Phenyl trifluoromethanesulfonate
![Phenyl trifluoromethanesulfonate Structure](CAS/GIF/17763-67-6.gif)
- CAS No.
- 17763-67-6
- Chemical Name:
- Phenyl trifluoromethanesulfonate
- Synonyms
- Phenol triflate;PHENYL TRIFLATE;Phenol trifluoromethanesulfonate;PHENYL TRIFLUOROMETHANESULFONATE;Trifluoromethylsulfonyloxybenzene;Phenyl rifluoromehanesulfonae, 98%;PhenylTrifluoromethanesulfonate>Phenyl trifluoromethanesulfonate 98%;Trifluoromethanesulfonic acid phenyl ester;Methanesulfonic acid, 1,1,1-trifluoro-, phenyl ester
- CBNumber:
- CB5369083
- Molecular Formula:
- C7H5F3O3S
- Molecular Weight:
- 226.17
- MOL File:
- 17763-67-6.mol
- Modify Date:
- 2023/6/8 17:06:37
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS05,GHS06 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H301+H311-H314 | |||||||||
Precautionary statements | P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P361+P364 | |||||||||
Hazard Codes | T | |||||||||
Risk Statements | 36/37/38-34-24/25 | |||||||||
Safety Statements | 26-36-45-36/37/39 | |||||||||
RIDADR | UN 2927 6.1/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
HS Code | 29049090 | |||||||||
NFPA 704 |
|
Phenyl trifluoromethanesulfonate price More Price(3)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 423939 | Phenyl trifluoromethanesulfonate 98% | 17763-67-6 | 5ML | ₹10540 | 2022-06-14 | Buy |
TCI Chemicals (India) | P1829 | Phenyl Trifluoromethanesulfonate min. 98.0 % | 17763-67-6 | 1G | ₹2600 | 2022-05-26 | Buy |
TCI Chemicals (India) | P1829 | Phenyl Trifluoromethanesulfonate min. 98.0 % | 17763-67-6 | 5G | ₹8300 | 2022-05-26 | Buy |
Phenyl trifluoromethanesulfonate Chemical Properties,Uses,Production
Chemical Properties
Colorless Liquid.
Uses
Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies:
As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos.
As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling.
Synthesis of N-(2,6-diarylbenzoyl)anilines by diarylation of benzanilides with phenyl triflate in the presence of palladium-based catalyst.
As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofuran by the arylation of 2,3-dihydrofuran.
Preparation
Synthesis of Phenyl trifluoromethanesulfonate: The reaction of phenol (1.00 g, 10.6 mmol) with triflic anhydride as outlined in the general procedure provided phenyl trifluoromethanesulfonate as colorless oil (0.73 g, 30%).
1H NMR (400 MHz, CDCl3) δ 7.50 – 7.42 (m, 2H), 7.41 – 7.36 (m, 1H), 7.32 – 7.24 (m, 2H).
General Description
Phenyl trifluoromethanesulfonate (phenyl triflate) is an aryl fluorosulphonate. It has been synthesized by the reaction of phenol with fluorosulphonic anhydride.
Phenyl trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
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TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29825 | 58 | Inquiry |
Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | China | 13219 | 58 | Inquiry |
Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | China | 34571 | 58 | Inquiry |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | China | 52861 | 58 | Inquiry |
Aromsyn Co., Ltd. | +86-0571-85585865 +8613336024896 | China | 19185 | 58 | Inquiry |
Hebei Guanlang Biotechnology Co., Ltd. | +8619930503259 | China | 18431 | 58 | Inquiry |
PT CHEM GROUP LIMITED | +86-85511178 +86-85511178 | China | 35426 | 58 | Inquiry |
GIHI CHEMICALS CO.,LIMITED | +8618058761490 | China | 49999 | 58 | Inquiry |
Aceschem Inc. | +1-817863-6948 +1-(817)863-6948 | United States | 19639 | 58 | Inquiry |
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