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Phenyl sulfoxide

Phenyl sulfoxide Structure
CAS No.
945-51-7
Chemical Name:
Phenyl sulfoxide
Synonyms
PhS(O)Ph;thionylbenzene;PHENYL SULFOXIDE;Diphenyl sulfoxid;PHENYL SULPHOXIDE;sulfinyldibenzene;1,1'-sulfinylbis-;sulfoxide,diphenyl;DIPHENYL SULFOXIDE;Two phenylsulfoxide
CBNumber:
CB5187724
Molecular Formula:
C12H10OS
Molecular Weight:
202.27
MOL File:
945-51-7.mol
MSDS File:
SDS
Modify Date:
2024/4/23 16:18:34

Phenyl sulfoxide Properties

Melting point 69-71 °C (lit.)
Boiling point 206-208 °C/13 mmHg (lit.)
Density 1.1833 (rough estimate)
refractive index 1.6090 (estimate)
Flash point 206-208°C/13mm
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), DMSO (Slightly)
form Crystalline Powder
color White to off-white
Water Solubility Soluble in water. Soluble in most organic solvents.
BRN 1908444
InChIKey JJHHIJFTHRNPIK-UHFFFAOYSA-N
CAS DataBase Reference 945-51-7(CAS DataBase Reference)
NIST Chemistry Reference Diphenyl sulfoxide(945-51-7)
EPA Substance Registry System Benzene, 1,1'-sulfinylbis- (945-51-7)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02
Signal word  Danger
Hazard statements  H225
Precautionary statements  P210-P403+P235
Hazard Codes  Xi
Safety Statements  22-24/25
WGK Germany  3
RTECS  DA9185000
Hazard Note  Irritant
TSCA  Yes
HS Code  29309070
NFPA 704
0
1 0

Phenyl sulfoxide price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) P35405 Diphenyl sulfoxide 96% 945-51-7 25G ₹3518.13 2022-06-14 Buy
Sigma-Aldrich(India) P35405 Diphenyl sulfoxide 96% 945-51-7 100G ₹8486.8 2022-06-14 Buy
TCI Chemicals (India) D1002 Diphenyl Sulfoxide min. 99.0 % 945-51-7 5G ₹1500 2022-05-26 Buy
TCI Chemicals (India) D1002 Diphenyl Sulfoxide min. 99.0 % 945-51-7 25G ₹3600 2022-05-26 Buy
TCI Chemicals (India) D1002 Diphenyl Sulfoxide min. 99.0 % 945-51-7 100G ₹8100 2022-05-26 Buy
Product number Packaging Price Buy
P35405 25G ₹3518.13 Buy
P35405 100G ₹8486.8 Buy
D1002 5G ₹1500 Buy
D1002 25G ₹3600 Buy
D1002 100G ₹8100 Buy

Phenyl sulfoxide Chemical Properties,Uses,Production

Chemical Properties

white to off-white crystalline powder

Uses

Diphenyl sulfoxide is a reagent used as an oxidant and hydroxyl activator in combination with a variety of electrophilic reagents. Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane was reported. Direct glycosylations with 1-hydroxy glycosyl donors is made using trifluoromethanesulfonic anhydride and diphenyl sulfoxide. The preparation of triarylsulfonium halides was by the action of aryl Grignard reagents on diphenyl sulfoxide.

Synthesis Reference(s)

Journal of the American Chemical Society, 114, p. 6269, 1992 DOI: 10.1021/ja00041a069
Tetrahedron Letters, 31, p. 4533, 1990 DOI: 10.1016/S0040-4039(00)97667-6

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1,1’-sulfinylbis-benzen 1,1’-sulfinylbis-Benzene Diphenyl sulfoxide,Phenyl sulfoxide Phenyl sulfoxide, 97% 100GR Phenyl sulfoxide, 97% 25GR Diphenyl sulfoxid (benzenesulfinyl)benzene bis-(phenyl)-sulfoxide Two phenylsulfoxide Benzene, 1,1'-sulfinylbis- Phenylsulfinylbenzene Sulfoxide, diphenyl sulfoxide,diphenyl DIPHENYL SULFOXIDE DIPHENYL SULPHOXIDE PHENYL SULPHOXIDE PHENYL SULFOXIDE DIPHENYL SULFOXIDE PESTANAL DiphenylSulphoxide98% Diphenyl sulfoxide, 97+% Diphenyl Sulphoxide 98% Diphenylsulphoxide,97% thionylbenzene Diphenyl sulfoxide, 98+% sulfinyldibenzene Phenyl sulfoxide, 97% 25g PhS(O)Ph Phenyl sulfoxide,97% 1,1'-sulfinylbis- Diphenyl Sulfoxide > 945-51-7 C12H10O1S1 C6H52SO C12H10OS Sulfoxides Sulfur Compounds Organic Building Blocks Building Blocks Reagents for Oligosaccharide Synthesis Building Blocks Chemical Synthesis Organic Building Blocks Sulfoxides Sulfur Compounds fine chemicals Biochemistry Reagents for Oligosaccharide Synthesis bc0001