Sodium trifluoromethanesulfonate
- CAS No.
- 2926-30-9
- Chemical Name:
- Sodium trifluoromethanesulfonate
- Synonyms
- SODIUM TRIFLATE;Sodium trifluoride;Sodium trifluorometha;Sodium trifluomethanesulfonate;SODIUM TRIFLUOROMETHANESULFONATE;SODIUM TRIFLUOROMETHANESULPHONATE;Sodiumtrifluoromethanesulphonate98%;Sodium trifluoromethanesulfonate,98%;SodiuM trifluoroMethanesulfonate 98%;Sodium trifluoromethanesulphonate 98%
- CBNumber:
- CB5330814
- Molecular Formula:
- CF3NaO3S
- Molecular Weight:
- 172.06
- MOL File:
- 2926-30-9.mol
- Modify Date:
- 2024/3/13 10:16:46
| Melting point | 253-255 °C (lit.) |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| form | Powder |
| color | White to off-white |
| Water Solubility | soluble |
| Sensitive | Hygroscopic |
| Hydrolytic Sensitivity | 0: forms stable aqueous solutions |
| BRN | 3728797 |
| InChIKey | KKVTYAVXTDIPAP-UHFFFAOYSA-M |
| CAS DataBase Reference | 2926-30-9(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,C,Xn | |||||||||
| Risk Statements | 36/37/38-20/21/22 | |||||||||
| Safety Statements | 26-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 3-10 | |||||||||
| Hazard Note | Corrosive | |||||||||
| TSCA | No | |||||||||
| HS Code | 29049090 | |||||||||
| NFPA 704 |
|
Sodium trifluoromethanesulfonate price More Price(10)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 367907 | Sodium trifluoromethanesulfonate 98% | 2926-30-9 | 5G | ₹4926.85 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 367907 | Sodium trifluoromethanesulfonate 98% | 2926-30-9 | 25G | ₹15086.5 | 2022-06-14 | Buy |
| ALFA India | ALF-B20776-22 | Sodium trifluoromethanesulfonate, 98% | 2926-30-9 | 100g | ₹59175 | 2022-05-26 | Buy |
| ALFA India | ALF-B20776-14 | Sodium trifluoromethanesulfonate, 98% | 2926-30-9 | 25g | ₹8955 | 2022-05-26 | Buy |
| ALFA India | ALF-B20776-06 | Sodium trifluoromethanesulfonate, 98% | 2926-30-9 | 5g | ₹4420 | 2022-05-26 | Buy |
Sodium trifluoromethanesulfonate Chemical Properties,Uses,Production
Description
Sodium trifluoromethanesulfonate is commonly known as trifluoromethanesulfonic acid or TFMS. Possessing unique properties, TFMS is water-soluble, anionic, and boasts a range of valuable attributes. As a colorless, odorless, and non-toxic substance, TFMS finds widespread use as a reagent in organic synthesis, a catalyst in industrial applications, and a buffer in various biochemical experiments. In scientific research, TFMS stands out due to its robust acidity, enabling it to act as a potent catalyst in organic synthesis. Additionally, it effectively serves as a reliable buffer at pH levels, ensuring precise pH maintenance in biochemical experiments. As an anionic compound, TFMS functions as a strong acid in solution, facilitating the donation of protons to other molecules, thus reducing the pH.
Chemical Properties
White to off-white powder
Uses
Sodium trifluoromethanesulfonate is used in the preparation of N-fluoro-2-methylpyridinium triflate by reaction with dinitrogen difluoride as a reagent. It is also used as a chaotropic mobile phase additive in reversed-phase liquid chromatography (RP-LC).
Preparation
Sodium trifluoromethanesulfonate is prepared by adding a slight excess of sodium sulfate to an aqueous solution of barium trifluoromethanesulfonate. The reaction mixture is stirred for several minutes and allowed to stand for one day, and the white precipitate of barium sulfate is removed by filtration. The clear filtrate is evaporated to dryness, and the solid product is recrystallized from dry acetone. The salt is dried under vacuum at 110?°C.1 Barium trifluoromethanesulfonate can be easily prepared from aqueous trifluoromethanesulfonic acid and barium carbonate. Other methods include the preparation of sodium trifluoromethane sulfonate from sodium dithionite and bromotrifluoromethane and its oxidation to sodium trifluoromethane sulfonate using hydrogen peroxide.
General Description
Sodium trifluoromethanesulfonate (Sodium triflate or NaOTf) is an efficient catalyst as well as a reagent in many organic reactions. The prominent application includes catalytic asymmetric Mannich-type reactions, Mannich-type reactions in water, and Diels-Alder reactions.
Solubility in organics
soluble in water, alcohol, acetonitrile, N,N-dimethylformamide, and most highly polar organic solvents.
Sodium trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
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