1-Naphthylacetonitrile

1-Naphthylacetonitrile  Structure
CAS No.
132-75-2
Chemical Name:
1-Naphthylacetonitrile
Synonyms
ANNAFOMINA;1-NAPHTHALENEACETO;1-Naphthyl acetonitr;1-Naphtylacetonitrile;1-phthyl acetonitrile;LABOTEST-BB LTBB001326;a-naphthylacetonitrile;1-NAPHTHYLACETONITRILE;Naphazoline Impurity C;1-NAPHTHYLMETHYLCYANIDE
CBNumber:
CB4416463
Molecular Formula:
C12H9N
Molecular Weight:
167.21
MOL File:
132-75-2.mol
MSDS File:
SDS
Modify Date:
2024/8/13 18:45:30

1-Naphthylacetonitrile Properties

Melting point 33-35 °C(lit.)
Boiling point 191-194 °C18 mm Hg(lit.)
Density 1.1110 (rough estimate)
refractive index n20/D 1.6192(lit.)
Flash point >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Sparingly), Dichloromethane (Slightly), Methanol (Slightly)
form Liquid After Melting
color Clear yellow to brown
BRN 1101012
CAS DataBase Reference 132-75-2(CAS DataBase Reference)
NIST Chemistry Reference 1-Naphthaleneacetonitrile(132-75-2)
EPA Substance Registry System 1-Naphthaleneacetonitrile (132-75-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS07
Signal word  Warning
Hazard statements  H302-H312-H315-H319-H332-H335-H331
Precautionary statements  P261-P280-P305+P351+P338-P304+P340-P405-P501a
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38-22
Safety Statements  26-37/39-24/25-37-36
RIDADR  3276
WGK Germany  3
RTECS  AM1240000
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29269090
Toxicity mouse,LD50,intravenous,180mg/kg (180mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03835,
NFPA 704
1
2 0

1-Naphthylacetonitrile price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemicals (India) N0366 1-Naphthylacetonitrile min. 98.0 % 132-75-2 25G ₹2900 2022-05-26 Buy
ALFA India ALF-L06696-22 1-Naphthylacetonitrile, 97% 132-75-2 100g ₹9202 2022-05-26 Buy
ALFA India ALF-L06696-14 1-Naphthylacetonitrile, 97% 132-75-2 25g ₹3380 2022-05-26 Buy
TCI Chemicals (India) N0366 1-Naphthylacetonitrile min. 98.0 % 132-75-2 500G ₹23100 2022-05-26 Buy
ALFA India ALF-L06696-06 1-Naphthylacetonitrile, 97% 132-75-2 5g ₹1967 2022-05-26 Buy
Product number Packaging Price Buy
N0366 25G ₹2900 Buy
ALF-L06696-22 100g ₹9202 Buy
ALF-L06696-14 25g ₹3380 Buy
N0366 500G ₹23100 Buy
ALF-L06696-06 5g ₹1967 Buy

1-Naphthylacetonitrile Chemical Properties,Uses,Production

Chemical Properties

White to yellow solid or melt. Insoluble in water.

Uses

2-(Naphthalen-1-yl)acetonitrile is useful for the preparation of tert-Bu benzoates.

Preparation

Synthesis of 1-naphthylacetonitrile: 695g of 1-chloromethyl naphthalene, 1500ml of methanol and 475ml of water, 350g of sodium cyanide mixture boiling reflux, stirring the reaction for 2h. 1300ml of methanol was evaporated, cooled, and the reactants were washed with water to neutral to obtain 670-680g of 1-naphthylacetonitrile.

Application

1-Naphthylacetonitrile is an organic synthesis intermediate. It is used in the synthesis of 1-naphthylacetate.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 39, p. 3030, 1991 DOI: 10.1248/cpb.39.3030

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(1-naphthyl)-acetonitril Acetonitrile, (1-naphthyl)- alpha-(1-naphthyl)acetonitrile a-naphthylacetonitrile ALPHA-NAPHTHYLACETONITRILE LABOTEST-BB LTBB001326 1-Naphthylene Acetonitrile 1-Naphtylacetonitrile 1-Naphthylacetonitrile97% 1-NAPHTHYLACETONITRILE 1-NAPHTHYLMETHYLCYANIDE 1-NAPHTHALENEACETONITRILE 45) 1-NAPHTHYL ACETONITILE A-NAPHTHALENEACETONITRILE (SEE 5049) 1-NAPHTHYLACETONITIRILE pure 1-Cyanomethylnaphthalene 2-(1-Naphthyl)acetonitrile Naphthalene-1-acetonitrile naphthalenyl-acetonitrile 1-Naphthyl acetonitr Naphazoline IMpurity C (1-Naphthyl Acetonitrile) 1-Naphthylacetonitrile, 97% 5GR naphthalen-1-ylacetonitrile 1-phthyl acetonitrile 1-NAPHTHALENEACETO Naphazoline Impurity 3(Naphazoline EP Impurity C) Naphazoline EP Impurity C ANNAFOMINA 1-Naphthylacetonitrile, 97.5% (Naphthalen-1-yl)acetonitrile (1-Na 1-Naphthylacetonitrile> Naphazoline EP Impurity C (1-Naphthyl Acetonitrile) 1-Naphthaleneacetonitrile(NAN) Naphazoline Impurity C 1-Naphthylacetonitrile pure (naphthalen-1-yl)acetonitrile (1-naphthylacetonitrile) Naphazoline Hydrochloride Impurity C Naphazoline Hydrochloride EP Impurity C Naphazoline Nitrate Impurity C Naphazoline Nitrate EP Impurity C 132-75-2 132-75-3 C10H7CH2CN C10 to C27 Building Blocks Cyanides/Nitriles Nitrogen Compounds Organic Building Blocks Naphthalene series intermediates Aromatic Nitriles Intermediates of Dyes and Pigments