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Bromophenol Blue

Bromophenol Blue Structure
CAS No.
115-39-9
Chemical Name:
Bromophenol Blue
Synonyms
BPB;BROMPHENOL BLUE;BROMOPHENOL BLUE INDICATOR;ALBUTEST;NSC 7818;Aalbutest;Bromophnol blue;Bromophemol blue;BROMOPHENOL BLUE;bleudebromophenol
CBNumber:
CB3492457
Molecular Formula:
C19H10Br4O5S
Molecular Weight:
669.96
MOL File:
115-39-9.mol
Modify Date:
2024/8/14 18:30:21

Bromophenol Blue Properties

Melting point 273 °C
Density 0.954 g/mL at 20 °C
Flash point 58 °C
storage temp. Store at RT.
solubility methanol: soluble10mg/mL
form Solid
pka 3.85(at 25℃)
Boiling point 605.6±55.0 °C(Predicted)
color Reddish-violet
PH Range 3(Yellow)-4.6(Blue) 6(yellow)-7.6(blue)
PH pH : 3.0~4.6
Odor Odorless
Water Solubility Freely soluble in NaOH. Soluble in sodium hydroxide, alcohol, benzene, and acetic acid. Slightly soluble in water.
λmax 598nm, 592nm, 436nm, 422nm, 273nm
Merck 14,1444
BRN 61698
Stability Stable. Incompatible with strong oxidizing agents.
Major Application Nanotechnology, semiconductors, sol-gel matrix, fuel cells, display device, paints, packaging system, diapers, contact lens, determining nucleic acids, in saliva, water alkalinity, preserving genetic materials, detecting bacteria, vaginal infection test method
InChIKey UDSAIICHUKSCKT-UHFFFAOYSA-N
LogP 6.880 (est)
CAS DataBase Reference 115-39-9(CAS DataBase Reference)
EPA Substance Registry System Bromophenol blue (115-39-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07,GHS08
Signal word  Danger
Hazard statements  H226-H319-H335+H336-H340-H360-H372-H373
Precautionary statements  P201-P202-P210-P233-P240-P241+P242+P243-P260-P264-P270-P271-P280-P303+P361+P353-P304+P340+P312-P305+P351+P338+P337+P313-P308+P313-P403+P233-P405-P501
Hazard Codes  T,Xn
Risk Statements  61-20/21-36-36/37/38-20/21/22
Safety Statements  53-45-24/25-22-36-26
RIDADR  UN 2265 3/PG 3
WGK Germany  3
RTECS  SJ7453000
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29349990
NFPA 704
1
1 0

Bromophenol Blue price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 114391 Bromophenol Blue ACS reagent 115-39-9 5G ₹2879.45 2022-06-14 Buy
Sigma-Aldrich B0126 Bromophenol Blue 115-39-9 25G ₹8995.58 2022-06-14 Buy
Sigma-Aldrich(India) B0126 Bromophenol Blue 115-39-9 25G ₹8995.58 2022-06-14 Buy
Sigma-Aldrich(India) 114391 Bromophenol Blue ACS reagent 115-39-9 25G ₹3052.65 2022-06-14 Buy
Sigma-Aldrich(India) 1.08122 Bromophenol blue indicator ACS,Reag. Ph Eur 115-39-9 5G ₹7899.99 2022-06-14 Buy
Product number Packaging Price Buy
114391 5G ₹2879.45 Buy
B0126 25G ₹8995.58 Buy
B0126 25G ₹8995.58 Buy
114391 25G ₹3052.65 Buy
1.08122 5G ₹7899.99 Buy

Bromophenol Blue Chemical Properties,Uses,Production

Chemical Properties

Bromophenol Blue is pink or red powder, soluble in ethanol, benzene, ether and other organic solvents, slightly soluble in water, the aqueous solution is yellow, and blue-purple in alkaline solution. It is mainly used as an acid-base indicator, the pH discoloration range is 3.0 to 4.6, and the color changes from yellow to green to blue-violet.

Definition

ChEBI: Bromophenol blue is 3H-2,1-Benzoxathiole 1,1-dioxide in which both of the hydrogens at position 3 have been substituted by 3,5-dibromo-4-hydroxyphenyl groups. It is used as a laboratory indicator, changing from yellow below pH 3 to purple at pH 4.6, and as a size marker for monitoring the progress of agarose gel and polyacrylamide gel electrophoresis. It has also been used as an industrial dye. It has a role as a two-colour indicator, an acid-base indicator and a dye. It is a sultone, an arenesulfonate ester, a 2,1-benzoxathiole, a member of phenols and an organobromine compound.

