ChemicalBook > Product Catalog >Pharmaceutical intermediates >OLED material intermediate >1-Bromo-2-nitrobenzene
1-Bromo-2-nitrobenzene
- CAS No.
- 577-19-5
- Chemical Name:
- 1-Bromo-2-nitrobenzene
- Synonyms
- 2-BROMONITROBENZENE;O-NITROBROMOBENZENE;1-BroMo-2-;2-Nitrophenyl bromide;1-Bromo-2-Nitrobenene;Benzene,1-bromo-2-nitro-;AURORA KA-1883;2-Nitrobromobenzene;O-BROMONITROBENZENE;Sucrose Impurity 10
- CBNumber:
- CB5379602
- Molecular Formula:
- C6H4BrNO2
- Molecular Weight:
- 202.01
- MOL File:
- 577-19-5.mol
- Modify Date:
- 2025/1/27 9:38:02
| Melting point | 40-42 °C (lit.) |
|---|---|
| Boiling point | 261 °C (lit.) |
| Density | 1.7 g/cm3 (20℃) |
| refractive index | 1.6060 (estimate) |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | powder to crystal |
| color | Light yellow to Amber to Dark green |
| Water Solubility | insoluble |
| BRN | 2044109 |
| Stability | Stable. Combustible. Incompatible with strong bases, strong oxidizing agents. |
| CAS DataBase Reference | 577-19-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzene, 1-bromo-2-nitro-(577-19-5) |
| EPA Substance Registry System | o-Bromonitrobenzene (577-19-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS06,GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H301+H311+H331-H312-H331-H373-H302-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P270-P271-P280-P301+P310+P330-P302+P352+P312+P361+P364-P304+P340+P311-P305+P351+P338+P337+P313-P403+P233-P405-P501-P301+P312+P330-P305+P351+P338-P260-P304+P340-P501a | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 20/21/22-36/37/38-22 | |||||||||
| Safety Statements | 36/37-36/37/39-26-22 | |||||||||
| RIDADR | UN 3459 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | CY9040450 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29049085 | |||||||||
| NFPA 704 |
|
1-Bromo-2-nitrobenzene price More Price(8)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 365424 | 1-Bromo-2-nitrobenzene 98% | 577-19-5 | 25G | ₹21616.95 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 365424 | 1-Bromo-2-nitrobenzene 98% | 577-19-5 | 100G | ₹66222.35 | 2022-06-14 | Buy |
| ALFA India | ALF-A11686-30 | 1-Bromo-2-nitrobenzene, 99% | 577-19-5 | 250g | ₹31159 | 2022-05-26 | Buy |
| TCI Chemicals (India) | B0622 | 1-Bromo-2-nitrobenzene min. 99.0 % | 577-19-5 | 25G | ₹3500 | 2022-05-26 | Buy |
| ALFA India | ALF-A11686-18 | 1-Bromo-2-nitrobenzene, 99% | 577-19-5 | 50g | ₹6202 | 2022-05-26 | Buy |
1-Bromo-2-nitrobenzene Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powder
Uses
1-Bromo-2-nitrobenzene is used in organic synthesis. It also can react with 2-methylamino-benzoic acid to get N-methyl-N-(2-nitro-phenyl)-anthranilic acid. And it is also used in the preparation of 4-methoxy-2?-nitrodiphenyl ether, 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene.
General Description
1-Bromo-2-nitrobenzene undergoes palladium[0]-mediated Ullmann cross-coupling reaction with a range of β-halo-enals, -enones or -esters to afford the corresponding β-aryl derivatives. Palladium[0]-mediated Ullmann cross-coupling reaction of 1-bromo-2-nitrobenzene with β-bromo-α,β-unsaturated aldehydes is reported.
Purification Methods
Crystallise it twice from pet ether, using charcoal before the first crystallisation. [Beilstein 5 III 618, 5 IV 728.]
1-Bromo-2-nitrobenzene Preparation Products And Raw materials
Raw materials
Preparation Products
1-(2-NITROPHENYL)PIPERIDINE
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2-Bromo-6-nitrophenol
5,11-dihydro-5-phenylindolo[3,2-b]carbazole
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TIANFU-CHEM -1-Bromo-2-nitrobenzene
Benzene,1-bromo-2-nitro-
1-BroMo-2-
2-BROMONITROBENZENE
O-NITROBROMOBENZENE
2-Nitrophenyl bromide
1-Bromo-2-Nitrobenene
0-Bromonitrobenzene
Benzenepropanoicacid,7-chloro-β-oxo-,ethylester
2-nitro -1- bormo benzene
Sucrose Impurity 10
1-Bromo-2-nitrobenzene Solution in Isooctane
GA10735500ME1-Bromo-2-nitrobenzenE1000μg/mLi
1-Bromo-2-nitrobenzene in Acetone
1-Bromo-2-nitrobenzene 1000 μg/mL in Methanol
577-19-5
BrC6H4NO2
ARYL HALIDE
Nitro Compounds
Organic Building Blocks
Nitrogen Compounds
Building Blocks
Aromatic Hydrocarbons (substituted) & Derivatives
Benzene derivates
Miscellaneous
Bromine Compounds
Nitro Compounds
Nitro Compounds
Nitrogen Compounds
Organic Building Blocks