ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Polyamines >4,4'-Methylenebis(N,N-dimethylaniline)

4,4'-Methylenebis(N,N-dimethylaniline)

CAS No.: 101-61-1

Chemical Name:: 4,4'-Methylenebis(N,N-dimethylaniline)

Synonyms: michler’sbase;Michler's base;NCI-C01990;TETRA BASE;Methane Bas;ARNOLDS BASE;METHANE BASE;methylenebase;bazemichlerova;Methylene base

CBNumber:: CB4327020

Molecular Formula:: C17H22N2

Molecular Weight:: 254.37

MOL File:: 101-61-1.mol

MSDS File:: SDS

Modify Date:: 2024/4/24 17:21:45

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4,4'-Methylenebis(N,N-dimethylaniline) Properties

Melting point	88-89 °C(lit.)
Boiling point	390 °C
Density	1.0344 (rough estimate)
refractive index	1.5794 (estimate)
Flash point	178 °C
storage temp.	Sealed in dry,Room Temperature
pka	5.57±0.12(Predicted)
form	Crystalline Powder, Crystals and/or Chunks
color	Off-white or light gray or beige-brown
Water Solubility	Insoluble
Merck	14,6176
BRN	479956
Stability	Stable. Combustible. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides, active metals, oxides, chlorates, halogenated compounds, iron chloride, nitro acompounds, peroxides, strong ammonia solution, sulfides, vinyl polymers.
InChIKey	JNRLEMMIVRBKJE-UHFFFAOYSA-N
CAS DataBase Reference	101-61-1(CAS DataBase Reference)
IARC	2B (Vol. 27, Sup 7, 99) 2010
NIST Chemistry Reference	Benzenamine, 4,4'-methylenebis[N,N-dimethyl-(101-61-1)
EPA Substance Registry System	4,4'-Methylenebis[N,N-dimethylaniline] (101-61-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS08,GHS09

Signal word

Danger

Hazard statements

H350-H410

Precautionary statements

P202-P273-P280-P308+P313-P391-P405

Hazard Codes

T,N,Xi

Risk Statements

45-50/53

Safety Statements

53-45-60-61

RIDADR

UN 3077 9/PG 3

WGK Germany

RTECS

BY5250000

Hazard Note

Harmful/Irritant

TSCA

Yes

HazardClass

6.1(b)

PackingGroup

III

HS Code

29215990

NFPA 704

	1
2		0

4,4'-Methylenebis(N,N-dimethylaniline) price More Price(10)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	M44451	4,4′-Methylenebis(N,N-dimethylaniline) 98%	101-61-1	5G	₹3842.88	2022-06-14	Buy
Sigma-Aldrich(India)	M44451	4,4′-Methylenebis(N,N-dimethylaniline) 98%	101-61-1	100G	₹15284.9	2022-06-14	Buy
Sigma-Aldrich(India)	M44451	4,4′-Methylenebis(N,N-dimethylaniline) 98%	101-61-1	500G	₹61172.08	2022-06-14	Buy
ALFA India	ALF-A18466-30	4,4'-Methylenebis(N,N-dimethylaniline), 98+%	101-61-1	250g	₹5977	2022-05-26	Buy
ALFA India	ALF-A18466-18	4,4'-Methylenebis(N,N-dimethylaniline), 98+%	101-61-1	50g	₹2220	2022-05-26	Buy

Product number	Packaging	Price	Buy
M44451	5G	₹3842.88	Buy
M44451	100G	₹15284.9	Buy
M44451	500G	₹61172.08	Buy
ALF-A18466-30	250g	₹5977	Buy
ALF-A18466-18	50g	₹2220	Buy

4,4'-Methylenebis(N,N-dimethylaniline) Chemical Properties,Uses,Production

Chemical Properties

yellow to tan crystals

Uses

4,4'-Methylenebis(N,N-dimethylaniline)is used as a chemical intermediate in the manufacture of dyes and for its hydrochloric salt and is also used as an analytical reagent in the determination of lead.

