTECS  WO6560000
HazardClass  6.1(b)
PackingGroup  III

TOLYLFLUANID price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 90619 Tolylfluanid certified reference material, TraceCERT? 731-27-1 50MG ₹19138.6 2022-06-14 Buy
Sigma-Aldrich(India) 32060 Tolylfluanid PESTANAL?, analytical standard 731-27-1 250MG ₹7458.43 2022-06-14 Buy
Product number Packaging Price Buy
90619 50MG ₹19138.6 Buy
32060 250MG ₹7458.43 Buy

TOLYLFLUANID Chemical Properties,Uses,Production

Uses

Tolylfluanid is used to control a wide range of fungal diseases on apples, grapes, strawberries and other fruit and storage diseases on many crops.

Definition

ChEBI: A member of the class of sulfamides that is dichlofluanid in which the hydrogen at the para position of the phenyl group is replaced by a methyl group. A fungicide first marketed in 1971 and used in the cultivation of fruit and vegetables, as ell as in wood preservatives, it is no longer approved for use in the European Union.

Metabolic pathway

Tolylfluanid contains an unstable dichlorofluoromethylthio (sulfenyl) moiety that has been shown to undergo rapid hydrolytic and metabolic degradation to dimethylaminosulfotoluidide (2). By analogy with captan, presumably the dichlorofluoromethylthio moiety can be transferred to the sulfur atoms of cellular thiols such as cysteine and glutathione. Thus, in the presence of thiols tolylfluanid is probably cleaved at the N-S bond to form thiophosgene or its monofluoro analogue (3) and other gaseous products such as hydrogen sulfide, hydrogen chloride and carbonyl sulfide. Thiophosgene or its monofluoro analogue is rapidly hydrolysed by water. The dichlorofluoromethylthio group and thiophosgene may be intermediates in the formation of addition products, for example addition to cysteine affords thiazolidine-2-thione-4-carboxylica cid (4). A thiazolidine derivative of glutathione may also be formed. The main metabolic reactions in all media were cleavage of the N-S bond to give dimethylaminosulfotoluidide (2) followed by hydroxylation of the phenyl ring and oxidation of the methyl substituent on the phenyl ring. Glucoside conjugates were detected in plants and the cysteine adduct, thiazolidine-2- thione-4-carboxylic acid (4), was formed in rats.

TOLYLFLUANID Preparation Products And Raw materials

Raw materials

Preparation Products

TOLYLFLUANID Suppliers

Global( 54)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
Shaanxi Didu New Materials Co. Ltd +86-89586680 +86-13289823923 China 8673 58 Inquiry
Hangzhou MolCore BioPharmatech Co.,Ltd. +86-057181025280; +8617767106207 China 49739 58 Inquiry
SUZHOU SENFEIDA CHEMICAL CO.,LTD +86-0512-83500002 +8615195660023 China 23053 58 Inquiry
LEAPCHEM CO., LTD. +86-852-30606658 China 43348 58 Inquiry
Shanghai Acmec Biochemical Technology Co., Ltd. +undefined18621343501 China 33350 58 Inquiry
LGC Standards +44 (0)20 8943 8480 United Kingdom 6495 0 Inquiry
United States Biological 800.520.3011 or 781.639.5092 United States 6256 80 Inquiry
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd 15229059051 China 9976 58 Inquiry
Supplier Advantage
CLEARSYNTH LABS LTD. 58
Chongqing Chemdad Co., Ltd 58
Shaanxi Didu New Materials Co. Ltd 58
Hangzhou MolCore BioPharmatech Co.,Ltd. 58
SUZHOU SENFEIDA CHEMICAL CO.,LTD 58
LEAPCHEM CO., LTD. 58
Shanghai Acmec Biochemical Technology Co., Ltd. 58
LGC Standards 0
United States Biological 80
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd 58

731-27-1(TOLYLFLUANID)Related Search:

