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D-(+)-Camphoric acid

D-(+)-Camphoric acid Structure
CAS No.
124-83-4
Chemical Name:
D-(+)-Camphoric acid
Synonyms
(1R,3S)-CAMPHORIC ACID;(1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid;(1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid;1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)-;D-caMphor acid;D-(+)-Camphoric;(+)-CAMPHORIC ACID;D-(+)-Camphoricaci;D-(+)-Camphoric acid;Dextro-camphoric acid
CBNumber:
CB5296789
Molecular Formula:
C10H16O4
Molecular Weight:
200.23
MOL File:
124-83-4.mol
MSDS File:
SDS
Modify Date:
2023/6/30 15:45:59

D-(+)-Camphoric acid Properties

Melting point 186-189 °C
alpha 46.5 º (c=10, C2H5OH)
Boiling point 297.96°C (rough estimate)
Density 1.1860
refractive index 1.4459 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility DMSO (Slightly), Ethanol (Slightly), Methanol (Slightly)
form Crystalline Powder
pka pK1: 4.57;pK2: 5.10 (25°C)
color White
optical activity [α]20/D 46°, c = 1 in ethanol
Water Solubility 0.8 g/100 mL
Merck 14,1733
BRN 2050204
CAS DataBase Reference 124-83-4(CAS DataBase Reference)
NIST Chemistry Reference D-camphoric acid(124-83-4)
EPA Substance Registry System 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R,3S)- (124-83-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xn
Risk Statements  22
Safety Statements  24/25
WGK Germany  2
TSCA  Yes
HS Code  29172090
NFPA 704
0
0 0

D-(+)-Camphoric acid price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) C409 (1R,3S)-(+)-Camphoric acid 99% 124-83-4 5G ₹1688.7 2022-06-14 Buy
Sigma-Aldrich(India) C409 (1R,3S)-(+)-Camphoric acid 99% 124-83-4 100G ₹6971.3 2022-06-14 Buy
ALFA India ALF-B23106-36 (1R,3S)-(+)-Camphoric acid, 98+% 124-83-4 500g ₹38492 2022-05-26 Buy
ALFA India ALF-B23106-22 (1R,3S)-(+)-Camphoric acid, 98+% 124-83-4 100g ₹7698 2022-05-26 Buy
ALFA India ALF-B23106-14 (1R,3S)-(+)-Camphoric acid, 98+% 124-83-4 25g ₹1780 2022-05-26 Buy
Product number Packaging Price Buy
C409 5G ₹1688.7 Buy
C409 100G ₹6971.3 Buy
ALF-B23106-36 500g ₹38492 Buy
ALF-B23106-22 100g ₹7698 Buy
ALF-B23106-14 25g ₹1780 Buy

D-(+)-Camphoric acid Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

D-(+)-Camphoric acid is used primarily as a reagent in syntheses of crystalline structures. It is used in the preparation of polymeric transition metal dipyridylamine D-camphorate complexes.

General Description

Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.

Purification Methods

Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933

D-(+)-Camphoric acid Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 323)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
Reax Chemicals 08048372701Ext 416 Hyderabad, India 4223 58 Inquiry
S.Zhaveri Pharmakem Pvt. Ltd -66607687 Mumbai, India 58 58 Inquiry
Clearsynth Labs 91-22-45045900 Maharashtra, India 3889 58 Inquiry
SynZeal Research Pvt Ltd +1 226-802-2078 Gujarat, India 6522 58 Inquiry
Capot Chemical Co.,Ltd. 571-85586718 +8613336195806 China 29798 60 Inquiry
(1R,3S)-(+)-CAMPHORIC ACID (1R,3S)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID (+)-CAMPHORIC ACID D-caMphor acid D(+)-CaMphoric acid, 99% 100GR (1RS,3SR)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid(caMphoric acid) (1R,3S)-(+)-Camphoric acid 99% (1R,3S)-(+)-Camphoric acid, >=99% 1,3-Cyclopentanedicarboxylicacid, 1,2,2-trimethyl-, (1R,3S)- (1R,3S)-(+)-Camphoric acid D(+)-Camphoric acid (1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid 2,2-trimethyl-3-cyclopentanedicarboxylicaci(1theta-cis)-1 Cis-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylicacid Dextro-camphoric acid (+)-CAMPHORIC ACID, NATURAL 1,2,2-Trimethyl-1,3-cyclopentanedicarbonsaeure D-(+)-Camphoric (1R,3S)-(+)-Camphoric acid, 98+% (+)-Camphoric acid, (1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid (1R)-cis-Camphoric acid cis-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid, (1R) 1,2,2-Trimethyl-1β,3β-cyclopentanedicarboxylic acid D(+)-Camphoric acid,99% D-(+)-Camphoric acid Levocarnitine EP Impurity B Levocarnitine Impurity 2(Levocarnitine EP Impurity B) (+)-Camphoric Acid > Levocarnitine Impurity B (D-(+)-Camphoric Acid) D-(+)-Camphoric acid USP/EP/BP (1R,3S)-1,2,2-trimethylcyclopentane-1,3-dicarboxylate (1R,3S)-CAMPHORIC ACID 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)- (1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid (1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid D-(+)-Camphoricaci 124-83-4 Chiral Resolving Reagents Chiral Resolution Reagents Asymmetric Synthesis Optical Resolution Bicyclic Monoterpenes for Resolution of Bases Terpenes Bicyclic Monoterpenes Biochemistry for Resolution of Bases Optical Resolution Synthetic Organic Chemistry Terpenes Chiral Compound Pharmaceutical Intermediates FINE Chemical & INTERMEDIATES Miscellaneous Natural Products chiral