Cyclopropanecarboxaldehyde
- CAS No.
- 1489-69-6
- Chemical Name:
- Cyclopropanecarboxaldehyde
- Synonyms
- Cyclopropanecarbaldehyde;Formylcyclopropane;Cyclopropylmethanal;Cyclopropylcarboxaldehyde;1-Cyclopropanecarbaldehyde;Cyclopropanecarboxyaldehyde;Cyclopropane-1-carbaldehyde;opropanecarbaL;RARECHEM AK ML 0578;Cyclopropanecarboxal
- CBNumber:
- CB4132338
- Molecular Formula:
- C4H6O
- Molecular Weight:
- 70.09
- MOL File:
- 1489-69-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/4/24 17:21:45
Boiling point | 98-101 °C (lit.) |
---|---|
Density | 0.938 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | 45 °F |
storage temp. | 2-8°C |
solubility | soluble in Chloroform |
form | clear liquid |
color | Colorless to Light orange to Yellow |
Water Solubility | Soluble in water. |
Sensitive | Air Sensitive |
BRN | 906781 |
Stability | Volatile |
InChIKey | JMYVMOUINOAAPA-UHFFFAOYSA-N |
CAS DataBase Reference | 1489-69-6(CAS DataBase Reference) |
NIST Chemistry Reference | Cyclopropanecarboxaldehyde(1489-69-6) |
EPA Substance Registry System | Cyclopropanecarboxaldehyde (1489-69-6) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS05 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H225-H314 | |||||||||
Precautionary statements | P210-P233-P240-P280-P303+P361+P353-P305+P351+P338 | |||||||||
Hazard Codes | F,C | |||||||||
Risk Statements | 11-34 | |||||||||
Safety Statements | 16-26-36/37/39-45 | |||||||||
RIDADR | UN 2924 3/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | GZ1005000 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29122990 | |||||||||
NFPA 704 |
|
Cyclopropanecarboxaldehyde price More Price(6)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 272213 | Cyclopropanecarboxaldehyde 98% | 1489-69-6 | 1G | ₹1890 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 272213 | Cyclopropanecarboxaldehyde 98% | 1489-69-6 | 5G | ₹7510 | 2022-06-14 | Buy |
ALFA India | ALF-L14931-06 | Cyclopropanecarboxaldehyde, 98% | 1489-69-6 | 5g | ₹5885 | 2022-05-26 | Buy |
ALFA India | ALF-L14931-03 | Cyclopropanecarboxaldehyde, 98% | 1489-69-6 | 1g | ₹2676 | 2022-05-26 | Buy |
TCI Chemicals (India) | C1707 | Cyclopropanecarboxaldehyde min. 98.0 % | 1489-69-6 | 1G | ₹2900 | 2022-05-26 | Buy |
Cyclopropanecarboxaldehyde Chemical Properties,Uses,Production
Chemical Properties
clear colorless liquid
Uses
Cyclopropanecarboxaldehyde reacts with Grignard or organolithium reagents to give the expected secondary alcohols. These are susceptible to ring opening in the presence of HBr, providing stereoselective access to homoallylic bromides. It is also used in the synthesis of eta(2)-enonenickel complexes by reacting with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) and to prepare a cyclopropylidene tetralone which underwent an enantioselective palladium-catalyzed [3+2] TMM cycloaddition providing a chiral spiro-fused cyclopentene.
Application
Cyclopropanecarboxaldehyde is a reagent in the preparation of N-alkylphenylalaninamides of pyridinylphenyland oxobipyridinylamines as human GPR 142 agonists for potential use as anti-diabetic agents and the cytochrome P 450 inhibition.
Preparation
Cyclopropanecarboxaldehyde is prepared by reaction of cyclopropylmethanol. The reaction needs reagent pyridinium chlorochromate and solvent CH2Cl2 with other condition of ambient temperature for 3 hours. The yield is about 60%.
Cyclopropanecarboxaldehyde Preparation Products And Raw materials
Raw materials
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