(1R)-(-)-10-Camphorsulfonic acid
- CAS No.
- 35963-20-3
- Chemical Name:
- (1R)-(-)-10-Camphorsulfonic acid
- Synonyms
- (-)-CSA;(1R)-(-)-CAMPHOR-10-SULFONIC ACID;((1R,4S)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonic acid;(-)-10-CSA;L-(-)-CAMPHORSULFONIC ACID;(-)-10-CAMPHORSULFONIC ACID;d-Camphor-10-sulphonic acid;(-)-10-Camphorsulfonic Acid;(1R)-CAMPHOR-10-SULFONIC ACID;L-10-(-)-CAMPHOR SULFONIC ACID
- CBNumber:
- CB0365888
- Molecular Formula:
- C10H16O4S
- Molecular Weight:
- 232.3
- MOL File:
- 35963-20-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/9/13 19:17:58
Melting point | 198 °C (dec.)(lit.) |
---|---|
alpha | -22 º (c=20,H2O) |
Boiling point | 344.46°C (rough estimate) |
Density | 1.2981 (rough estimate) |
refractive index | -21.5 ° (C=5, H2O) |
storage temp. | Store below +30°C. |
solubility | DMSO (Slightly), Methanol (Slightly), Water (Sparingly) |
pka | 1.17±0.50(Predicted) |
form | Crystalline Powder |
color | White to slightly beige |
PH | 1.2-1.4 (20g/l, H2O) |
optical activity | [α]20/D 21°, c = 2 in H2O |
Water Solubility | soluble |
Sensitive | Hygroscopic |
BRN | 2809676 |
Stability | Stable. Hygroscopic. Incompatible with strong bases, strong oxidizing agents. |
InChIKey | MIOPJNTWMNEORI-XVKPBYJWSA-N |
CAS DataBase Reference | 35963-20-3(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 34 | |||||||||
Safety Statements | 26-36/37/39-45-24/25-27 | |||||||||
RIDADR | UN 3261 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 3-10 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29147090 | |||||||||
NFPA 704 |
|
(1R)-(-)-10-Camphorsulfonic acid price More Price(13)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 8.40094 | (1R)-(-)-Camphor-10-sulfonic acid for synthesis | 35963-20-3 | 10G | ₹3039.99 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 8.40094 | (1R)-(-)-Camphor-10-sulfonic acid for synthesis | 35963-20-3 | 100G | ₹20850 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 282146 | (1R)-(−)-10-Camphorsulfonic acid 98% | 35963-20-3 | 25G | ₹2468.1 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 282146 | (1R)-(−)-10-Camphorsulfonic acid 98% | 35963-20-3 | 100G | ₹7674.93 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 21365 | (−)-Camphor-10-sulfonic acid purum, ≥98.0% (T) | 35963-20-3 | 50G | ₹6310.98 | 2022-06-14 | Buy |
(1R)-(-)-10-Camphorsulfonic acid Chemical Properties,Uses,Production
Uses
1R)-(-)-10-Camphorsulfonic acid is a chiral derivative of Camphor.It has the following uses:
(1)It is also used for the racemization of optical isomers.
(2) It can be applied to the resolution of intermediate or isomer in medicine.
(3) It also could play a role as organic synthesis intermediates and resolving agent.
Definition
ChEBI: The R enantiomer of camphorsulfonic acid.
Purification Methods
It forms prisms from AcOH or EtOAc, and is deliquescent in moist air. Store it in tightly stoppered bottles. The NH4 salt forms needles from H2O [] D ±20.5o (c 5, H2O). [Burgess & Lowry J Chem Soc 127 279 1925, Marsi et al. J Am Chem Soc [ 78 3063 1956.] The RS-acid recrystallises from AcOH. [60g of (±)-acid in 60mL of AcOH at 105o gave 40g of crystals has m 202-203o [Bartlett & Knox Org Synth 45 12 1965.] [Beilstein 11 IV 642.]
(1R)-(-)-10-Camphorsulfonic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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chevron_rightSupplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
Vardhaman P Golechha | 9704422000 | Telangana, India | 294 | 58 | Inquiry |
Souvenier Chemicals | 08048372762Ext 645 | Mumbai, India | 396 | 58 | Inquiry |
Biopharmacule Speciality Chemicals P Ltd (India) | +91 40 6462 1866 | Hyderabad, India | 526 | 58 | Inquiry |
Eastern Chemicals (Mumbai) Pvt., Ltd. | 91-22-67365900 | Maharashtra, India | 104 | 58 | Inquiry |
Oceanic Pharmachem Pvt. Ltd. | 91-22-42128600 | Maharashtra, India | 2006 | 58 | Inquiry |
Chemic Life Sciences Pvt., Ltd. | 91-40-23720081 | Hyderabad, India | 7 | 58 | Inquiry |
Pharma Affiliates | 172-5066494 | Haryana, India | 6761 | 58 | Inquiry |
Sparchem | 91-22-62879419 | Maharashtra, India | 68 | 58 | Inquiry |
Jiya Pharmachem | 08068442303Ext 473 | Mumbai, India | 83 | 58 | Inquiry |
S. Amit Speciality Chemicals Pvt. Ltd. | 91-22-40013003 | Maharashtra, India | 177 | 58 | Inquiry |
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