ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Sulfonates / Sulfinates >(1R)-(-)-10-Camphorsulfonic acid

(1R)-(-)-10-Camphorsulfonic acid

(1R)-(-)-10-Camphorsulfonic acid Structure
CAS No.
35963-20-3
Chemical Name:
(1R)-(-)-10-Camphorsulfonic acid
Synonyms
(-)-CSA;(1R)-(-)-CAMPHOR-10-SULFONIC ACID;((1R,4S)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonic acid;(-)-10-CSA;L-(-)-CAMPHORSULFONIC ACID;(-)-10-CAMPHORSULFONIC ACID;d-Camphor-10-sulphonic acid;(-)-10-Camphorsulfonic Acid;(1R)-CAMPHOR-10-SULFONIC ACID;L-10-(-)-CAMPHOR SULFONIC ACID
CBNumber:
CB0365888
Molecular Formula:
C10H16O4S
Molecular Weight:
232.3
MOL File:
35963-20-3.mol
MSDS File:
SDS
Modify Date:
2024/9/13 19:17:58

(1R)-(-)-10-Camphorsulfonic acid Properties

Melting point 198 °C (dec.)(lit.)
alpha -22 º (c=20,H2O)
Boiling point 344.46°C (rough estimate)
Density 1.2981 (rough estimate)
refractive index -21.5 ° (C=5, H2O)
storage temp. Store below +30°C.
solubility DMSO (Slightly), Methanol (Slightly), Water (Sparingly)
pka 1.17±0.50(Predicted)
form Crystalline Powder
color White to slightly beige
PH 1.2-1.4 (20g/l, H2O)
optical activity [α]20/D 21°, c = 2 in H2O
Water Solubility soluble
Sensitive Hygroscopic
BRN 2809676
Stability Stable. Hygroscopic. Incompatible with strong bases, strong oxidizing agents.
InChIKey MIOPJNTWMNEORI-XVKPBYJWSA-N
CAS DataBase Reference 35963-20-3(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45-24/25-27
RIDADR  UN 3261 8/PG 2
WGK Germany  3
3-10
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29147090
NFPA 704
0
3 0

(1R)-(-)-10-Camphorsulfonic acid price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 8.40094 (1R)-(-)-Camphor-10-sulfonic acid for synthesis 35963-20-3 10G ₹3039.99 2022-06-14 Buy
Sigma-Aldrich(India) 8.40094 (1R)-(-)-Camphor-10-sulfonic acid for synthesis 35963-20-3 100G ₹20850 2022-06-14 Buy
Sigma-Aldrich(India) 282146 (1R)-(−)-10-Camphorsulfonic acid 98% 35963-20-3 25G ₹2468.1 2022-06-14 Buy
Sigma-Aldrich(India) 282146 (1R)-(−)-10-Camphorsulfonic acid 98% 35963-20-3 100G ₹7674.93 2022-06-14 Buy
Sigma-Aldrich(India) 21365 (−)-Camphor-10-sulfonic acid purum, ≥98.0% (T) 35963-20-3 50G ₹6310.98 2022-06-14 Buy
Product number Packaging Price Buy
8.40094 10G ₹3039.99 Buy
8.40094 100G ₹20850 Buy
282146 25G ₹2468.1 Buy
282146 100G ₹7674.93 Buy
21365 50G ₹6310.98 Buy

(1R)-(-)-10-Camphorsulfonic acid Chemical Properties,Uses,Production

Uses

1R)-(-)-10-Camphorsulfonic acid is a chiral derivative of Camphor.It has the following uses:
(1)It is also used for the racemization of optical isomers.
(2) It can be applied to the resolution of intermediate or isomer in medicine.
(3) It also could play a role as organic synthesis intermediates and resolving agent.

Definition

ChEBI: The R enantiomer of camphorsulfonic acid.

Purification Methods

It forms prisms from AcOH or EtOAc, and is deliquescent in moist air. Store it in tightly stoppered bottles. The NH4 salt forms needles from H2O [] D ±20.5o (c 5, H2O). [Burgess & Lowry J Chem Soc 127 279 1925, Marsi et al. J Am Chem Soc [ 78 3063 1956.] The RS-acid recrystallises from AcOH. [60g of (±)-acid in 60mL of AcOH at 105o gave 40g of crystals has m 202-203o [Bartlett & Knox Org Synth 45 12 1965.] [Beilstein 11 IV 642.]

