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(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine Structure
CAS No.
167316-27-0
Chemical Name:
(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
Synonyms
(S,S)-TSDPEN;N-((1S,2S)-2-amino-1,2-diphenylethyl)-4-methylbenzenesulfonamide;(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine;(1S,2S)-TSDPEN;2S)-(+)-N-p-Tosyl-1;2-diphenylethylenediaMine;(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-;(1S,2S)-N-P-TOSYL-1,2-DIPHENYLETHYLENE-D;(1S,2S)-N-Tosyl-1,2-diphenylethylene-1,2-diamine;(1S,2S)-(-)-N-P-TOSYL-1,2-DIPHENYLETHYLENEDIAMINE
CBNumber:
CB4775946
Molecular Formula:
C21H22N2O2S
Molecular Weight:
366.48
MOL File:
167316-27-0.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine Properties

Melting point 128-131 °C (lit.)
Boiling point 537.3±60.0 °C(Predicted)
alpha 61.5 º (C=1, CH2Cl2)
Density 1.1440 (rough estimate)
refractive index 30 ° (C=1, CHCl3)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Solubility in hot Acetonitrile (almost transparency).
form crystal
pka 10.76±0.50(Predicted)
color white
optical activity [α]20/D +35°, c = 1 in chloroform
CAS DataBase Reference 167316-27-0(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  29242990
NFPA 704
0
2 0

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 484342 (1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine 98% 167316-27-0 1G ₹20069.55 2022-06-14 Buy
ALFA India ALF-H27006-14 (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine 167316-27-0 25g ₹53865 2022-05-26 Buy
ALFA India ALF-H27006-06 (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine 167316-27-0 5g ₹54119 2022-05-26 Buy
ALFA India ALF-H27006-03 (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine 167316-27-0 1g ₹8109 2022-05-26 Buy
TCI Chemicals (India) A1699 (S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide 167316-27-0 1G ₹9700 2022-05-26 Buy
Product number Packaging Price Buy
484342 1G ₹20069.55 Buy
ALF-H27006-14 25g ₹53865 Buy
ALF-H27006-06 5g ₹54119 Buy
ALF-H27006-03 1g ₹8109 Buy
A1699 1G ₹9700 Buy

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine Chemical Properties,Uses,Production

Chemical Properties

White to slightly yellow crystalline powder

Uses

(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine is used as a catalyst in the synthesis of keramamine C, a carboline alkaloid that is isolated from the Okinawan sponge Amphimedon sp. (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine is also used as a catalyst in the synthesis of Tolvaptan (T536650), a selective oral vasopressin V2-receptor agonist that is used to treat hyponatremia.

General Description

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(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 263)Suppliers
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CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine Spectrum

(1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine (S,S)-Ts-DPEN, (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98% (S,S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE (1S, 2S)-(+)-N-(4-TOLUENE SULFONYL)1,2-DIPHENYL-1,2-ETHANE DIAMINE (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediaMine, 98% 500MG (1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine≥ 99% (Assay, Chiral purity) (1S,2S)-N-p-Tosyl-1,2-diphenylethylenediamine,99%e.e. (1S,2S)-(-)-N-p-Tosyl-1,2-diphenylethylenediaMine SynonyMs (S,S)-TsDPEN (1S,2S)-N-Tosyl-1,2-diphenylethylene-1,2-diamine (S,S)-N-(2-AMINO-1,2-DIPHENYLETHYL)-P-TOLUENESULFONAMIDE (1S,2S)-N-(4-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENE-1,2-DIAMINE (1S,2S)-(+)-N-(4-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE (1S,2S)-(+)-N-(4-TOLUENESULPHONYL)-1,2-DIPHENYLETHYLENEDIAMINE (1S,2S)-TSDPEN (1S,2S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYL-1,2-ETHANEDIAMINE (1S,2S)-(-)-N-P-TOSYL-1,2-DIPHENYLETHYLENEDIAMINE (1S,2S)-(+)-N-P-TOSYL-1,2-DIPHENYLETHYLENEDIAMINE (1S,2S)-N-P-TOSYL-1,2-DIPHENYLETHYLENE-D (1S,2S)-(+)-N-(4-toluenesulfonyl)-1,2-diphenylethylenediamine,98%(S,S)-TsDPEN (1S,2S)-(+)-N-(4-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE (S,S)-TSDPEN (1S,2S)-(-)-N-P-TOSYL-1,2-DIPHENYLETHYLENEDIAMINE 98% (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2- 2-diphenylethylenediaMine 2S)-(+)-N-p-Tosyl-1 (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine,98% (1S,2S)-N-p-toluenesulfonyl-1,2-dipheneylethylenediamine (S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide > (1S,2S)-(+)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine Benzenesulfonamide, N-[(1S,2S)-2-amino-1,2-diphenylethyl]-4-methyl- (1S,2S)-(+)-N-(4-toluenesulfonyl)-1,2-diphenylethylenediamine,98%,99%ee (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamin... (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine N-((1S,2S)-2-amino-1,2-diphenylethyl)-4-methylbenzenesulfonamide (S,S)-TSDPEN (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylen (1S,2S)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine / S-DPEN Tos 167316-27-0 CH3C6H4SO2NHCHC6H5CHC6H5NH2 C21H23N2O2S Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Hydrogenation Chiral Nitrogen DPEN Series API intermediates Asymmetric Synthesis Synthetic Organic Chemistry Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents HydrogenationChiral Building Blocks Organic Building Blocks Polyamines organic amine