ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic aluminum >Aluminum trifluoromethanesulfonate
Aluminum trifluoromethanesulfonate
- CAS No.
- 74974-61-1
- Chemical Name:
- Aluminum trifluoromethanesulfonate
- Synonyms
- ALUMINUM TRIFLATE;ALUMINIUM TRIFLATE;Aluminium(III) triflate;uminum trifL;ALUMINUM TRIFLUOROMETHANESULFONATE;ALUMINIUM TRIFLUOROMETHANESULFONATE;Aluminum Trifluoromethanesulfonatec;ALUMINIUM TRIFLUOROMETHANESULPHONATE;Aluminumtrifluoromethanesulfonate,98%;Aluminiumtrifluoromethanesulphonate99%
- CBNumber:
- CB7387584
- Molecular Formula:
- CH4AlF3O3S
- Molecular Weight:
- 180.08
- MOL File:
- 74974-61-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/4/23 13:52:06
| Melting point | 300 °C(lit.) |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | soluble in ether, acetone, acetonitrile, and diglyme; poorly soluble in nitromethane; sparingly soluble in SO2 and SO2 ClF. |
| form | Powder |
| color | White |
| Water Solubility | Insoluble in water. |
| Sensitive | Hygroscopic |
| Hydrolytic Sensitivity | 6: forms irreversible hydrate |
| Stability | hygroscopic |
| CAS DataBase Reference | 74974-61-1(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| Hazard Codes | C,Xi | |||||||||
| Risk Statements | 34-36/37/38 | |||||||||
| Safety Statements | 26-36/37/39-45-36 | |||||||||
| RIDADR | UN 3261 8/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Corrosive | |||||||||
| TSCA | No | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29049020 | |||||||||
| NFPA 704 |
|
Aluminum trifluoromethanesulfonate price More Price(4)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 515884 | Aluminum trifluoromethanesulfonate 99.9% trace metals basis | 74974-61-1 | 10G | ₹11383.45 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 515884 | Aluminum trifluoromethanesulfonate 99.9% trace metals basis | 74974-61-1 | 50G | ₹24971.85 | 2022-06-14 | Buy |
| ALFA India | ALF-B20785-14 | Aluminum trifluoromethanesulfonate, 99% | 74974-61-1 | 25g | ₹20226 | 2022-05-26 | Buy |
| ALFA India | ALF-B20785-06 | Aluminum trifluoromethanesulfonate, 99% | 74974-61-1 | 5g | ₹6930 | 2022-05-26 | Buy |
Aluminum trifluoromethanesulfonate Chemical Properties,Uses,Production
Chemical Properties
White powder
Uses
Aluminum trifluoromethanesulfonate is used in pharmaceutical intermediates.
Preparation
Can be prepared from aluminum trichloride and tribromide by heating with triflic acid in anhydrous conditions. Preparations from triethylaluminum, aluminum carbide, and aluminum isopropoxide have also been described.
Reactions
Friedel-Crafts Reactions.
Aluminum trifluoromethanesulfonate has been used for the Friedel-Crafts alkylation reaction of toluene with isopropyl and tert-butyl chlorides (eq 1), and for theacylationofbenzeneandtoluenewithacetylandbenzoylchlo- rides in low to moderate yields. Intramolecular Friedel-Crafts acylation of an aromatic compound with Meldrum’s acid has also been reported using catalytic amounts of Al(OTf) 3 . Acylation of 2-methoxynaphthalene with acetic anhydride has been reported using Al(OTf) 3 and lithium perchlorate as an additive to afford the corresponding 6-acetylated adduct in 83% yield. Effective acylation of arenes with carboxylic acids has also been disclosed using polystyrene-supported Al(OTf)3.
Aluminum trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 218)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| SURVIVAL TECHNOLOGIES LIMITED | +91 8108285261 | Gujarat, India | 294 | 58 | Inquiry |
| ORGANO FINE CHEMICALS | +91-91-22-42128300 +91-2242128300 | Mumbai, India | 258 | 58 | Inquiry |
| Organo Fine Chemicals | +91 (22) 2201-6968 / 2206-7521 | New Delhi, India | 266 | 60 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Reax Chemicals | 08048372701Ext 416 | Hyderabad, India | 4223 | 58 | Inquiry |
| Spectrochem Pvt., Ltd. | 91-22-22016968 | Maharashtra, India | 183 | 58 | Inquiry |
| ORGANO FINE CHEMICALS | +91-22-42128300 | Mumbai, India | 202 | 58 | Inquiry |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
| Supplier | Advantage |
|---|---|
| SURVIVAL TECHNOLOGIES LIMITED | 58 |
| ORGANO FINE CHEMICALS | 58 |
| Organo Fine Chemicals | 60 |
| CLEARSYNTH LABS LTD. | 58 |
| A.J Chemicals | 58 |
| Alfa Aesar | 58 |
| Reax Chemicals | 58 |
| Spectrochem Pvt., Ltd. | 58 |
| ORGANO FINE CHEMICALS | 58 |
| Capot Chemical Co.,Ltd. | 60 |
74974-61-1(Aluminum trifluoromethanesulfonate)Related Search:
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Bismuth(III) trifluoromethanesulfonate
Lithium trifluoromethanesulfonate
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