Global( 610)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Vardhaman P Golechha 9704422000 Telangana, India 294 58 Inquiry
Souvenier Chemicals 08048372762Ext 645 Mumbai, India 396 58 Inquiry
Biopharmacule Speciality Chemicals P Ltd (India) +91 40 6462 1866 Hyderabad, India 526 58 Inquiry
Eastern Chemicals (Mumbai) Pvt., Ltd. 91-22-67365900 Maharashtra, India 104 58 Inquiry
Oceanic Pharmachem Pvt. Ltd. 91-22-42128600 Maharashtra, India 2006 58 Inquiry
Chemic Life Sciences Pvt., Ltd. 91-40-23720081 Hyderabad, India 7 58 Inquiry
Pharma Affiliates 172-5066494 Haryana, India 6761 58 Inquiry
Sparchem 91-22-62879419 Maharashtra, India 68 58 Inquiry
Jiya Pharmachem 08068442303Ext 473 Mumbai, India 83 58 Inquiry
S. Amit Speciality Chemicals Pvt. Ltd. 91-22-40013003 Maharashtra, India 177 58 Inquiry

Related articles

(-)-CAMPHOR-10-SULPHONIC ACID (-)-CAMPHOR-10-SULFONIC ACID L-10-(-)-CAMPHOR SULFONIC ACID L-(-)-CAMPHORSULFONIC ACID L-(+)-CAMPHOR SULFONIC ACID L(+)-CAMPHORSULPHONIC ACID L-CAMPHORSULPHONIC ACID L-(-)-CAMPHOR-10-SULFONIC ACID (1R)-(-)-CAMPHOR-10-SULPHONIC ACID (1R)-(-)-CAMPHOR-10-SULFONIC ACID (1R)-CAMPHOR-10-SULFONIC ACID (1R)-(-)-CAMPHORSULFONIC ACID (1r)-[7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]methanesulphonic acid (1R)-(-)-10-CAMPHORSULFONIC ACID (-)-10-CAMPHORSULFONIC ACID Voriconazole Related Compound 11 2-Oxo-10-bornane-sulfonicacid 7,7-Dimethyl-2-oxobicyclo[2,2,1]heptane-1-methane-sulfonicacid Camphor-sulphonicacid Voriconazole Related CoMpound F (1R)-(-)-10-Camphosulfonic acid L - Campho 10 Sulphonic Acid (1R)-(-)-Camphor-10-sulfonic acid, 98+% CLOPIDOGREL INTERMEDIATES d-Camphor-10-sulphonic acid (1R)-(-)-CAMPHOR-10-SULPHONIC ACID 99% S-(-)-CAMPHORSULFONIC ACID (1R)-(-)-CAMPHER-10-SULFONSURE Voriconazole EP Impurity E (1R)-Isomer )-Camphor-10-sulfonic acid (1R)-Camphor-10-sulfonic acid L(-)-Camphorsulfonic acid (1R)-(-)-Camphor-10-sulfonic acid for synthesis [(1S,4R)-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl]methanesulfonic acid (1R)-(-)-10-CaMphorsulfonic acid 98% L- caMphor sulfonic acid (L-caMphor sulfonic acid) L(-)-Camphorsulfonic acid 1R-(-)-10-Camphorsulfonic acid (-)-10-CSA [(4R)-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl]methanesulfonic acid Camphor Impurity 3((1R)-10-Camphorsulfonic Acid) (-)-CamphorsuL (-)-Camphor-10-sulfonic acid, (1R)-(-)-Camphor-10-sulfonic acid, (1R)-Camphor-10-sulfonic acid (-)-(1R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1R,4S)- (1R,4S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid (1R,4S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1α-methanesulfonic acid [1R,4S,(-)]-2-Oxobornane-10-sulfonic acid [1R,4S,(-)]-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid (1R)-Camphor-10-sulfonic acid L(-)-Camphorsulfonic acid (-)-10-Camphorsulfonic acid ,99% ()-Camphor-10-sulfonic acid,(1R)-()-Camphor-10-sulfonic acid (1R)-()-10-Camphorsulfonic acid,()-Camphor-10-sulfonic acid, (1R)-()-Camphor-10-sulfonic acid, (1R)-Camphor-10-sulfonic acid L(-)-Camphorsulfonic L(-)-Camphorsulfonic acid,98% (1R)-(-)-CAMPHOR-10-SULPHONIC ACIDCaMphorSulfonic Acid L(-)-CaMphorsulfonic acid, 98% 5GR ((1R,4S)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonic acid (R)-()-10-CaMphorsulfonic acid (-)-10-Camphorsulfonic acid, 99%, reagent grade (-)-10-Camphorsulfonic Acid >