ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Sulfonates / Sulfinates salts >Lanthanum trifluoromethanesulfonate
Lanthanum trifluoromethanesulfonate
- CAS No.
- 52093-26-2
- Chemical Name:
- Lanthanum trifluoromethanesulfonate
- Synonyms
- La(OTf)3;LANTHANUM TRIFLATE;anthanum(III) TrifL;LANTHANUM(III) TRIFLATE;Lanthanum trifluoromesylate;LANTHANUM TRIFLUOROMETHANESULFONATE;Lanthanum Trifluoromethnesulfonate;LANTHANUM TRIFLUOROMETHANESULPHONATE;Lanthanumtrifluoromethanesulphonate98%;LanthanuM(Ⅲ) trifluoroMethanesulfonate
- CBNumber:
- CB7427257
- Molecular Formula:
- C3F9LaO9S3
- Molecular Weight:
- 586.11
- MOL File:
- 52093-26-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/2/23 21:28:46
| Melting point | >300°C |
|---|---|
| Density | 1.7 |
| storage temp. | Inert atmosphere,2-8°C |
| solubility | sol H2O; partially sol THF, CH2Cl2; sparingly sol Et2O; insol hexane. |
| form | Crystalline Powder |
| color | White to light beige |
| Water Solubility | Soluble in water. |
| Sensitive | Hygroscopic |
| Hydrolytic Sensitivity | 6: forms irreversible hydrate |
| BRN | 9009103 |
| Stability | hygroscopic |
| InChI | InChI=1S/3CHF3O3S.La/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3 |
| InChIKey | WGJJZRVGLPOKQT-UHFFFAOYSA-K |
| SMILES | C(F)(S([O-])(=O)=O)(F)F.C(F)(F)(F)S([O-])(=O)=O.C(F)(F)(F)S([O-])(=O)=O.[La+3] |
| CAS DataBase Reference | 52093-26-2(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H314-H318-H315-H319-H335 | |||||||||
| Precautionary statements | P260h-P301+P330+P331-P303+P361+P353-P405-P501a-P261-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| RIDADR | UN 1759 8/PG III | |||||||||
| WGK Germany | 3 | |||||||||
| F | 3-10 | |||||||||
| Hazard Note | Irritant | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28469099 | |||||||||
| NFPA 704 |
|
Lanthanum trifluoromethanesulfonate price More Price(8)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 430609 | Lanthanum(III) trifluoromethanesulfonate 99.999% trace metals basis | 52093-26-2 | 5G | ₹2522.23 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 430609 | Lanthanum(III) trifluoromethanesulfonate 99.999% trace metals basis | 52093-26-2 | 25G | ₹10045.6 | 2022-06-14 | Buy |
| ALFA India | ALF-L19657-14 | Lanthanum trifluoromethanesulfonate, anhydrous, 99% | 52093-26-2 | 25g | ₹11400 | 2022-05-26 | Buy |
| ALFA India | ALF-L19657-06 | Lanthanum trifluoromethanesulfonate, anhydrous, 99% | 52093-26-2 | 5g | ₹2770 | 2022-05-26 | Buy |
| TCI Chemicals (India) | T1293 | Lanthanum(III) Trifluoromethanesulfonate | 52093-26-2 | 5G | ₹3200 | 2022-05-26 | Buy |
Lanthanum trifluoromethanesulfonate Chemical Properties,Uses,Production
Description
Lanthanum trifluoromethanesulfonate is a Lewis acid catalyst useful for aldol, Michael, Diels-Alder, and other C-C bond forming reactions; also useful for preparing organolanthanum reagents, which react with hindered tertiary amides to afford ketones.
Chemical Properties
white to light beige crystalline powder
Uses
Lanthanum trifluoromethanesulfonate is a water-tolerant Lewis acid used in the Aldol reaction of silyl enol ethers with aldehydes. It is an effective catalyst for the Baylis-Hillman reaction. It also catalyzes Michael additions to methyl vinyl ketone in water.
Synthesis
To an aqueous solution of triflic acid (50% v/v), a slight excess of lanthanum oxide (La2O3) is added; the resulting mixture is stirred for 15 min at rt and then filtered to remove the unreacted oxide; the filtrate is concentrated in vacuo at about 60 °C; residual water is removed by azeotropic distillation with toluene in vacuo to dryness; the resulting hydrate is placed in a flask equipped with a stirring bar, a stopcock filled with a glass wool plug, and a NaOH trap, and is then dehydrated by heating under vacuum (140 °C/0.1 mmHg or 180 °C/1.0 mmHg) for 16 h. The anhydrous Lanthanum trifluoromethanesulfonate La(OTf)3 is a white to gray-white solid.
storage
Anhydrous La(OTf)3 is hygroscopic and should be stored and weighed in a glove-box. Use in a fume hood.