General Description

Yellowish glistening leaflets or plates or tan crystals. Weak odor. Sublimes without decomposition.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4,4'-Methylenebis(N,N-dimethylaniline) is incompatible with acids, acid chlorides, acid anhydrides and oxidizing agents. 4,4'-Methylenebis(N,N-dimethylaniline) is also incompatible with active metals, potassium, oxides, chlorates, halogenated compounds, iron chloride, nitro compounds, peroxides, strong ammonia solutions, sulfides and vinyl polymers .

Fire Hazard

4,4'-Methylenebis(N,N-dimethylaniline) is combustible.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic by ingestion. Mutation data reported. A flammable liquid. When heated to decomposition it emits toxic fumes of NOx.

Potential Exposure

4,40 -methylenebis(N,N-dimethyl) benzenamine is used as an intermediate in dye manufacture and as an analytical reagent in the determination of lead.

Carcinogenicity

4,4′-Methylenebis(N,N-dimethyl)benzenamine is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

Shipping

UN3259 Amines, solid, corrosive, n.o.s, or Polyamines, solid, corrosive, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Purification Methods

Crystallise the base from EtOH (2mL/g) or 95% EtOH (ca 12mL/g). It sublimes on heating. [Beilstein 13 IV 390.]

Incompatibilities

Strong acids, oxidizers, acid chlorides; acid anhydrides.

4,4'-Methylenebis(N,N-dimethylaniline) Preparation Products And Raw materials

Raw materials

Formic acid Paraformaldehyde N,N-Dimethylaniline Acetic acid 4-(DIMETHYLAMINO)BENZYL ALCOHOL

N-Methylformanilide Dimethyl sulfoxide

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Preparation Products

Tetrakis[4-(dimethylamino)phenyl]ethene 4,4'-Bis(dimethylamino)thiobenzophenone Trimethylphenylammonium chloride 4,4'-Bis(dimethylamino)benzhydrol N-METHYLACETANILIDE

N,N,N',N'-TETRAMETHYLBENZIDINE Acridinium, 3,6-bis(dimethylamino)-10-methyl-, methyl sulfate ACRIDINE ORANGE Basic Orange 14

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4,4'-Methylenebis(N,N-dimethylaniline) Suppliers

Global( 208)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
CLEARSYNTH LABS LTD.	+91-22-45045900	Hyderabad, India	6351	58	Inquiry
Otto Chemie Pvt. Ltd.	+91 9820041841	Mumbai, India	5873	58	Inquiry
Alfa Aesar	1 800 209 7001	Maharashtra, India	6913	58	Inquiry
Central Drug House(P) Ltd.	91-11-49404040	New Delhi, India	6160	58	Inquiry
Oxford laboratories	+91 250 239 0032	Maharashtra, India	652	58	Inquiry
Chemco International	91-22-66548894	Maharashtra, India	24	58	Inquiry
Kakadiya Chemicals	91--9173839693	Gujarat, India	20	58	Inquiry
HiMedia Laboratories	91-22-61471919	Maharashtra, India	1843	58	Inquiry
Clearsynth Labs	91-22-45045900	Maharashtra, India	3889	58	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry

Supplier	Advantage
CLEARSYNTH LABS LTD.	58
Otto Chemie Pvt. Ltd.	58
Alfa Aesar	58
Central Drug House(P) Ltd.	58
Oxford laboratories	58
Chemco International	58
Kakadiya Chemicals	58
HiMedia Laboratories	58
Clearsynth Labs	58
TCI Chemicals (India) Pvt. Ltd.	58

4,4'-Methylenebis(N,N-dimethylaniline) Spectrum

4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)MS 4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)¹HNMR 4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)¹³CNMR 4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)IR1 4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)IR2 4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)Raman

101-61-1(4,4'-Methylenebis(N,N-dimethylaniline))Related Search:

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N,N-Dimethylformamide N,N-Dimethylacetamide 3,4'-DIAMINODIPHENYLMETHANE N,N-Diethylaniline Chlorodiphenylmethane

