Mannitol hexanitrate,wetted with not less than 40% water,or mixture of alcohol and water,by mass

Mannitol hexanitrate,wetted with not less than 40% water,or mixture of alcohol and water,by mass Structure
CAS No.
15825-70-4
Chemical Name:
Mannitol hexanitrate,wetted with not less than 40% water,or mixture of alcohol and water,by mass
Synonyms
Maxitate;Nitromannitol;MannitylNitrate;Hexanitromannite;hexanitromannitol;mannitol hexanitrate;mannitol hexanitrate nitromannite;D-Mannitol, 1,2,3,4,5,6-hexanitrate;[(2R,3R,4R,5R)-1,2,4,5,6-pentanitrooxyhexan-3-yl] nitrate;nitric acid [(1R,2R,3R)-1-[(1R)-1,2-dinitrooxyethyl]-2,3,4-trinitrooxy-butyl] ester
CBNumber:
CB3851959
Molecular Formula:
C6H8N6O18
Molecular Weight:
452.16
MOL File:
15825-70-4.mol
Modify Date:
2023/7/18 8:29:11

Mannitol hexanitrate,wetted with not less than 40% water,or mixture of alcohol and water,by mass Properties

Melting point 106-108°
Boiling point 559.71°C (rough estimate)
Density 1.8000
refractive index 1.7500 (estimate)
CAS DataBase Reference 15825-70-4
EPA Substance Registry System D-Mannitol, hexanitrate (15825-70-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS01
Signal word  Danger
Hazard statements  H201
Precautionary statements  P210-P230-P240-P250-P280-P370+P380-P372-P373-P401-P501
Hazard Codes  E
Risk Statements  3
Safety Statements  35
RIDADR  0133
HazardClass  1.1D
PackingGroup  II

Mannitol hexanitrate,wetted with not less than 40% water,or mixture of alcohol and water,by mass Chemical Properties,Uses,Production

Chemical Properties

Colorless crystals.Soluble in alcohol, acetone, ether; insoluble in water.

Uses

Explosive cap ingredient, medicine (admixed with at least 10 parts of carbohydrate).

General Description

Colorless needles. Used for filling blasting caps.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Nitroalkanes, such as Mannitol hexanitrate,wetted with not less than 40% water,or mixture of alcohol and water,by mass, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive. Nitroalkanes are insoluble in water.

Hazard

Dangerous fire and explosion risk; an initiating explosive.

Health Hazard

Fire may produce irritating, corrosive and/or toxic gases.

Fire Hazard

MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO.

Safety Profile

Moderately toxic by ingestion and inhalation causing a fall in blood pressure that may result in weakness, headache, and dizziness. Chronic exposure may produce methemoglobinemia with cyanosis. A powerful explosive sensitive to shock or heat. Upon decomposition it emits toxic fumes of NOx. See also NITRATES and EXPLOSIVES, HIGH.

Purification Methods

The hexanitrate crystallises from EtOH or dilute EtOH as silky white needles. EXPLOSIVE (on detonation). [Hayward J Am Chem Soc 73 1974 1951, Patterson & Todd J Chem Soc 2876 1929, Beilstein 1 IV 2841.]

Mannitol hexanitrate,wetted with not less than 40% water,or mixture of alcohol and water,by mass Preparation Products And Raw materials

Raw materials

Preparation Products

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Nitromannitol [(2R,3R,4R,5R)-1,2,4,5,6-pentanitrooxyhexan-3-yl] nitrate nitric acid [(1R,2R,3R)-1-[(1R)-1,2-dinitrooxyethyl]-2,3,4-trinitrooxy-butyl] ester Hexanitromannite Mannitol hexanitrate,wetted with not less than 40% water,or mixture of alcohol and water,by mass mannitol hexanitrate MannitylNitrate hexanitromannitol mannitol hexanitrate nitromannite Maxitate D-Mannitol, 1,2,3,4,5,6-hexanitrate 15825-70-4 C6H8ONO26