(4-Methylphenyl)sulfonyl acetate

(4-Methylphenyl)sulfonyl acetate Structure
CAS No.
26908-82-7
Chemical Name:
(4-Methylphenyl)sulfonyl acetate
Synonyms
acetyl p-toluenesulfonate;UOAJUPONZOXFNX-UHFFFAOYSA-N;(4-METHYLPHENYL)SULFONYL ACETATE;(4-Methylbenzene)sulfonyl Acetate;Acetic P-Toluenesulfonic Anhydride;Acetic Acid, Anhydride With P-Toluenesulfonic Acid;Acetic acid, anhydride with 4-methylbenzenesulfonic acid
CBNumber:
CB4949882
Molecular Formula:
C9H10O4S
Molecular Weight:
214.24
MOL File:
26908-82-7.mol
Modify Date:
2023/7/5 8:28:20

(4-Methylphenyl)sulfonyl acetate Properties

Boiling point 325.7±35.0 °C(Predicted)
Density 1.279±0.06 g/cm3(Predicted)

(4-Methylphenyl)sulfonyl acetate Chemical Properties,Uses,Production

Purification Methods

The most likely impurity is p-toluenesulfonic acid (could be up to 10%). This can be removed by dissolving it in dry Et2O and cooling until the anhydride crystallises out. It decomposes on heating; below ~130o it gives the disulfonic anhydride and above ~130o polymers are formed, but it can be distilled in a vacuum if it is free of acid. It is used for cleaving ethers [Prep, IR, NMR: Karger & Mazur J Org Chem 36 528, Karger & Mazur J Org Chem 36 532 1971]. [Beilstein 11 III 255.]

(4-Methylphenyl)sulfonyl acetate Preparation Products And Raw materials

(4-Methylphenyl)sulfonyl acetate Suppliers

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Acetic Acid, Anhydride With P-Toluenesulfonic Acid Acetic P-Toluenesulfonic Anhydride (4-METHYLPHENYL)SULFONYL ACETATE UOAJUPONZOXFNX-UHFFFAOYSA-N acetyl p-toluenesulfonate Acetic acid, anhydride with 4-methylbenzenesulfonic acid (4-Methylbenzene)sulfonyl Acetate 26908-82-7