Phenylboronic acid
- CAS No.
- 98-80-6
- Chemical Name:
- Phenylboronic acid
- Synonyms
- BENZENEBORONIC ACID;phenyboronic;PHENYLBORIC ACID;Phenylboronic acid D5;CAS:98-80-6;phenyl-boronicaci;Phenylboranic acid;BORONIC ACID, PHENYL-;Phenylboronic Acid (contains varying amounts of Anhydride);t-500
- CBNumber:
- CB5323625
- Molecular Formula:
- C6H7BO2
- Molecular Weight:
- 121.93
- MOL File:
- 98-80-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/6/13 17:03:25
| Melting point | 216-219 °C(lit.) |
|---|---|
| Boiling point | 265.9±23.0 °C(Predicted) |
| Density | 1.13±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly) |
| form | Crystalline Powder |
| pka | 8.83(at 25℃) |
| color | White to off-white |
| Water Solubility | 10 g/L (20 ºC) |
| Sensitive | Hygroscopic |
| Merck | 14,1068 |
| BRN | 970972 |
| Stability | Hygroscopic |
| InChIKey | HXITXNWTGFUOAU-UHFFFAOYSA-N |
| CAS DataBase Reference | 98-80-6(CAS DataBase Reference) |
| EPA Substance Registry System | Boronic acid, phenyl- (98-80-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302 | |||||||||
| Precautionary statements | P264-P270-P301+P312-P501 | |||||||||
| Hazard Codes | Xn,Xi,N | |||||||||
| Risk Statements | 22-36/37/38-20/21/22 | |||||||||
| Safety Statements | 22-24/25-36/37/39-26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | CY8575000 | |||||||||
| Hazard Note | Harmful | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | IRRITANT, MOISTURE SENSITIVE | |||||||||
| HS Code | 29310095 | |||||||||
| Toxicity | LD50 orl-rat: 740 mg/kg 14KTAK -,693,64 | |||||||||
| NFPA 704 |
|
Phenylboronic acid price More Price(15)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | P20009 | Phenylboronic acid 95% | 98-80-6 | 10G | ₹2240.78 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | P20009 | Phenylboronic acid 95% | 98-80-6 | 50G | ₹7707.4 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | P20009 | Phenylboronic acid 95% | 98-80-6 | 250G | ₹24529.45 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 78181 | Phenylboronic acid purum, ≥97.0% (HPLC) | 98-80-6 | 1G | ₹2305.73 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 78181 | Phenylboronic acid purum, ≥97.0% (HPLC) | 98-80-6 | 10G | ₹7804.83 | 2022-06-14 | Buy |
Phenylboronic acid Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powder. Insoluble in water and benzene, easily soluble in ether and methanol. When exposed to air or under heating conditions, it is easy to dehydrate and form a three-molecular polymer.
Uses
Phenylboronic Acid is a compound used in organic synthesis of various pharmaceutical goods.
Phenylboronic acid (PBA) and its derivatives can bind sugars and other diol compounds to form cyclic boronate esters. These esters bear negative charges. Due to this reaction, sugars can be detected by means of electrochemical and optical techniques.
PBA modified electrodes have been constructed as reagentless electrochemical sensors. There, PBA is absorbed on the electrode surface either as a self- assembled monolayer film ore a polymer thin film. Basically, for optical detection techniques for the detection of sugars, PBA is modified with a chromophore that should change its properties on reaction with a sugar.
Reaction of Phenylboronic acid with a sugar
Definition
ChEBI: Phenylboronic acid is a member of boronic acids. It is functionally related to a boronic acid.
General Description
Phenylboronic acid (PBA) is an organoboronic acid. It behaves as a molecular receptor that can attach to compounds containing cis-diol group. Microwave-assisted Suzuki coupling of aryl chlorides with phenylboronic acid in the presence of Pd/C (catalyst) and water (solvent) has been described. Palladium-catalyzed cross-coupling reaction of phenylboronicacid with haloarenes to afford biaryls has been reported.
Safety Profile
Poison by intravenous andintraperitoneal routes. Moderately toxic by ingestion.Mildly toxic by skin contact. When heated to decomposition it emitsacrid smoke and irritating fumes.
Phenylboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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| ANJI BIOSCIENCES | 58 |
| JIVICHEM SYNTHESIS PVT LTD | 58 |
| Varada Pharma Chem Pvt Ltd | 58 |
| PRODIGIOUS LIFE SCIENCES | 58 |
| REDDY N REDDY PHARMACEUTICALS | 58 |
| JSK Chemicals | 58 |
| VINEET LABORATORIES LIMITED | 58 |
| Honour Lab Limited | 58 |
| Rivashaa Agrotech Biopharma Pvt. Ltd. | 58 |
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