YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE
![YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Structure](CAS/GIF/54761-04-5.gif)
- CAS No.
- 54761-04-5
- Chemical Name:
- YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE
- Synonyms
- YB(OTF)3;YTTERBIUM TRIFLUOROMETHANESULFONATE;YTTERBIUM(III) TRIFLATE HYDRATE;YTTERBIUM (III) TRIFLUOROMETHANESULFONATE;YTTERBIUM TRIFLUOROMETHANESULPHONATE;Yb(TFA)3;Ytterbiumtriflate;YTTERBIUM (III) TRIFLATE;Acid Ytterbium(III) Salt;YTTERBIUM TRIFLATE HYDRATE
- CBNumber:
- CB7142534
- Molecular Formula:
- C3F9O9S3Yb
- Molecular Weight:
- 620.24
- MOL File:
- 54761-04-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/2/7 13:49:33
Melting point | 8 °C |
---|---|
storage temp. | Inert atmosphere,Room Temperature |
solubility | Methanol |
form | Powder |
color | White to Off-White |
Sensitive | Hygroscopic |
Hydrolytic Sensitivity | 6: forms irreversible hydrate |
Merck | 14,10106 |
Stability | Hygroscopic |
CAS DataBase Reference | 54761-04-5(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36 | |||||||||
RIDADR | UN 3261 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 3-10 | |||||||||
Hazard Note | Irritant/Hygroscopic | |||||||||
TSCA | No | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 28469099 | |||||||||
NFPA 704 |
|
YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE price More Price(4)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 430595 | Ytterbium(III) trifluoromethanesulfonate 99.99% | 54761-04-5 | 1G | ₹2089.23 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 430595 | Ytterbium(III) trifluoromethanesulfonate 99.99% | 54761-04-5 | 5G | ₹6267.68 | 2022-06-14 | Buy |
TCI Chemicals (India) | T1610 | Ytterbium(III) Trifluoromethanesulfonate Hydrate | 54761-04-5 | 5G | ₹5200 | 2022-05-26 | Buy |
TCI Chemicals (India) | T1610 | Ytterbium(III) Trifluoromethanesulfonate Hydrate | 54761-04-5 | 25G | ₹18900 | 2022-05-26 | Buy |
YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Chemical Properties,Uses,Production
Uses
Versatile rare earth metal catalyst in organic synthesis.
Preparation
Ytterbium(III) Trifluoromethanesulfonate is prepared by addition of an excess of ytterbium(III) oxide (commercially available, 99.9%) to an aqueous solution of Trifluoromethanesulfonic Acid (50% v/v) followed by heating at boiling for 0.5-1 h. The mixture is then purified by filtration to remove unreacted ytterbium oxide; residual water is removed under reduced pressure. The resultant hydrate is dried by heating under vacuum (1 mmHg) at 180 to 200 °C for 48 h. The reagent is then used without further purification.[1] The organoytterbium reagent is prepared at -78 °C from Yb(OTf)3 and organolithiums or organomagnesiums.[2]
storage
Ytterbium(III) Trifluoromethanesulfonate forms hydrates in aqueous media in the presence of amines; however, it survives mild aqueous workup.
References
1. Forsberg, J. H.; Spaziano, V. T.; Balasubramanian, T. M.; Liu, G. K.; Kinsley, S. A.; Duckworth, C. A.; Poteruca, J. J.; Brown, P. S.;
Miller, J. L. JOC 1987, 52, 1017.
2. Molander, G. A.; Burkhardt, E. R.; Weinig, P. JOC 1990, 55, 4990
YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
SURVIVAL TECHNOLOGIES LIMITED | +91 8108285261 | Gujarat, India | 294 | 58 | Inquiry |
JSK Chemicals | +919879767970 | Gujarat, India | 3753 | 58 | Inquiry |
Manus Aktteva Biopharma LLP | 08048250218Ext 800 | Ahmedabad, India | 655 | 58 | Inquiry |
Survival Technologies Pvt Ltd | +91 (22) 4212-8221 | New Delhi, India | 290 | 50 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6100 | 58 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6257 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | China | 29793 | 60 | Inquiry |
Accela ChemBio Inc. | +1-858-6993322 | United States | 18463 | 58 | Inquiry |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39894 | 58 | Inquiry |
Supplier | Advantage |
---|---|
SURVIVAL TECHNOLOGIES LIMITED | 58 |
JSK Chemicals | 58 |
Manus Aktteva Biopharma LLP | 58 |
Survival Technologies Pvt Ltd | 50 |
A.J Chemicals | 58 |
CLEARSYNTH LABS LTD. | 58 |
TCI Chemicals (India) Pvt. Ltd. | 58 |
Capot Chemical Co.,Ltd. | 60 |
Accela ChemBio Inc. | 58 |
Chongqing Chemdad Co., Ltd | 58 |
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