D-(+)-Camphoric acid
![D-(+)-Camphoric acid Structure](CAS/GIF/124-83-4.gif)
- CAS No.
- 124-83-4
- Chemical Name:
- D-(+)-Camphoric acid
- Synonyms
- (1R,3S)-CAMPHORIC ACID;(1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid;(1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid;1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)-;D-caMphor acid;D-(+)-Camphoric;(+)-CAMPHORIC ACID;D-(+)-Camphoricaci;D-(+)-Camphoric acid;Dextro-camphoric acid
- CBNumber:
- CB5296789
- Molecular Formula:
- C10H16O4
- Molecular Weight:
- 200.23
- MOL File:
- 124-83-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/6/30 15:45:59
Melting point | 186-189 °C |
---|---|
alpha | 46.5 º (c=10, C2H5OH) |
Boiling point | 297.96°C (rough estimate) |
Density | 1.1860 |
refractive index | 1.4459 (estimate) |
storage temp. | Sealed in dry,Room Temperature |
solubility | DMSO (Slightly), Ethanol (Slightly), Methanol (Slightly) |
form | Crystalline Powder |
pka | pK1: 4.57;pK2: 5.10 (25°C) |
color | White |
optical activity | [α]20/D 46°, c = 1 in ethanol |
Water Solubility | 0.8 g/100 mL |
Merck | 14,1733 |
BRN | 2050204 |
CAS DataBase Reference | 124-83-4(CAS DataBase Reference) |
NIST Chemistry Reference | D-camphoric acid(124-83-4) |
EPA Substance Registry System | 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R,3S)- (124-83-4) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H302-H315-H319 | |||||||||
Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
Hazard Codes | Xn | |||||||||
Risk Statements | 22 | |||||||||
Safety Statements | 24/25 | |||||||||
WGK Germany | 2 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29172090 | |||||||||
NFPA 704 |
|
D-(+)-Camphoric acid price More Price(7)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | C409 | (1R,3S)-(+)-Camphoric acid 99% | 124-83-4 | 5G | ₹1688.7 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | C409 | (1R,3S)-(+)-Camphoric acid 99% | 124-83-4 | 100G | ₹6971.3 | 2022-06-14 | Buy |
ALFA India | ALF-B23106-36 | (1R,3S)-(+)-Camphoric acid, 98+% | 124-83-4 | 500g | ₹38492 | 2022-05-26 | Buy |
ALFA India | ALF-B23106-22 | (1R,3S)-(+)-Camphoric acid, 98+% | 124-83-4 | 100g | ₹7698 | 2022-05-26 | Buy |
ALFA India | ALF-B23106-14 | (1R,3S)-(+)-Camphoric acid, 98+% | 124-83-4 | 25g | ₹1780 | 2022-05-26 | Buy |
D-(+)-Camphoric acid Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powde
Uses
D-(+)-Camphoric acid is used primarily as a reagent in syntheses of crystalline structures. It is used in the preparation of polymeric transition metal dipyridylamine D-camphorate complexes.
General Description
Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.
Purification Methods
Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933
D-(+)-Camphoric acid Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
Reax Chemicals | 08048372701Ext 416 | Hyderabad, India | 4223 | 58 | Inquiry |
S.Zhaveri Pharmakem Pvt. Ltd | -66607687 | Mumbai, India | 58 | 58 | Inquiry |
Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
SynZeal Research Pvt Ltd | +1 226-802-2078 | Gujarat, India | 6522 | 58 | Inquiry |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
Supplier | Advantage |
---|---|
CHEMSWORTH | 30 |
A.J Chemicals | 58 |
CLEARSYNTH LABS LTD. | 58 |
TCI Chemicals (India) Pvt. Ltd. | 58 |
Alfa Aesar | 58 |
Reax Chemicals | 58 |
S.Zhaveri Pharmakem Pvt. Ltd | 58 |
Clearsynth Labs | 58 |
SynZeal Research Pvt Ltd | 58 |
Capot Chemical Co.,Ltd. | 60 |
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