Lanthanum trifluoromethanesulfonate Preparation Products And Raw materials
Global( 244)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| SURVIVAL TECHNOLOGIES LIMITED | +91 8108285261 | Gujarat, India | 294 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| Triveni chemicals | 08048762458 | New Delhi, India | 6088 | 58 | Inquiry |
| Spectrochem Pvt., Ltd. | 91-22-22016968 | Maharashtra, India | 183 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6257 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6700 | 30 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6100 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6905 | 58 | Inquiry |
| Sisco Research Laboratories Pvt. Ltd. | +91-22-4268 5800 | Mumbai, India | 4315 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| SURVIVAL TECHNOLOGIES LIMITED | 58 |
| JSK Chemicals | 58 |
| Triveni chemicals | 58 |
| Spectrochem Pvt., Ltd. | 58 |
| CLEARSYNTH LABS LTD. | 58 |
| CHEMSWORTH | 30 |
| A.J Chemicals | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Sisco Research Laboratories Pvt. Ltd. | 58 |
52093-26-2(Lanthanum trifluoromethanesulfonate)Related Search:
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PALLADIUM(II) TRIFLUOROACETATE
Bismuth(III) trifluoromethanesulfonate
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LANTHANUM(III) TRIFLATE
LANTHANUM(III) TRIFLUOROMETHANESULFONATE
LANTHANUM TRIFLATE
LANTHANUM TRIFLUOROMETHANESULFONATE
LANTHANUM TRIFLUOROMETHANESULPHONATE
TRIFLUOROMETHANESULFONIC ACID LANTHANUM(III) SALT
TRIFLUOROMETHANESULFONIC ACID LANTHANUM SALT
Lanthanum(III) trifluoromethanesulfonate, 99.999% metals basis
LANTHANUM TRIFLUOROMETHANESULFONATE, ANHYDROUS
Lanthanum(III)trifluoromethanesulfonate,min.97%(Lanthanumtriflate)
Lanthanum trifluoromethanesulphonate 98%
Lanthanumtrifluoromethanesulphonate98%
Tri(trifluoromethylsulfonyloxy) lanthanum
Tris(trifluoromethanesulfonic acid)lanthanum salt
Tris(trifluoromethylsulfonyloxy) lanthanum
Tris[(trifluoromethyl)sulfonyloxy] lanthanum
Lanthanum(III) trifluoromethanesulfonate,99%
Lanthanum Trifluoromethnesulfonate
Lanthanum(III) triflate, Trifluoromethanesulfonic acid lanthanum salt
LanthanuM(Ⅲ) trifluoroMethanesulfonate
Lanthanum (III) trifluoromethanesulfonate, 97+% (99.9%-La) (Lanthanum triflate)
Methanesulfonic acid,1,1,1-trifluoro-, lanthanuM(3+) salt (3:1)
LanthanuM(III) trifluoroMethanesulfonate, 99% 1GR
LanthanuM(III) trifluoroMethanesulfonate,97% (LanthanuM triflate) La(CF3SO3)3
Lanthanum(III) Triflate
Trifluoromethanesulfonic Acid Lanthanum(III) Salt
La(OTf)3
Lanthanum tris(trifluoromethanesulfonate)
Tris(trifluoromethanesulfonato)lanthanum
Lanthanum(III) trifluoromethanesulfonate 99.999% trace metals basis
Lanthanum(III) trifluoromethanesulphonate 98%
Lanthanum(III) trifluoromethanesulfonate, min. 97%
TRIFLUOROMETHANESULFONIC ACID LANTHANUM(III
anthanum(III) TrifL
LANTHANUM TRIFLUOROMETHANESULFONATE, ANHYDROUSLANTHANUM TRIFLUOROMETHANESULFONATE, ANHYDROUSLANTHANUM TRIFLUOROMETHANESULFONATE, ANHYDROUSLANTHANUM TRIFLUOROMETHANESULFONATE, ANHYDROUS
Lanthanum(III)trifluoromethanesulfonate,min.97%
Lanthanum (III) Trifluoromethanesulfonate extrapure, 98%
Lanthanum trifluoromesylate
LANTHANIUM TRIFLUOROMETHANE SULPHONATE
52093-26-2
52063-26-2
LaSO3CF33
CF3SO33La
LaCF3SO33
3CF3O3SLa
C3F9LaO9S3
Lanthanum
Rare-Earth Metals
Metal Triflates
Transition Metal Compounds
La (Lanthanum)
Homogeneous Catalysts
Stable Lewis Acids in Aqueous Media
Classes of Metal Compounds
Catalysts for Organic Synthesis
Catalysis and Inorganic Chemistry
triflate
metal triflate compounds
Stable Lewis Acids in Aqueous Media