Scandium trifluoromethanesulfonate
- CAS No.
- 144026-79-9
- Chemical Name:
- Scandium trifluoromethanesulfonate
- Synonyms
- Sc(OTf)3;Scandium tris(trifluoromethanesulfonate);SCANDIUM TRIFLATE;SCANDIUM(III) TRIFLUOROMETHANESULFONATE;SCANDIUM(III) TRIFLATE;PS-SC(OTF)2;SC(O3SCF3)3;SCANDIUM TRIFLATE RESIN;SCANDIUM(III) TRIFLUOROMETHANESULPHONATE;TRIFLUOROMETHANESULFONIC ACID SCANDIUM(III) SALT
- CBNumber:
- CB4256487
- Molecular Formula:
- C3F9O9S3Sc
- Molecular Weight:
- 492.16
- MOL File:
- 144026-79-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/7/26 16:38:32
| Melting point | >300 °C |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Water (Slightly) |
| form | Powder |
| color | White |
| Water Solubility | Soluble in water, alcohol and acetonitrile. |
| Sensitive | Hygroscopic |
| Hydrolytic Sensitivity | 6: forms irreversible hydrate |
| BRN | 8510151 |
| Stability | hygroscopic |
| InChI | InChI=1S/3CHF3O3S.Sc/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3 |
| InChIKey | HZXJVDYQRYYYOR-UHFFFAOYSA-K |
| SMILES | C(F)(S([O-])(=O)=O)(F)F.C(F)(F)(F)S([O-])(=O)=O.C(F)(F)(F)S([O-])(=O)=O.[Sc+3] |
| CAS DataBase Reference | 144026-79-9(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P305+P351+P338-P280a-P304+P340-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 3-10 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | No | |||||||||
| HS Code | 28469099 | |||||||||
| NFPA 704 |
|
Scandium trifluoromethanesulfonate price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 418218 | Scandium(III) triflate 99% | 144026-79-9 | 250MG | ₹1948.5 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 483354 | Scandium(III) triflate 99.995% trace metals basis | 144026-79-9 | 1G | ₹4026.9 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 418218 | Scandium(III) triflate 99% | 144026-79-9 | 1G | ₹4026.9 | 2022-06-14 | Buy |
| Sigma-Aldrich | 418218 | Scandium(III) triflate 99% | 144026-79-9 | 5G | ₹17439.08 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 418218 | Scandium(III) triflate 99% | 144026-79-9 | 5G | ₹17439.08 | 2022-06-14 | Buy |
Scandium trifluoromethanesulfonate Chemical Properties,Uses,Production
Description
Scandium trifluoromethanesulfonate, commonly called Scandium(III) triflate, is a chemical compound with formula Sc(SO3CF3)3, a salt consisting of scandium cations Sc3+ and triflate SO3CF3? anions.
Scandium(III) triflate is an extremely active, efficient, recoverable and reusable acylation catalyst. Its an important catalyst for the Friedel-Crafts acylation, Diels-Alder reactions and other carbon-carbon bond-forming reactions. It also stereochemically catalyzes the radical polymerization of acrylates. Scandium(III) triflate complex of (4′S,5′S)-2,6-bis[4′-(triisopropylsilyl)oxymethyl-5′-phenyl-1′,3′-oxazolin-2′-yl]pyridine has been employed as catalyst for the asymmetric Friedel-Crafts reaction between substituted indoles and methyl (E)-2-oxo-4-aryl-3-butenoates.
Chemical Properties
White powder
Uses
Scandium(III) trifluoromethanesulfonate is widely used as a catalyst in hydrothiolation, selective two-electron reduction of oxygen by ferrocene derivatives and vinylogous Fridel-crafts alkylation of indoles and pyrrole in water. It is involved in the Mukaiyama aldol addition and stereochemically catalyzes the radical polymerization of acrylates. It acts as a Lewis acid catalyst and used in the synthesis of bullvalone via a stabilized sulfur ylide.
Application
Scandium(III) triflate was used as a catalyst in:
Hydrothiolation reaction of aromatic and aliphatic thiols.
Selective two-electron reduction of O2 by ferrocene derivatives.
Vinylogous Friedel-Crafts alkylation of indoles and pyrroles in water.
Synthesis of β-cyanoketones.
Combination with triethylsilane to reductively open functionalized pyranoside rings.
The key steps of synthesis of bullvalone via a stabilized sulfur ylide.
Preparation
Scandium triflate (Scandium trifluoromethanesulfonate) can be prepared from the corresponding oxide (Sc2O3) and aqueous trifluoromethanesulfonic acid (TfOH). After filtration and concentration of the clear aqueous solution in vacuo, the resulting hydrated salt is dried in vacuo (<1 mmHg) at 200?°C for 40 h to afford the anhydrous triflate stored over P2O5.
Reactions
- Water tolerant Lewis acid.
- Commonly used in a range of Lewis acid catalyzed reactions.
- Efficient metal source for Lewis acid catalyzed asymmetric reactions.
- Catalyzes Friedel-Crafts alkylation, acylation and related reactions.
- Catalyzes various domino- and multi-component processes.
- Catalyzes electrophilic additions of alpha-diazoesters with ketones.
- Catalyzes carbon insertion reactions.
General Description
Scandium(III) triflate is an extremely active, efficient, recoverable and reusable acylation catalyst. Its an important catalyst for the Friedel-Crafts acylation, Diels-Alder reactions and other carbon-carbon bond-forming reactions. It also stereochemically catalyzes the radical polymerization of acrylates. Scandium(III) triflate complex of (4′S,5′S)-2,6-bis[4′-(triisopropylsilyl)oxymethyl-5′-phenyl-1′,3′-oxazolin-2′-yl]pyridine has been employed as catalyst for the asymmetric Friedel-Crafts reaction between substituted indoles and methyl (E)-2-oxo-4-aryl-3-butenoates.
Scandium trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| SAGAR LIFE SCIENCES PVT LTD | +91-8770359041 +91-8770359041 | Gujarat, India | 79 | 58 | Inquiry |
| Sadasivarao g | +91 9515157878 | Hyderabad, India | 107 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| Survival Technologies Pvt Ltd | +91 (22) 4212-8221 | New Delhi, India | 290 | 50 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Sisco Research Laboratories Pvt. Ltd. | +91-22-4268 5800 | Mumbai, India | 4317 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| SAGAR LIFE SCIENCES PVT LTD | 58 |
| Sadasivarao g | 58 |
| JSK Chemicals | 58 |
| Survival Technologies Pvt Ltd | 50 |
| CHEMSWORTH | 30 |
| CLEARSYNTH LABS LTD. | 58 |
| A.J Chemicals | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Sisco Research Laboratories Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
144026-79-9(Scandium trifluoromethanesulfonate)Related Search:
1of4
chevron_right