Preparation

Bromophenol Blue is prepared by slow addition of excess bromine to a hot solution of phenolsulfonphthalein in glacial acetic acid.
Synthesis steps: Dissolve phenol red in glacial acetic acid, add a solution of bromine in glacial acetic acid with stirring, pour into 60°C hot water after stirring for a few minutes, cool to room temperature, and place overnight. Filter, wash the filter cake with glacial acetic acid and benzene in turn, and air dry to obtain bromophenol blue.

Purification Methods

Crystallise the dye from *C6H6 or Me2CO/AcOH, and dry it in air. It is an indicator: at pH 3.0 it is yellow and it is purple at pH 4.6. [Beilstein 19/3 V 458.]

Bromophenol Blue Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 531)Suppliers
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Arnish Laborates Pvt Ltd +91 7208475595 Maharashtra, India 187 58 Inquiry
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Oster Chemical & Pharmaceutical Works Pvt. Ltd. 91-33-23508577 Kolkata, India 101 58 Inquiry
BROMOPHENOL BLUE INDICATOR, REAG. PH. EU R. BROMOPHENOL BLUE SOLUTION, ~1% IN N,N-DI METHYLFORMAMIDE BROMOPHENOL BLUE, A.C.S. REAGENT BROMOPHENOL BLUE SOLUTION, 100 ML BROMOPHENOL BLUE SOLUTION ACID-BASE & bleudebromophenol bromophenolblue(0.1%inwater) tetrabromophenolsulfonphthalein Bromophenol blue, indicator, ACS Bromophenol blue, solution 0,04%, indicator Bromophenol Blue p.a. Aalbutest Bromophemol blue BroMophenol Blue, Electrophoresis Grade BroMophenol Blue, conforM to ACS, pure 5GR BroMophenol Blue, indicator, pure 25GR (0.1% in ca. 50% Ethanol) [for Titration] BroMophenol Blue  BROMOPHENOL BLUE INDICATOR PH 3.0-4.6 AC BroMophenol blue (BPB) Bromophnol blue CHROMOCULT COLIFORM PETRI 55MM (3X30) MAY-GRUNWALD'S EOSIN METHYLENE BLUE SOLN TRYPTONE YEAST EXTRACT 3X10PETRI 55MM Bromophenol Blue, Free Acid Bromophenol blue, For ACS analysis Bromophenol Blue, Pure BROMOPHENOL BLUE BROMOPHENOL BLUE ETHANOL(50) BROMOPHENOL BLUE LOADING SOLUTION BROMOPHENOL BLUE SULFONE FORM BROMOPHENOL BLUE TS BROMPHENOL BLUE SULTONE FORM A,A-BIS(3,5-DIBROMO-4-HYDROXYPHENYL)-A-HYDROXY-O-TOLUENESULFONIC ACID G-SULTONE ALBUTEST ALPHA,ALPHA-BIS(3,5-DIBROMO-4-HYDROXYPHENOL)-ALPHA-HYDROXY-O-TOLUENESULFONIC ACID 3',3'',5'5''-TETRABROMOPHENOL-SULFONTHALEIN 3',3'',5',5''-TETRABROMOPHENOLSULFOPHTHALEIN 3',3'',5',5''-TETRABROMOPHENOLSULFONEPHTHALEIN 3',3'',5',5''-TETRABROMOPHENOLSULFONPHTHALEIN 3,3',5,5'-TETRABROMOPHENOLSULFONPHTHALEIN 3,3-BIS(3,5-DIBROMO-4-HYDROXYPHENYL)-2,1LAMBDA6-BENZOXATHIOLE-1,1(3H)-DIONE TETRABROMOPHENOLSULFOPHTHALEIN TETRABROMOPHENOLTETRABROMOSULFONEPHTHALEIN NSC 7818 PHENOL, 4,4'-(1,1-DIOXIDO-3H-2,1-BENZOXATHIOL-3-YLIDENE)BIS[2,6-DIBROMO- PHENOL, 4,4'-(3H-2,1-BENZOXATHIOL-3-YLIDENE)BIS[2,6-DIBROMO-, S,S-DIOXIDE 4,4’-(3h-2,1-benzoxathiol-3-ylidene)bis(2,6-dibromophenol)s,s-dioxide BROMOPHENOL BLUE, FOR MICROSCOPY BROMOPHENOL BLUE PH 3.0-4.6 ACS BromophenolBlueIndicatorGr BromophenolBlue,SultoneForm BromophenolBlueIndicatorSolution 3',3'',5',5''-Tetrabromophenolsulfonephthaleine BROMOPHENOL BLUE, REAG. α,α-Bis(3,5-dibromo-4-hydroxy-phenyl) α-Hydroxy-o-toluenesulfonic acid, γ-sultone Bromophenol Blue, 0.1% in water, pure