4-Dimethylaminopyridine Tris(hydroxymethyl)aminomethane 4-Dimethylaminobenzaldehyde

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Aniline, 4,4'-methylenebis[N,N-dimethyl- Baze michlerova bazemichlerova bazemichlerova(czech) Benzenamine, 4,4'-methylenebis*N,N-dimethyl- bis(4-(n,n-dimethylamino)phenyl)methane bis(p-(dimethylamino)phenyl)-methan bis(p-(n,n-dimethylamino)phenyl)methane bis(p-dimethylamino)diphenylmethane Bis[4-(N,N-dimethylamino)phenyl]methane Bis[p-(N,N-dimethylamino)phenyl]methane Diphenylmethane, tetramethyldiamino- Methane base Michler's hydride Methane, bis(4,4'-dimethylaminophenyl)- Methane, bis(p-(dimethylamino)phenyl)- Methanediamine, tetramethyl-N,N'-diphenyl- Methylene base methylenebase methylenebis(n,n-dimethylaniline) michler’sketone,reduced michler’smethane Michler's methane N-(4-[4-(Dimethylamino)benzyl]phenyl)-N,N-dimethylamine N,N,N',N'-Tetramethyl-p,p'-diaminodiphenylmethane N,N,N’,N’-Tetramethyl-4,4’-dia n,n,n’,n’-tetramethyl-p,p’-diaminodiphenylmethane n,n,n’n’-tetramethyl-p,p’-diaminodiphenylmethane 4,4'-Tetramethyldia n,n’-tetramethyldiaminodiphenylmethane N,N'-Tetramethyldiaminodiphenylmethane NCI-C01990 p,p’-bis(dimethylamino)diphenylmethane p,p’-bis(n,n-dimethylaminophenyl)methane p,p'-Bis(dimethylamino)diphenylmethane p,p'-Bis(N,N-dimethylaminophenyl)methane p,p-Dimethylaminodiphenylmethane Reduced michler'S ketone reducedmichler’sketone tetramethyldiamino-diphenylmethan 4,4'-Bis(diMethylaMinophenyl)Metha Methane Base 4,4'-Methylenebis(N,N-dimethylaniline) Tetra Base 4,4'-Tetramethyldiaminodiphenylmethane 4,4’-methylenebis(n,n-dimethyl)-benzenamine 4,4’-methylenebis(n,n-dimethyl-anilin 4,4’-methylenebis(n,n-dimethyl-benzenamin 4,4’-methylenebis(N,N-dimethyl-Benzenamine 4,4'-(Dimethylamino)diphenylmethane 4,4’-(dimethylamino)diphenylmethane 4,4’-methylenebis(n,n-dimethyl)benzenamine Bis[4-(dimethylamino)phenyl]methane 4,4'-Methylenebis(N,N-dimethylaniline) N,N,N′,N′-Tetramethyl-4,4′-methylenedianiline,4,4′-Methylenebis-N,N-dimethylaniline, Arnolds base, N,N,N′,N′-Tetramethyl-4,4′-diaminodiphenylmethane 4,4′-Methylenebis(N,N-dimethylaniline),N,N,N′,N′-Tetramethyl-4,4′-diaminodiphenylmethane, N,N,N′,N′-Tetramethyl-4,4′-methylenedianiline, Arnolds base 4,4′-Methylenebis(N Methane Bas N,N,N′,N′-Tetramethyl-4,4′-methylenedianiline N,N,N′,N'-Tetramethyl-4,4'-diaminodiphenylmethane Arnolds base 4,4'-Tetramethyldiaminodiphenyl methane Bis[4-(dimethylamino)phenyl]methane 4,4'-Methylenebis(N,N-dimethylaniline) Methane Base Tetra tetramethyl-n,n’-diphenyl-methanediamin Methylene bis(N,N'-dimethyl)aniline, 4,4'-? Michler's Base 4,4'-bis(N,N-dimethyl)aminodiphenylmethane 4,4'-Methylenebis(N,N-dimethylaniline)~N,N,N',N'-Tetramethyl-4,4'-diaminodiphenylmethane