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Phenyl trifluoromethanesulfonate

Phenyl trifluoromethanesulfonate Structure
CAS No.
17763-67-6
Chemical Name:
Phenyl trifluoromethanesulfonate
Synonyms
Phenol triflate;PHENYL TRIFLATE;Phenol trifluoromethanesulfonate;PHENYL TRIFLUOROMETHANESULFONATE;Trifluoromethylsulfonyloxybenzene;Phenyl rifluoromehanesulfonae, 98%;PhenylTrifluoromethanesulfonate>Phenyl trifluoromethanesulfonate 98%;Trifluoromethanesulfonic acid phenyl ester;Methanesulfonic acid, 1,1,1-trifluoro-, phenyl ester
CBNumber:
CB5369083
Molecular Formula:
C7H5F3O3S
Molecular Weight:
226.17
MOL File:
17763-67-6.mol
Modify Date:
2023/6/8 17:06:37
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Phenyl trifluoromethanesulfonate Properties

Boiling point 99-100 °C/60 mmHg (lit.)
Density 1.396 g/mL at 25 °C (lit.)
refractive index n20/D 1.435(lit.)
Flash point 160 °F
storage temp. Inert atmosphere,Room Temperature
form clear liquid
color Colorless to Almost colorless

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS06
Signal word  Danger
Hazard statements  H301+H311-H314
Precautionary statements  P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P361+P364
Hazard Codes  T
Risk Statements  36/37/38-34-24/25
Safety Statements  26-36-45-36/37/39
RIDADR  UN 2927 6.1/PG 2
WGK Germany  3
HS Code  29049090
NFPA 704
2
2 0

Phenyl trifluoromethanesulfonate price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 423939 Phenyl trifluoromethanesulfonate 98% 17763-67-6 5ML ₹10540 2022-06-14 Buy
TCI Chemicals (India) P1829 Phenyl Trifluoromethanesulfonate min. 98.0 % 17763-67-6 1G ₹2600 2022-05-26 Buy
TCI Chemicals (India) P1829 Phenyl Trifluoromethanesulfonate min. 98.0 % 17763-67-6 5G ₹8300 2022-05-26 Buy
Product number Packaging Price Buy
423939 5ML ₹10540 Buy
P1829 1G ₹2600 Buy
P1829 5G ₹8300 Buy

Phenyl trifluoromethanesulfonate Chemical Properties,Uses,Production

Chemical Properties

Colorless Liquid.

Uses

Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies:
As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos.
As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling.
Synthesis of N-(2,6-diarylbenzoyl)anilines by diarylation of benzanilides with phenyl triflate in the presence of palladium-based catalyst.
As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofuran by the arylation of 2,3-dihydrofuran.

Preparation

Synthesis of Phenyl trifluoromethanesulfonate: The reaction of phenol (1.00 g, 10.6 mmol) with triflic anhydride as outlined in the general procedure provided phenyl trifluoromethanesulfonate as colorless oil (0.73 g, 30%).
1H NMR (400 MHz, CDCl3) δ 7.50 – 7.42 (m, 2H), 7.41 – 7.36 (m, 1H), 7.32 – 7.24 (m, 2H).

General Description

Phenyl trifluoromethanesulfonate (phenyl triflate) is an aryl fluorosulphonate. It has been synthesized by the reaction of phenol with fluorosulphonic anhydride.

Phenyl trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

4-Nitrophenylboronic acid pinacol ester N-PHENYL-3-BIPHENYLAMINE R-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol 4-PHENYL-3-BUTYN-1-OL 1-PHENYLCYCLOPENTENE
3-HYDROXYBENZOPHENONE Methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate Phenylpentane
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Phenyl trifluoromethanesulfonate Suppliers

Global( 93)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29825 58 Inquiry
Zhengzhou Alfa Chemical Co.,Ltd +8618530059196 China 13219 58 Inquiry
Hefei TNJ Chemical Industry Co.,Ltd. 0551-65418671 China 34571 58 Inquiry
Dayang Chem (Hangzhou) Co.,Ltd. 571-88938639 +8617705817739 China 52861 58 Inquiry
Aromsyn Co., Ltd. +86-0571-85585865 +8613336024896 China 19185 58 Inquiry
Hebei Guanlang Biotechnology Co., Ltd. +8619930503259 China 18431 58 Inquiry
PT CHEM GROUP LIMITED +86-85511178 +86-85511178 China 35426 58 Inquiry
GIHI CHEMICALS CO.,LIMITED +8618058761490 China 49999 58 Inquiry
Aceschem Inc. +1-817863-6948 +1-（817）863-6948 United States 19639 58 Inquiry
Supplier Advantage
TCI Chemicals (India) Pvt. Ltd. 58
career henan chemical co 58
Zhengzhou Alfa Chemical Co.,Ltd 58
Hefei TNJ Chemical Industry Co.,Ltd. 58
Dayang Chem (Hangzhou) Co.,Ltd. 58
Aromsyn Co., Ltd. 58
Hebei Guanlang Biotechnology Co., Ltd. 58
PT CHEM GROUP LIMITED 58
GIHI CHEMICALS CO.,LIMITED 58
Aceschem Inc. 58

Phenyl trifluoromethanesulfonate Spectrum

Phenyl trifluoromethanesulfonate(17763-67-6)IR

17763-67-6(Phenyl trifluoromethanesulfonate)Related Search:

4-BROMOPHENYL TRIFLUOROMETHANESULFONATE Trimethylsilyl trifluoromethanesulfonate TRIFLUOROMETHYL SULFINYL CHLORIDE SILVER TRIFLUOROMETHANESULFONATE Trifluoromethanesulfonyl chloride
Ethyl trifluoromethanesulfonate Trifluoromethanesulfonic anhydride Sodium trifluoromethanesulfonate Trifluoromethanesulfonic acid Lithium trifluoromethanesulfonate
Methyl trifluoromethanesulfonate 4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,98.0+%(GC),4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE P-TOLYL TRIFLATE 1-NAPHTHYL TRIFLATE 4-NITROPHENYL TRIFLUOROMETHANESULFONATE
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE METHYL 2-TRIFLUOROMETHANESULFONYLOXY-1-NAPHTHOATE (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
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PHENYL TRIFLUOROMETHANESULFONATE PHENYL TRIFLATE Phenol triflate Phenol trifluoromethanesulfonate Trifluoromethanesulfonic acid phenyl ester Trifluoromethylsulfonyloxybenzene Trifluoromethanesulfonic Acid Phenyl Ester Phenyl Triflate Phenyl trifluoromethanesulfonate 98% PhenylTrifluoromethanesulfonate> Methanesulfonic acid, 1,1,1-trifluoro-, phenyl ester Phenyl rifluoromehanesulfonae, 98% 17763-67-6 C6H5SO3CF3 Building Blocks Organic Building Blocks Organic Triflates Sulfur Compounds