Tralkoxydim Permethrin Tau-fluvalinate Hexaconazole DICHLOFLUANID
N,N-Dimethylsulfamide Dichloromonofluoromethane Dimethyl sulfide TOLYLFLUANID SOLUTION 100UG/ML IN TOLUENE 1ML TOLYLFLUANID SOLUTION 100UG/ML IN ACETONITRILE 1ML
TOLYLFLUANID Sulfamide DMST
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N,N-DIMETHYL-N'-TOLYL-N'-(DICHLOROFLUOROMETHYLTHIO) SULFAMIDE TOLYFLUANID TOLYLFLUANID N-dichlorofluoromethylthio-N,N-dimethyl-N-p-tolylsulphamide dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide T0LYLFLUANID, 250MG, NEAT TOLYLFLUANID PESTANAL, 250 MG N-Dichlorfluormethylthio-N',N'-dimethyl-N-p-tolylsulfamid Tolylfluanid=Tolyfluanid tolylfluanid (bsi,iso) EUPARENMULTI N-(dichlorofluoromethyl)thio-N',N'-dimethyl- N-(p-tolyl)-Sulfamide n-((dichlorofluoromethyl)thio)-n',n'-dimethyl-n-(p-tolyl)-sulfamid tolylfluanid (ISO) dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide 1,1-DICHLORO-N-[(DIMETHYLAMINO)SULFONYL]-1-FLUORO-N-(4-METHYLPHENYL)METHANESULFENAMIDE B-49854 EUPAREN M EUPAREN M(R) ELVARON M 1,1-dichloro-n-((dimethylamino)sulfonyl)-1-fluoro-n-(4-methanesulfanenamid 1,1-Dichloro-N-((dimethylamino)sulfonyl)-1-fluoro-N-(4-methylphenyl)methanesulfonamide BAY 49854 BAY 5212 BAY 5712a bay49854 bay5212 bay5712a BAYER 49854 Bayer 5712a bayer49854 N,N-Dimethyl-N'-(4-tolyl)-N'-(dichlorfluormethylthio)-sulfamid N,N-Dimethyl-N-(4-tolyl)-N-(dichlorofluor-methylthio)-sulfamide n,n-dimethyl-n’-(4-tolyl)-n’-(dichlorfluormethylthio)-sulfamid n’-dichlorofluoromethylthio-n,n-dimethyl-n’-(4-tolyl)sulfamide N'-Dichlorofluoromethylthio-N,N-dimethyl-N'-(4-tolyl)sulfamide Sulfamide, N-((dichlorofluoromethyl)thio)-N',N'-dimethyl-N-(p-tolyl)- Tolyfluanide Tolylfluanide dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide,tolylfluanid (ISO) bayer5712a Dichlofluanid-methyl KUE 13183b kue13183b Methanesulfanenamide, 1,1-dichloro-N-((dimethylamino)sulfonyl)-1-fluoro-N-(4-methylphenyl)- Methanesulfenamide, 1,1-dichloro-N-[(dimethylamino)sulfonyl]-1-fluoro-N-(4-methylphenyl)- methanesulfenamide,1,1-dichloro-n-[(dimethylamino)sulfonyl]-1-fluoro-n-(4-meth n-((dichlorofluoromethyl)thio)-n’,n’-dimethyl-n-(p-tolyl)-sulfamid N-([Dichloro(fluoro)methyl]sulfanyl)-N',N'-dimethyl-N-(4-methylphenyl)sulfamide N-(dichlorofluoromethyl)thio-N’,N’-dimethyl-N-(p-tolyl)-Sulfamide [[dichloro(fluoro)methyl]thio]-(dimethylsulfamoyl)-(4-methylphenyl)amine N-[dichloro(fluoro)methyl]sulfanyl-N-(dimethylsulfamoyl)-4-methylaniline N-[dichloro(fluoro)methyl]sulfanyl-N-(dimethylsulfamoyl)-4-methyl-aniline Tolylfluanid 250mg [731-27-1] Tolylfluanid Solution, 100ppm 1,1-Dichloro-N-((Dimethylamino)Sulfonyl)-1-Fluor Tolylfluanid Standard Tolylfluanid Solution, 1000ppm Euparen M(TM) Tolylfluanide @100 μg/mL in MeOH